• Title/Summary/Keyword: SC structure

Search Result 553, Processing Time 0.044 seconds

Synthesis, Photovoltaic Properties and Side-chain Effect of Copolymer Containing Phenothiazine and 2,1,3-Benzothiadiazole (Phenothiazine과 2,1,3-Benzothiadiazole을 포함한 Copolymer의 합성 및 Side-chain 치환에 따른 Photovoltaic 특성 연구)

  • Yun, Dae-Hee;Yoo, Han-Sol;Seong, Ki-Ho;Lim, Jeong-Ho;Park, Yong-Sung;Wo, Je-Wan
    • Applied Chemistry for Engineering
    • /
    • v.25 no.5
    • /
    • pp.487-496
    • /
    • 2014
  • In this study, three kinds of polymers based on phenothiazine-benzothiadiazole were synthesized by a Suzuki coupling reaction, and the various side-chains were substituted at the nitrogen of phenothiazine. The optical and electrochemical properties of synthesized polymers were analyzed. The results indicate that their absorption ranged from 300 to 700 nm, and also confirmed the ideal highest occupied molecular orbital (HOMO) energy level was about -5.4 eV with low band-gap energy. Photovoltaic devices were fabricated using a photoactive layer composed of a blended solution of the polymer and $PC_{71}BM$ in ortho-dichlorobenzene The device with P2HDPZ-bTP-OBT containing the branched side-chain and long chain showed the best performance; the maximum power conversion efficiency of this device was 2.4% (with $V_{OC}$ : 0.74 V, $J_{SC}$ : $6.9mA/cm^2$, FF : 48.0%).

Fabrication and Electrochemical Characterization of LSM/GDC based Cathode Supported Direct Carbon Fuel Cells (직접탄소 연료전지용 LSM/GDC 공기극 지지체 제조 및 전기화학 특성 평가)

  • Ahmed, Bilal;Wahyudi, Wandi;Lee, Seung-Bok;Song, Rak-Hyun;Lee, Jong-Won;Lim, Tak-Hyoung;Park, Seok-Joo
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.24 no.3
    • /
    • pp.230-236
    • /
    • 2013
  • In this study, successive coating and co-sintering techniques have been used to fabricate LSM/GDC based cathode supported direct carbon fuel cells. The porous LSM/GDC cathode substrate, dense, thin and crack free GDC and ScSZ layers as bi-layer electrolyte, and a porous Ni/ScSZ anode layer was obtained by co-firing at $1400^{\circ}C$. The porous structure of LSM/GDC cathode substrate, after sintering at $1400^{\circ}C$, was obtained due to the presence of GDC phase, which inhibits sintering of LSM because of its higher sintering temperature. The electrochemical characterization of assembled cell was carried out with air as an oxidant and carbon particles in molten carbonate as fuel. The measured open circuit voltages (OCVs) were obtained to be more than 0.99 V, independent of testing temperature. The peak power densities were 116, 195 and $225mWcm^{-2}$ at 750, 800 and $850^{\circ}C$, respectively.

A Study on Flexural and Shear Behavior of the Structure with Steel Plate Concrete to Reinforced Concrete Member's Connection (철근 콘크리트와 강판 콘크리트 간 이질접합부로 구성된 구조물의 휨 및 전단거동 특성 연구)

  • Hwang, Kyeong Min;Lee, Kyung Jin;Lee, Jong Bo;Won, Deok Hee
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • v.32 no.5A
    • /
    • pp.267-275
    • /
    • 2012
  • This paper describes the experimental study on the structural behavior of the joint plane between a RC(Reinforced Concrete) wall and a SC(Steel Plate Concrete) wall under out-of plane flexural loads and in-plane shear loads. The test specimens were produced with L and I shape to assess efficiently flexural and shear behavior of the structures. In order to consider dynamic loads such as earthquake, cyclic loading tests were carried out. As results of the out-of plane flexural tests, ductile failure mode of vertical bars was shown under a push load and the failure load was more than nominal strength of the specimen. And the latter test was performed to verify the variation which was composition presence of horizontal bars in the SC member. The test results showed that capacity of the specimens was more than their nominal strength regardless of composition presence of horizontal bars.

