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Synthesis of Polymers in Supercritical Carbon Dioxide (초임계 유체를 이용한 고분자 합성 연구)

  • Lee, Hyun-Suk;Kim, Jin-Woong
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.36 no.1
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    • pp.17-32
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    • 2010
  • This review shows the design and the development of new $CO_2$-soluble hydrocarbon copolymers which can be used as effective stabilizers for successful dispersion polymerizations of bio-compatible materials in supercritical carbon dioxide ($scCO_2$). The basic concepts of supercritical fluid including its solvent properties and applications in polymer synthesis are described. We report the facile synthesis of highly soluble hydrocarbon based copolymers, prepared with good control via controlled free radical polymerization from readily accessible and commercially available monomers. The phase behaviour of these materials was monitored in pure $CO_2$ to investigate how the molecular weights and the composition of the copolymers affect their solubility in $CO_2$. Their activity as a stabilizer was then tested in dispersion polymerization of N-vinyl pyrrolidone in $CO_2$ at various reaction conditions to identify the key parameters required for a successful dispersion stabilization of growing PVP particles. Some prospective potentials of this research which can be applied in developing new polymer materials in an environmentally-friendly fashion for use in cosmetics are also discussed.

Impact of Online Learning in India: A Survey of University Students during the COVID-19 Crisis

  • Goswami, Manash Pratim;Thanvi, Jyoti;Padhi, Soubhagya Ranjan
    • Asian Journal for Public Opinion Research
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    • v.9 no.4
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    • pp.331-351
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    • 2021
  • The unprecedented situation of COVID-19 caused the government of India to instruct educational institutions to switch to an online mode to mitigate the losses for students due to the pandemic. The present study attempts to explore the impact of online learning introduced as a stop-gap arrangement during the pandemic in India. A survey was conducted (N=289), via Facebook and WhatsApp, June 1-15, 2020 to understand the accessibility and effectiveness of online learning and constraints that students of higher education across the country faced during the peak times of the pandemic. The analysis and interpretation of the data revealed that the students acclimatized in a short span of time to online learning, with only 33.21% saying they were not satisfied with the online learning mode. However, the sudden shift to online education has presented more challenges for the socially and economically marginalized groups, including Scheduled Caste (SC), Scheduled Tribes (ST), Other Backward Class (OBC), females, and students in rural areas, due to factors like the price of high-speed Internet (78.20% identified it as a barrier to online learning), insufficient infrastructure (23.52% needed to share their device frequently or very frequently), poor Internet connectivity, etc. According to 76.47% of respondents, the future of learning will be in "blended mode." A total of 88.92% of the respondents suggested that the government should provide high-quality video conferencing facilities free to students to mitigate the division created by online education in an already divided society.

Characterization of Light Effect on Photovoltaic Property of Poly-Si Solar Cell by Using Photoconductive Atomic Force Microscopy (Photoconductive Atomic Force Microscopy를 이용한 빛의 세기 및 파장의 변화에 따른 폴리실리콘 태양전지의 광전특성 분석)

  • Heo, Jinhee
    • Korean Journal of Materials Research
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    • v.28 no.11
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    • pp.680-684
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    • 2018
  • We investigate the effect of light intensity and wavelength of a solar cell device using photoconductive atomic force microscopy(PC-AFM). A $POCl_3$ diffusion doping process is used to produce a p-n junction solar cell device based on a polySi wafer, and the electrical properties of prepared solar cells are measured using a solar cell simulator system. The measured open circuit voltage($V_{oc}$) is 0.59 V and the short circuit current($I_{sc}$) is 48.5 mA. Moreover, the values of the fill factors and efficiencies of the devices are 0.7 and approximately 13.6 %, respectively. In addition, PC-AFM, a recent notable method for nano-scale characterization of photovoltaic elements, is used for direct measurements of photoelectric characteristics in limited areas instead of large areas. The effects of changes in the intensity and wavelength of light shining on the element on the photoelectric characteristics are observed. Results obtained through PC-AFM are compared with the electric/optical characteristics data obtained through a solar simulator. The voltage($V_{PC-AFM}$) at which the current is 0 A in the I-V characteristic curves increases sharply up to $18W/m^2$, peaking and slowly falling as light intensity increases. Here, $V_{PC-AFM}$ at $18W/m^2$ is 0.29 V, which corresponds to 59 % of the average $V_{oc}$ value, as measured with the solar simulator. Furthermore, while the light wavelength increases from 300 nm to 1,100 nm, the external quantum efficiency(EQE) and results from PC-AFM show similar trends at the macro scale but reveal different results in several sections, indicating the need for detailed analysis and improvement in the future.

