• Title/Summary/Keyword: SBR latex

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A Study on the Viscous Properties of Polyvinyl Acetate Emulsion Mixed with SBR, Polyurethane and Epoxy Latex (SBR, 폴리우레탄 및 에폭시 라텍스를 혼합한 폴리초산비닐 에멀젼 수지의 점성에 관한 연구)

  • Choi, Sang-Goo;Suh, Won-Dong;Park, In-Suk
    • Elastomers and Composites
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    • v.33 no.2
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    • pp.83-92
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    • 1998
  • SBR latex, polyurethane latex and epoxy latex were mixed with polyvinyl acetate emulsion in 0~15% (wt.%). For the mixtures, the viscous properties were examined. The viscosity was influenced by the dispersed phase and the chain structures of polymer, and decreased with the rising of temperatures. The viscosity was increased with mixing of epoxy latex, but decreased with addition of SBR latex or polyurethane latex. Thixotropic index was influenced on the size of micelle and hydrogen bond. The thixotropic index was increased with mixing of epoxy latex or polyurethane latex within 5%, but keep up equality over that. The thixotropic index was decreased with mixing of SBR latex within 5%, but keep up equality over that. The relative viscosity were influenced on the activity of molecule and the interference of dispersed phases, was increased with the rising of temperatures. The relative viscosity was decreased with mixing of epoxy latex, but increased with mixing of SBR latex or polyurethane latex.

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A Study on the Properties of Polyvinyl Acetate Emulsion Mixed with SBR, Polyurethane and Epoxy Latex (SBR, 폴리우레탄 및 에폭시 라텍스를 혼합한 폴리초산비닐 에멀젼 수지의 물성에 관한 연구)

  • Suh, Won-Dong
    • Elastomers and Composites
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    • v.33 no.3
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    • pp.149-158
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    • 1998
  • SBR latex, polyurethane latex and epoxy latex were separately mixed with polyvinyl acetate emulsion. The various physical properties were examined for the mixtures. Epoxy mixtures gave a transparent film. Both polyurethane and SBR mixtures showed opaque film with high viscosity. In SBR and polyurethane increase in hardness was dependent on the evaporation rate of water, but in epoxy it was dependent on the degrees of crosslink. Epoxy's showed excellent water-resistance. SBR showed a good flexural strength and impact strength. When vinyl acetate emulsion was mixed with less than 10% latex paper tube showed the ductile fracture, but over latex content 20%, it showed the brittle fracture.

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Study on the Effect of SBR Latex on the Properties of Soil Pavement (SBR Latex를 이용한 흙 포장의 재료특성 연구)

  • Lee, Sang Yum;Hwang, Sung Do;Yang, Sung Lin
    • International Journal of Highway Engineering
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    • v.16 no.5
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    • pp.73-82
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    • 2014
  • PURPOSES : The purpose of this study is to determine the optimum addition rate of SBR latex through the evaluation of durability and strength of SBR latex applied soil pavement. Formerly used materials such as fly ash and cement in soil pavement had resulted in decreased durability due to micro crack by heat of hydration and shrinkage crack in winter. However, that agglutinated polymers help adhesion to aggregate increased comes up with preventing the crack opening when the number of capillary tubes of SBR latex get decreased in the hydration process of cement. Therefore, in this study, it is suggested that the evaluation of the field applicability of soil pavement be conducted through the performance lab test in terms of strength increment, adhesion improvement, and crack resistance based on SBR latex addition rate. METHODS : In order to evaluate the field applicability of soil pavement, SBR latex was added 0 to 3% by 1% increment, with fixed cement contents of 3% and 5%. The resistance of shear failure and crack of soil pavement were evaluated by performing the uniaxial compressive strength test and indirect tensile strength test at -20 and $20^{\circ}C$, respectively. RESULTSCONCLUSIONS : It was found out that from both tests, resistance of shear failure and crack were improved with increment of curing time, and especially more than 2% of SBR latex addition rate and 5% cement content gave better results.

