• Journal of the Korean Ceramic Society
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• v.37 no.12
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• pp.1221-1228
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• 2000

TiO$_2$를 포함한 희토류 알루미노 규산염계 (NAS: Nd$_2$O$_3$-Al$_2$O$_3$-SiO$_2$) 유리의 상분리 현상에 대하여 연구되었다. 0~10wt%의 TiO$_2$포함한 NAS 조성은 유리전이온도(T$_{g}$) 부근에서 열처리하여 HF로 부식 후 주사전자현미경, 라만 및 IR 분석기로 상분리가 조사되었다. 그 결과로 상분리한 내부결정화는 8wt% 이상의 TiO$_2$를 포함한 NAS 조성에서 나타났다. 어닐링후 T$_{g}$ 부근에서 열처리의 결과는 투명 연핑크색의 유리를 불투명의 연푸른 우유빛 색으로 변하게 하였으며, Si와 Nd-Ti가 각각 풍부한 10$mu extrm{m}$ 이상과 0.1$\mu\textrm{m}$ 이하의 크기인 구형상의 영역으로 균일한 다상분리를 일으켰다. Nd$_2$O$_3$-Al$_2$O$_3$-SiO$_2$-TiO$_2$계에서 상분리는 내부 결정화와 관련하여 매우 중요한 인자로 확인되었다.

• Journal of the Korean Ceramic Society
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• v.32 no.3
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• pp.385-393
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• 1995

Akali-resistant porous glass was prepared by phase separation in Na2O-B2O3-SiO2 system containing ZrO2 and MgO. ZrO2 was added for alkali-resistance and MgO for anti-cracking during leaching. Optimal content of ZrO2 for alkali-resistance was 7wt% and devitrification by heat treatment resulted from further addition. Pore size and pore volume were decreased and specific surface area was increased with ZrO2 addition due to depression in phase separation. Addition of 3mol% MgO to mother glass containing 7wt% ZrO2 was effective for anti-crack during leaching. In this case, with phase separation at 55$0^{\circ}C$ and 5$25^{\circ}C$ for 20 hrs. crack-free porous glasses could be prepared. The relation between pore size r and heat treatment time t at 55$0^{\circ}C$ was D=25.58＋18.16t. According to measurement of gas permeability, the mechanism of gas permeation was Knudsen flow. N2 and He permeability of porous glass which was prepared by heat treatment at 55$0^{\circ}C$ for 20 hrs. were 0.843$\times$10-7mol/$m^2$.s.Pa and 2.161$\times$10-7mol/$m^2$.s.Pa respectively.

• Journal of the Korean Ceramic Society
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• v.18 no.1
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• pp.27-34
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• 1981

The phase separation of low-alkali borosilicate glass with the composition of $6.25Na_2O$.$18.75B_2O_3$.$75.00SiO_2$(mole%) substituting $Li_2O$ for $Na_2O$ was studied. The phase separation in the temperature range of transformation was examined with various heating temperatures and soaking times. Durability to water, thermal expansion and specific density of the specimen were investigated and the microstructure of the separated phase was also observed by transmission electron micrograph techniques. The maximum alkali extraction result with the best phase separation effect was obtained when $Na_2O$ of the base glass was replaced with $1.88Li_2O$ (mole %) and electron micrograph of carbon film replica of $1.88Li_2O$$4.37Na_2O$.$18.75B_2O_3$.$75.00SiO_2$ (mole %) glass showed that the glass consisted of homogeneous two phases. The minimum specific density was shown with the specimen treated at 57$0^{\circ}C$ and it was also shown that the longer the treating time the lower the specific density. The apparent activation energies of approximately 45 kcal/mole by the alkali extraction and 43kcal/mole by the thermal expansion method were derived from the Arrhenius plots, respectively.

• Journal of the Korean institute of surface engineering
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• v.39 no.6
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• pp.255-262
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• 2006

Pd-Cu alloy membrane for hydrogen separation was fabricated by sputtering and Cu reflow process. At first, the Pd and Cu was continuously deposited by sputtering method on oxidized Si support, the Cu reflow process was followed. Microstructure of the surface and permeability of the membrane was investigated depending on various reflow temperature, time, Pd/cu composition and supports. With respect to our result, Pd-Cu thin film (90 wt.% Pd/10 wt.% Cu) deposited by sputtering process with thickness of $2{\mu}m$ was heat-treated for Cu reflow The voids of the membrane surface were completely filled and the dense crystal surface was formed by Cu reflow behavior at $700^{\circ}C$ for 1 hour. Cu reflow process, which is adopted for our work, could be applied to fabrication of dense Pd-alloy membrane for hydrogen separation regardless of supports. Ceramic or metal support could be easily used for the membrane fabricated by reflow process. The Cu reflow process must result in void-free surface and dense crystalline of Pd-alloy membrane, which is responsible for improved selectivity oi the membrane.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.1
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• pp.181-187
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• 2016

Silica is an essential material in the electronics industries of LCDs and OLEDs, which particularly require high purity. This study attempted to find the optimal design of a magnetic separator for silica sand containing iron compounds using CFD simulation. Three designs of magnetic separation were prepared and their efficiency was examined. As a result of the evaluation, the sufficient contact of particulate silica with the surface of magnetic emitters improved the magnetic separation effects. In addition, the loss of $SiO_2$ and the removal rate of $Fe_2O_3$ depended strongly on the particle size, flow rate and magnetic flux density. In addition, magnetic separation is quite effective for a particle size of $10{\mu}m$ with a 0.2 m/s flow rate.