Annual Intensities (2016-2017) Analysis of Energy Use and CO2 Emission by End Use based on Measurements of Sample Apartment Units (표본건물 계측에 의한 공동주택 세대에서의 용도별 에너지사용량 및 CO2 배출량 연간 원단위 (2016 - 2017) 분석)

  • Jin, Hye-Sun;Lim, Han-Young;Lee, Soo-Jin;Kim, Sung-Im;Lim, Jae-Han;Song, Seung-Yeong
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.34 no.7
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    • pp.43-52
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    • 2018
  • In this study, annual site and primary energy use intensities (EUIs) and CO2 emission intensities (CEIs) per area by end use were estimated based on the measurement data from June 2016 to May 2017 of 50 sample apartment units in Seoul. In addition, estimated site EUIs by end use were compared to the U.S. Residential Energy Consumption Survey (RECS) 2009 data. Site EUIs by end use were found to be in the order of heating > electric appliance > domestic hot water > cooking > lighting > cooling > air movement. In the case of primary EUIs and CEIs by end use, electric appliance was found to be the largest. As results of comparison with the RECS 2009 data, it was found that site EUIs were very similar for heating, domestic hot water and electric appliance, etc., but slightly different for cooling. The number of sample apartment units will continue to increase until 2020 (total number of samples 200) and intensities data by end use will be continuously updated through continuous collection of measurement data.

Comprehensive Analysis of Energy Consumption Rate and New Technology Trend in High-Performance Buildings related with Different Climatic Zones (세계 기후대별 High-Performance Buildings의 에너지 소비 원단위 평가 및 신기술 적용 동향 분석 연구)

  • Kim, Chul-Ho;Lee, Seung-Eon;Kim, Kang-Soo
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.34 no.11
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    • pp.63-72
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    • 2018
  • In this study, we analyzed high-performance building technologies through a case study of 65 high-performance buildings in the U.S., Europe, Asia and Oceania. In detail, we reviewed the international trend of building energy-saving technology and energy consumption per unit area by analyzing buildings constructed within a 10 year period(2008-018). The primary energy consumption was $48-440kWh/m^2$, and the average value was calculated as $169.3kWh/m^2$. Although some buildings received high certification ratings, they did not meet either Korean or international energy evaluation standards. The system analysis revealed that many energy-saving technologies show various application rates in different countries because the technologies possess different properties. Furthermore, small-area building groups tended to have less primary energy consumption than the medium and large-area buildings, but the area-energy relationship $R^2$ value was analyzed as 0.3161, indicating no clear proportional relationship. Therefore, we propose that it is necessary to maximize the energy savings of buildings by taking into consideration a region's code, climate, building usage, area and space-using patterns to reduce energy and greenhouse gas emissions.

The Wind Load Evaluation on Building Considering Vertical Profile of Fluctuating Wind Force (변동풍력의 연직분포를 고려한 건축물의 풍하중 평가)

  • Ryu, Hye-Jin;Shin, Dong-Hyeon;Ha, Young-Cheol
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.7
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    • pp.157-164
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    • 2019
  • The wind tunnel test makes it possible to predict the wind loads for the wind resistant design. There are many methods to evaluate wind loads from data obtained from the wind tunnel test and these methods have advantages and disadvantages. In this study, two of these methods were analyzed and compared. One is the wind load evaluation method by fluctuating displacement and the other is the wind load evaluation method considering vertical profile of fluctuating wind force. The former method is evaluated as the sum of the mean wind load of the average wind force and the maximum value of the fluctuating wind load. The latter method is evaluated as the sum of the mean wind load and maximum value of the background wind load, and the maximum value of the resonant wind load. Two methods were applied to the wind tunnel test to compare the evaluated wind loads according to the two methods, with a maximum difference of about 1.2 times. The wind load evaluated by the method considering vertical profile of the fluctuating wind force (VPFWF) was larger than the wind load evaluated by the method by fluctuating displacement (FD). Especially, the difference of the wind load according to the two methods is large in the lower part of the building and the wind load is reversed at a specific height of the building. VPFWF of evaluating resonant wind loads and background wind loads separately is more reasonable.

Design Shear Force Reduction Factor of Upper Structure in Seismic Base-isolated System Considering Response Acceleration Decrement Effect (면진구조의 응답가속도 감소효과를 고려한 상부구조의 설계전단력 저감계수)

  • Chen, Hao;Oh, Sang-Hoon
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.7
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    • pp.165-170
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    • 2019
  • The structural damage caused by earthquake to the upper structure of seismic base-isolated system can be suppressed effectively because it is designed to concentrate the input energy on the seismic isolation floor. Further, the response acceleration of seismic base-isolated system can be greatly reduced compared to the seismic structure because of the long period, which means that the design shear force of the seismic base-isolated system can be reduced appropriately. However, when the design shear force is determined to be reduced, the design stiffness will decrease, and the response acceleration will increase oppositely. Therefore, for finding the extent to which the design shear force of the upper structure can be reduced, this paper considered the seismic base-isolated structure as the analytical model and proposed the design shear force reduction factor of the base-isolated structure through the dynamic response analysis, while considering the decrement effect of response acceleration. The research result shows that the response acceleration of the isolated the upper structure can be reduced by 50%~70% of the seismic structure under the same design conditions, and the design shear force can be reduced by up to 40%. By increasing the design stiffness over to 1.8 times of the original design value, the design shear force can be reduced to the same extent as the response acceleration can be reduced compared to the seismic structure.