Improvement of Abrasion and Debris on Styrene-Butadiene-Styrene Block Copolymer with Carboxylated SBR Latex and Zinc Oxide (카르복실화 SBR 라텍스와 산화아연을 이용한 SBS의 내마모성과 데브리스(debris) 개선 연구)

  • Lee, Jin Hyok;Bae, Jong Woo;Kim, Jung Su;Yoon, Yoo-Mi;Jo, Nam-Ju
    • Elastomers and Composites
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    • v.48 no.3
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    • pp.225-231
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    • 2013
  • In this study, we observed the effect of carboxylated SBR latex and zinc oxide on styrene-butadiene-styrene( SBS) composites for improving abrasion and debris. SBS composite, which added only silica, showed poor mechanical properties, NBS abrasion, and debris, caused by strong filler-filler interaction of silica. In case of adding carboxylated SBR latex, mechanical properties, NBS abrasion and debris of SBS composite were improved. Because of carboxyl group of carboxylated SBR latex interacted with silanol group of silica. Both carboxylated SBR latex and zinc oxide were added, SBS composite showed highest mechanical properties, NBS abrasion, and debris by forming ion cluster between carboxylated SBR latex and zinc oxide. By FT-IR analysis, ion clusters were confirmed that observed zinc carboxylated group stretch peak at $1550{\sim}1650cm^{-1}$ range. SBS composite, SC-4, showed excellent mechanical properties ; tensile strength $156kgf/cm^2$, elongation 936%, tear strength 59.4kgf/cm ; and excellent abrasion characteristics ; NBS abrasion 338%. Also, debris of SC-4 was minimized and showed wave-shape in fracture surface.

A Study on the Properties of Latex Modified Concrete using Recycled Coarse Aggregate (재생굵은골재를 이용한 라텍스 개질 콘크리트의 특성에 관한 연구)

  • Yoo, Deok-Ryong;Go, Seong-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.5
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    • pp.147-156
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    • 2006
  • This study is purposed to improve the performance of concrete made of recycled coarse aggregate. For this, recycled aggregate concrete was produced with SBR latex, and fluidity, dynamic performance and drying shrinkage were examined. According to the result, with mixing 6% of SBR latex, fluidity having resistance against segregation can be insured and compressive and flexural strength was increased. Especially the increment in terms of flexures was remarkable. In addition to, with above mixing ratio, drying shrinkage was reduced. Therefore there is a strong inference that superior recycled aggregate concrete can be produced with using 6% of SBR latex.

Modification of SBR Latex and its Adhesion Characteristic (SBR Latex의 개질 및 접착특성)

  • Kim, Goo-Ni;Chun, Yong-Chul;Oh, Sang-Taek;Park, Seung-Hyeun;Lee, Chang-Ho;Yoo, Chong-Sun;Min, Byung-Kwon
    • Elastomers and Composites
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    • v.29 no.5
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    • pp.444-452
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    • 1994
  • Emulsion graft copolymerizations of vinyl monomers, butyl acrylate(BA), methyl methacrylate(MMA), 2-ethylhexyl acrylate (EHA), glycidyl methacrylate (GMA), 2-hydroxyethyl methacrylate(HEMA), methacrylonitrile(MAN), dimethylaminoethyl methacrylate(DAMA) or 2-vinyl pyridine(VP), onto carboxyl-terminated SBR latex were carried out under different experimental conditions. In case of synthesizing SBR-g-poly(butyl acrylate), the degree of grafting was increased with increasing the amount of emulsifier, polymerization temperature and the amount of initiator. Pull-out strength of resorcinol-formaldehyde-latex(RFL) adhesives formulated with modified latexes was very higher than that of RFL adhesive formulated with ungrafted latex. When the modified latexes with GMA, HEMA, MAN, DAMA or VP were used, the break occurred at cords. Peel strength of RFL adhesives formulated with SBR-g-poly(GMA), SBR-g-poly(HEMA) or SBR-g-poly(VP) was higher by about 1.3 times than that of RFL adhesives formulated with unmodified SBR against nylon cord and was higher by about 2.0 times against polyester cord.