Fungicidal Activity of 3-(X-Sub. phenyl)-1-(2-furyl)propenone Derivatives (3-(치환(X)-phenyl)-1-(2-furyl)propenone 유도체의 항균활성)

  • Sung, Nack-Do;Kang, Hee-Deog;Maeng, Joo-Yang;Shin, Dong-Rin
    • Applied Biological Chemistry
    • /
    • v.37 no.4
    • /
    • pp.287-294
    • /
    • 1994
  • New 3-phenyl-1-(2-furyl)propenones, 1 and 3-phenyl-1-(2-furyl)-3-thiophenyl-propanone, 2 derivatives were synthesized, and their fungicidal activities in vitro against Botrytis cineria (BC), Valsa ceratosperma (VC), Scelerotium cepivorum (SC) and Phytophthora capsici (PC) were investigated using a generalized structure-activity relationship (SAR). The activity of 1 was superior to those of 2, and nonsubstituent, 1a and chloro group substituent, 1d of E (Syn) conformer were the most effective $(EC_{50}=10{\sim}12\;ppm)$ compound to BC. Antifungal activities were able to predict to depend essentially on the ${\beta}$ carbon and their positive charge from the results that the good correlation $(r^2=0.90)$ was observed between hydrolysis rate constant (logk) of 1 and the electronic parameter $({\sigma})$ of X-substituent on the ${\beta}-phenyl$ ring.

  • PDF

Increased Refolding Yield of Disulfide Bond Bridged Fab-Toxin Homodimers by the Insertion of CH3 Domains

  • Song Jeong-Wha;Won Jae-Seon;Lee Yong-Chan;Choe Mu-Hyeon
    • Journal of Microbiology and Biotechnology
    • /
    • v.16 no.7
    • /
    • pp.1104-1110
    • /
    • 2006
  • Recombinant antibody-toxin is a bifunctional protein that binds and kills a target cell expressing a specific antigen on the surface of the cell, and its structure is chimeric, in which a toxin is fused to an antigen-binding domain such as scFv or Fab. Divalent antibody-toxin molecules showed higher cytotoxicities against cancer cell lines than monovalent molecules. However, the yields of the divalent molecules were very low. In this study, we introduced the CH2, CH3, or CH2-CH3 (=Fc) domain of antibody in the middle of the Fab-toxin between the hinge region of human IgG1 and the toxin domain to increase the yield. The covalently bonded dimer could be formed by three disulfide bridges from cysteine residues in the hinge region. The molecule with the CH3 domain showed about 3-fold higher dimerization yield than previously constructed Fab-toxin molecules, while maintaining the cytotoxic activity comparable to that of scFv-toxin. However, the introduction of CH2 or Fc domain to the same position showed little effect on the dimerization yield. We also observed that the introduction of the CH3 region made it possible to form noncovalently associated dimer molecules.

H-Anim-based Definition of Character Animation Data (캐릭터 애니메이션 데이터의 H-Anim 기반 정의)

  • Lee, Jae-Wook;Lee, Myeong-Won
    • Journal of KIISE:Computing Practices and Letters
    • /
    • v.15 no.10
    • /
    • pp.796-800
    • /
    • 2009
  • Currently, there are many software tools that can generate 3D human figure models and animations based on the advancement of computer graphics technology. However, we still have problems in interoperability of human data models in different applications because common data models do not exist. To address this issue, the Web3D Consortium and the ISO/IEC JTC1 SC24 WG6 have developed the H-Anim standard. However, H-Anim does not include human motion data formats although it defines the structure of a human figure. This research is intended to obtain interoperable human animation by defining the data for human motions in H- Anim figures. In this paper, we describe a syntactic method to define motion data for the H-Anim figure and its implementation. In addition, we describe a method of specifying motion parameters necessary for generating animations by using an arbitrary character model data set created by a general graphics tool.