Development of Corner-Supported Auto Climbing Formwork System (강합성코어벽을 활용한 코너지지형 거푸집시스템 개발)

  • Hong, Geon-ho;Shim, Woo-Kyung
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.7
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    • pp.171-178
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    • 2019
  • Auto Climbing Formwork System (ACS) for construction of high-rise building is a construction method for automatically lifting the formwork system supported by the anchor on the pre-constructed concrete wall. It has excellent construction speed and quality, but it has the possibility of structural failure depending on the quality of concrete and also has low economical efficiency due to the use of foreign technology. In order to overcome these problems, this study conducted an optimum design for the development of a new concept of Corner Supported Auto Climbing System (CS-ACS) in conjunction with the development of corner steel-reinforced concrete core wall system. For the design the formwork system, the basic module and structural member compositions were planned, and the structural analysis program was used to analyze the optimum member's cross section and spacing. As a result, the horizontal displacement and the stress of the horizontal members were influenced by the spacing more than the cross-section of the member. On the other hand, vertical members did not affect the displacement and stress of the formwork system. The form tie was very effective in controlling the displacement when adjusting the spacing of the horizontal members, but when the spacing of the form tie is more than 1,500mm, it is analyzed that form tie is yielding in basic module. When the span of the formwork system is more than 30m, it is analyzed that the basic module needs to be changed because of the increase of overall displacement.

Evaluation of Axial Behavior of Strengthened Columns according to Different Peripheral Closed Hoops in Jacket Section (확대단면에서 폐쇄형 외부 띠철근 배근 방법에 따른 보강기둥의 중심축하중 거동 평가)

  • Hwang, Yong-Ha;Yang, Keun-Hyeok;Sim, Jae-Il;Choi, Yong-Soo
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.7
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    • pp.139-146
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    • 2019
  • This study examined the effect of various arrangement methods for forming peripheral closed hoops in the jacket section on the axial behavior of section enlargement strengthening columns. Four types of peripheral closed hoops arranged in the jacket section were prepared as follows: 1) Closed connection of prefabricated bar units (column P); 2) V-clip installation across the overlapped legs of channel-type bars (column V); 3) Use of glass fiber mesh for an alternative of steel bars (column F); and 4) combination of prefabricated bar units and glass fiber mesh (column PF). The V-clip is designed to form the closed hoops in the jacket section using the overlapped channel-type bars, preventing the opening of the channel bar legs. The glass fiber mesh is to examine the feasibility to apply for closed hoops in the jacket section as an alternative for steel bars, considering the easy construction. In the jacket section of all the strengthened columns, V-ties were arranged for supplementary ties, avoiding the interruption of the existing column. The axial stiffness and strength of the strengthened columns were insignificantly affected by the arrangement methods of closed hoops in the jacket section. The axial ductility ratio of the strengthened columns P, V, and PF was enhanced more than twice of that measured in the non-seismic existing column. However, the column F exhibited a lower ductility than the other strengthened columns because of the fracture of the mesh at the ultimate strength of the column. The V-clip approach was favorable to enhance the ductility of the strengthened column, preventing the opening of the legs of channel-type bars.

Greenhouse Gas Emissions from Building Sector based on National Building Energy Database (국가 건물에너지 통합DB 기반 건물부문 온실가스 배출현황)

  • Ji, Chang-Yoon;Choi, Min-Seok;Gwon, Oh-In;Jung, Ha-Rim;Shin, Sung-Eun
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.36 no.4
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    • pp.143-152
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    • 2020
  • This study analyzes in detail greenhouse gas emissions in building sector. To this end, this study used data on building characteristics (including building type, region, and construction year) and monthly energy consumptions (including electricity, city gas, and district heat) for all buildings from 2015 to 2018. These data were collected from the National Building Energy Database and the energy consumptions were converted into greenhouse gas (GHG) emissions. The total amount of GHG emissions from the building sector has increased steadily from 2015 (118.1MtCO2eq.) to 2018 (132.6MtCO2eq.). On the other hand, the more recently constructed buildings had lower GHG intensities. This result shows that strengthening building design criteria was effective on the reduction of GHG emissions in buildings, and that the increased buildings contributed to increasing GHG emissions of the building sector. In addition, sales facilities are thought to have the largest reduction potential as they had the highest amount of GHG emissions and GHG intensity. This study is expected to help establish new policies for GHG reduction in building sector as well as to evaluate the effects of existing policies.