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Manufacturing of Multi-layer Coated Paper with Eco-friendly Biobinder for Cost Saving (3) - Mill Trial of Eco-friendly Biobinder for Cost Saving - (친환경 원가절감형 바이오바인더를 이용한 다층 도공지 제조 (제3보) - 친환경 원가 절감형 바이오바인더의 공장 적용 실험 -)

  • Lee, Yong Kyu;An, Guk Heon;Kim, Chang Su;Won, Jong Myoung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.5
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    • pp.127-133
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    • 2015
  • Recent worldwide trends are to develop the environmental friendly chemicals and processes in order to reduce the global warming and climate change phenomena. One of similar efforts in paper industry is to substitute the petroleum-based SBR latex by starch-based biobinder. The disadvantage of biobinder found through laboratory scale study was the lower dry pick strength than SBR latex. The objective of this study is to confirm the substitutability of SBR latex with biobinder through mill trial. Although biobinder itself gave lower dry pick strength, it was found that the use of SBR latex and biobinder mixture (50:50) could improve the dry pick strength. The introduction of biobinder into coating binder system improved the opacity of coated paper. Optical properties (brightness and whiteness), ink trapping, print gloss and mottling level of paper coated with biobinder system were similar to those of SBR latex.

Strength Properties of SBR-Modified Concretes Using Ground Granulated Blast-Furnace Slag (고로슬래그 미분말을 이용한 SBR혼입 폴리머 시멘트 콘크리트의 강도특성)

  • ;;Yoshihiko Ohama
    • Journal of the Korea Concrete Institute
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    • v.14 no.3
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    • pp.315-320
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    • 2002
  • The effects of slag content and polymer-binder ratio on the strength properties of the polymer-modified concretes using ground granulated blast-furnace slag and a styrene-butadiene rubber (SBR) latex are examined. As a result, the compressive, tensile and flexural strengths of the SBR-modified concretes using slag increase with increasing polymer-binder ratio and slag content, and maximized at a slag content of 40 %. In particular, the SBR-modified concretes with a slag content of 40 % provide approximately two times higher tensile and flexural strengths than unmodified concretes. Such high strength development is attributed to the high tensile strength of SBR polymer and the improved bond between cement hydrates and aggregates because of the addition of SBR latex.

Development of Water-Permeable Polymer Concrete for Pavement (투수성 포장 폴리머 콘크리트의 개발)

  • 이윤수;주명기;연규석
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.147-152
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    • 2001
  • The purpose of this study is to ascertain the strength properties of water-permeable polymer concretes with SBR latex and redispersible polymer powder. The water-permeable polymer concretes using SBR latex and redispersible polymer powder with water-binder ratio of 29%, polymer-cement ratios of 0, 5, 10, 15 and 20% are prepared, and tested for compressive strength, tensile strength, flexural strength, water permeability. From the test results, improvements in the strength properties of the water-permeable polymer concretes due to the addition of the SBR latex and redispersible polymer powder are discussed.

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fundamental Properties of Water-Permeable Polymer-Modified Concrete (투수성 폴리머 시멘트 콘크리트의 기공적 성질)

  • 이윤수;주명기
    • Journal of the Korea Concrete Institute
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    • v.14 no.3
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    • pp.402-408
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    • 2002
  • The permeable polymer-modified concrete has a lot of internal voids, which has more excellent performance in permeability and durability than asphalt and cement concrete. Therefore, the purpose of this study is to ascertain the strength properties of water-permeable polymer concretes with SBR latex and redispersible polymer powder. The water-permeable polymer concretes using SBR latex and redispersible polymer powder with water-binder ratio of 29 %, polymer-cement ratios of 0, 5, 10, 15 and 20 % are prepared, and tested for compressive strength, splitting tensile strength, flexural strength, water permeablility. From the test results, improvements in the strength properties of the water-permeable polymer concretes due to the addition of the SBR latex and redispersible polymer powder are discussed.