• Resources Recycling
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• v.19 no.6
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• pp.77-85
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• 2010

This study was carried out to develop a process flow sheet for recovering valuables (gold and high purity silica) from the gold mine tailings containing 1.7 g/ton of gold and 79.48 wt.% $SiO_2$. Float-sink tests using heavy liquids was conducted to explore the possibility of recovering gold by gravity separation. Hydrocyclone, froth flotation, and triboelectrostatic separatoin tests were conducted to recover high purity silica from the gold mine tailings. The results of float-sink tests showed that particles containing 5.58 g/ton of gold could be obtained at 2.72 specific gravity, but with very low yields around 3%. Meanwhile, all tests with hydrocyclone, froth flotation, and triboelectrostatic separation showed that high purity silica with $SiO_2$ content over 90% could be obtained. The purity could be improved further up to about 94% by employing several recleaning steps in the froth flotation and triboelectrostatic process.

• Proceedings of the Korean Nuclear Society Conference
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• 1999.10a
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• pp.299.2-299
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• 1999

• Resources Recycling
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• v.19 no.5
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• pp.31-43
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• 2010

To fabricate porous SiC candle filter for filtration facility of the IGCC system, the candle type filter preforms were fabricated by ramming and vacuum extrusion process. A commercially available ${\alpha}$-SiC powders with various particle size were used as starting raw materials, and $44\;{\mu}m$ mullite, $CaCO_3$ powder were used as non-clay based inorganic sintering additive. The candle typed preforms by ramming process and vacuum extrusion were sintered at $1400^{\circ}C$ for 2h in air atmosphere. The effect of forming method and particle size of filter matrix on porosity, density, strength (flexural and compressive strength) and microstructure of the sintered porous SiC candle tilters were investigated. The sintered porous SiC filters which were fabricated by ramming process have more higher density and strength than extruded filter in same particle size of the matrix, and its maximum density and 3-point bending strength were $2.00\;g/cm^3$ and 45 MPa, respectively. Also, corrosion test of the sintered candle filter specimens by different forming method was performed at $600^{\circ}C$ for 2400h using IGCC syngas atmosphere for estimation of long-term reliability of the candle filter matrix.

• Nuclear Engineering and Technology
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• v.29 no.5
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• pp.361-367
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• 1997

The phase separation in ferrite phase of duplex stainless steel is the primary cause of thermal aging embrittlement of the LWR primary pressure boundary components. In this study the phase separation of simulated duplex stainless steel was detected by Mossbauer spectroscopy and magnetic property analysis by VSM(Vibrating Specimen Magnetometer). The simulated duplex stainless steels, Fe-Cr binary, Fe-Cr-Ni ternary, and Fe-Cr-Ni-Si quarternary allots, were aged at 370 and 40$0^{\circ}C$ up to 5,340 hours. It was observed from Mossbauer spectra analysis that internal magnetic field increases with aging time and from VSM that the specific saturation magnetization and Curie temperature increase with aging time. These result are indicative that phase separation into Fe-rich region and Cr-rich region is caused by thermal aging in the temperature range of 370~40$0^{\circ}C$ In cases of specimens containing Ni, the increase of specific saturation magnetization is much higher. This implies that Ni seems to promote Fe-Cr interdiffusion, which accelerates the phase separation into Fe-rich $\alpha$ phase and Cr-rich $\alpha$' phase.

• Proceeding of Spring/Autumn Annual Conference of KHA
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• 2008.11a
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• pp.475-478
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• 2008

In Korea, there has been a tendency that multi-family housings are constructed by providers such as constructors or real estate agents for the economical benefits and selling efficiency, using standardized plans, load-bearing wall system, water-based construction method, and uniformized formworks. Especially, the traditional installation works which service equipments are buried into structures cause serious problems such as shortening building life span, increasing times of remodeling during specific period (100 years) and wasting resources. Also the unilateral way of massive distribution by providers for multi-family housings is not appropriate to meet the various social needs of residents. To solve these problems, it is necessary to build long-life housing which can be easily separated installations, interior and exterior finishings from structural parts. Therefore, this paper will examine the present administrative law and the civil law in order to find negative factors that can be obstructions for providing long-life housings and set the direction to revise the regulations.