AFORS HET Simulation for Optimization of High Efficiency HIT Solar Cell (고효율 HIT Solar Cell 제작을 위한 AFORS HET 시뮬레이션 실험)

  • Cho, Soo-Hyun;Heo, Jong-Kyu;Yi, Jun-Sin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2008.11a
    • /
    • pp.450-451
    • /
    • 2008
  • Amorphous silicon Solar cell has n-i-p structure in general, and each layer's thickness and doping concentration are very important factors which are as influential on efficiency of salar cell. Using AFORS HET simulation to get the high efficiency, by adjusting n layer's thickness and doping concentration, p layer's doping concentration. The optimized values are a-Si:H(n)'s thickness of 1nm, a-Si:H(n)r's doping concentration of $2\times10^{20}cm^{-3}$, a-Si:H(p+)r's doping concentration of $1\times10^{19}cm^{-3}$. After optimization, the solar cell shows $V_{oc}$=679.5mV, $J_{sc}$=39.02mA/$cm^2$, FF=83.71%, and a high Efficiency=22.21%. Though this study, we can use this study for planning or manufacturing solar cell which has high efficiency.

  • PDF

Application of Metal Oxide Nanofiber for Improving Photovoltaic Properties of Dye-Sensitized Solar Cells (염료감응형 태양전지의 광전기적 특성 개선을 위한 금속산화물 나노파이버의 응용)

  • Dong, Yong Xiang;Jin, En Mei;Jeong, Sang Mun
    • Clean Technology
    • /
    • v.24 no.3
    • /
    • pp.249-254
    • /
    • 2018
  • In order to improve the photo conversion efficiency (${\eta}$) of dye-sensitized solar cells (DSSCs), the electrospun $TiO_2$, $SiO_2$, $ZrO_2$ and $SnO_2$ nanofibers were added into the hydrothermally prepared $TiO_2$ nanoparticles for application to a photoelectrode for DSSCs. The $TiO_2$ nanofiber added photoelectrode exhibited a higher photo current density ($J_{sc}$) compared to the bare $TiO_2$ nanoparticles, which is caused from acceleration of the transfer of excited electron from dye molecule due to the nanofiber structure. The DSSCs with $SiO_2$ nanofibers shows a higher open circuit voltage ($V_{oc}$) of 0.67 V and the highest photo conversion efficiency was found to be 6.24%.

Fabrication of Silica and Titania Inverse Opals via Supercritical Deposition (초임계 증착법을 통한 실리카와 타이타니아 역 오팔의 제조)

  • Yu, Hye-Min;Lim, Jong-Sung
    • Clean Technology
    • /
    • v.18 no.1
    • /
    • pp.38-42
    • /
    • 2012
  • Photonic crystals (PCs) are highly ordered porous materials which have been much attention because of its potential for controlling the light sauces. There are many methods for synthesizing this kind of materials among them we chose the supercritical deposition. With this method the reactants can easily infiltrate into the complex structure. In this paper, supercritical carbon dioxide ($scCO_2$) was used as a reaction medium, which is known as a sustainable solvent due to its nontoxic and noninflammable characteristics. We coated the colloidal template with metal alkoxide by using $scCO_2$ and then obtained macro-porous inverse opals. The reaction was carried out at $40^{\circ}C$ and 80 bar. We synthesized two different inverse opals which called silica and titania inverse opals by use of tetraethyl orthosilicate (TEOS) and titanium isopropoxide (TTIP) as a precursor, respectively.

Application of Performance Indicators for Digital Library Services Focusing on the Analysis of ISO/DIS 11620 : 2007 (디지털도서관 서비스의 성과지표 측정 및 적용 - ISO/DIS l1620 : 2007을 중심으로 -)

  • Choi, Jae-Hwang;Kwak, Seung-Jin;Kim, Jeong-Taek
    • Journal of the Korean Society for Library and Information Science
    • /
    • v.41 no.3
    • /
    • pp.81-102
    • /
    • 2007
  • The purpose of this study is to examine the ISO/DIS 11620 : 2007(library performance indicators) in terms of structures, objectives, and BSC, and to apply the selected performance indicators to the digital library services for the case of 'B' University in Korea. Standardization of library statistics and of qualify or performance measures for libraries is carried on within ISO in the frame of the TC46/SC8/WG4. While the first edition of ISO 11620 grouped the indicators as to service areas, the ISO/DIS 11620:2007 uses the structure of the balanced scorecard(BSC). For the study, 44 performance indicators are grouped into traditional, hybrid. and digital libraries according to the characteristics of them. Ten selected Performance indicators, which are classified into digital libraries, are verified for the applicability.