• Title/Summary/Keyword: SALT REDUCTION

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Evaluation of Structural Performance of Reinforced Concrete Slab due to Steel Corrosion (철근이 부식된 철근콘크리트 슬래브의 구조성능 평가)

  • Lee, Chang-Bok;Lee, Kyung-Un;Park, Hyun-Soo;Chung, Lan
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.597-600
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    • 1999
  • Recitly, the use of sea-sand is increasing in the construction due to the rapid reduction of river-sand. In that case, one of the major problem is that a sand salt in sea-sand induce the corrosion of embedded reinforcing bar in concrete. In addition, the deterioration of concrete quality arises a social problem in the durability of reinforced concrete. This research is aimed at providing the data for the control of design method of repair and rehabilitation in the reinforced concrete structure by means of the evaluation of structural performance due to corrosion.

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Dyeability Improvement of Berberine Colorant by Electrostatic Attractive Force of a Reactive Anionic Agent (반응형 음이온화제의 정전기적 인력에 의한 베르베린 색소의 염착성 향상)

  • 김태경;윤석한;임용진;손영아
    • Textile Coloration and Finishing
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    • v.15 no.6
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    • pp.47-54
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    • 2003
  • To be dyed with cationic Berberine, the cotton fiber was modified with reactive anionic agent. The Berberine, a natural cationic colorant of pure yellow, is the major component of Amur Cork tree extract and also can be employed as a natural antimicrobial agent due to its characteristic of cationic quaternary ammonium salt. By LC/MS analysis, it became obvious that the Berberine was contained in Amur Cork tree extract as a major color component. The adsorption of the Berberine on the cotton fabrics pretreated with the anionic agent was greatly increased comparing to that of untreated fabric. Because the anionic agent was colorless, it did not cause unintended color change of the dyeings. The dyed fabric with the Berberine has strong antimicrobial activity showing 99.5% of reduction of bacteria against Staphylococcu aureus.

Studies on L-Glutamic Acid-Producing Bacteria(I) (L-Glutamic Acid 생성균에 관한 연구 1)

  • 홍순우;하영칠;차승희
    • Korean Journal of Microbiology
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    • v.12 no.1
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    • pp.37-51
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    • 1974
  • Three strains which accumulated large quantities of L-hlutamic acid as the chief product of metabolism in the presence of glucose and inorhanic ammonium salt under the aerobic condition sere newly isolated. These strains have the general characters as follows: Gram-positive, short fod-shaped, non-sporulating, non-motile, and facultative anaerobe. A change of cell shates was not almost observed in their life cycles and neither a phenomenon of cell-elongation nor a pleomorphism was recognized in any cases. Together with rigid stability in Gram-stain, these characters as above indicated evidences that newly isolates would belong to genus Brevibacterium clearly differentiated from genus Corynebacterium. At the same time the newly isolates, in addition to nutritional requirement of biotin and thiamine, showed the distinctive character of requirement of special amino acid such as histidine or cysteine for their considerable growth. These physiological characters including nitrates reduction, reaction on milk, and slow formation of acid from sugar also were useful in confirming that these bacteria would be Brevibacterium ammoniagenes.

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An experimental study on surface performance improvement of concrete influencing on resistance to chloride (콘크리트의 표면성능개선이 염소이온투과저항성에 미치는 영향에 관한 실험적 연구)

  • Kim, Jae-Sung;Kang, Suk-Pyo;Hong, Sung-Yoon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.782-785
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    • 2004
  • Salt attack is one of the serious deterioration factor with respect to the durability of concrete structure. Especially, in case of exposed rebar concrete structure in marine environment, corrosion of rebar is accelerated by penetration of $Cl^-$ from exterior. Through this path, volume of corroded rebar is increased about two and half times due to increased inner pressure originated from rust. As a consequence, the overall deterioration of concrete structure, namely, cracks, reduction of adhesive strength and pop-out is followed. In this paper, the effect of structure treatment of concrete on chloride resistance has been investigated. At the same time, the relationship among several characteristics, such as resistance to chloride, water absorption coefficient and surface hardness of concrete has been investigated. It is believed that surface performance improvement by the application of penetrative hardening agent influences on positively water absorption coefficient, surface hardness of concrete and resistance to chloride ion penetration.

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The Effect of Ni Addition on the Sintering Kinetics of Ball-milled Mosi$_2$ Powder Compacts (Ni 첨가가 볼밀링한 MoSi$_2$분말성형체의 소결속도에 미치는 영향)

  • 최선호;홍경태;김영도;문인형
    • Journal of Powder Materials
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    • v.5 no.4
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    • pp.241-249
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    • 1998
  • Sintering kinetics of ball-milled $MoSi_2$ was studied with the addition of Ni. $MoSi_2$ powder with the average particle size of 1 $\mu\textrm{m}$ was obtained from ball-milling of 10 $\mu\textrm{m}$ powder. Small amount of Ni was added to the ball-milled $MoSi_2$ powder by salt solution and reduction method. The powder was compacted into cylindrical shape at 200 MPa and isothermally sintered in a $H_2$ atmosphere at the temperature range of 1100~$1400^{\circ}C$ for 3~600 minutes. The changes of linear shrinkage and sintered density were monitored as a function of sintering time. The microstructure was observed by using optical microscopy and scanning electron microscopy. Phases were identified by X-ray diffratometer and electro-probe micro analysis. Sintering kinetics of Ni-added powder was compared to as-milled powder and the apparent activation energy was calculated from Arrhenius plot.

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Effects of Alloying Elements and Pro-eutectoid Ferrite on Mechanicl Properties in Medium Carbon Steels (중탄소강에서 합금원소 및 초석 페라이트가 기계적성질에 미치는 영향)

  • 심혜정;송형락;남원종
    • Transactions of Materials Processing
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    • v.13 no.4
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    • pp.350-358
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    • 2004
  • The effects of alloying elements on microstructural features and mechanical properties in 0.55%C medium carbon steels were investigated. The samples were austenitized at 105$0^{\circ}C$ for 30min. followed by quenching in a salt bath in the temperature range of 500 ~ $620^{\circ}C$. The addition of Cr resulted in the decrease of the volume fraction of pro-eutectoid ferrite and interlamellar spacing in pearlite and the increase of strength. However, the addition of B caused the increase of the volume fraction of pro-eutectoid ferrite. Reduction of area and Charpy impact values were influenced by the combined effect of microstructural features, such as the volume fraction of pro-eutectoid ferrite, interlamellar spacing and the thickness of lamellar cementite in pearlite.

The Determination of TRC using an Electrochemical Method (I: Au electrode) (전기화학적 방법의 TRC(Total residual chlorine) 측정 연구(I: Au전극 이용))

  • Lee, JunCheol;Pak, DaeWon
    • Journal of Korean Society on Water Environment
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    • v.30 no.3
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    • pp.298-303
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    • 2014
  • We measured by electrochemical method for TRC (total residual chlorine) in ocean. From the results of Au electrode used for working electrode through cyclic voltammetry test, we obtained charge in voltage ranged from 0.0V-1.0V, and analyzed correlations of charge for TRC. Reduction peak TRC was investigated to be approximately 0.65 V vs. Ag/AgCl, and in the case that salt concentrations and temperatures in ocean appeared different, charge was analyzed for being different in the same TRC. However, in the case that each condition was constant, charge was measured at highly correlations for TRC.

Low Temperature Dyeing Process by Intercellular diffusion through Cell Membrane Complex Modification of Wool. - Technology based on CSIRO and ICI (양모의 저온 염색 소개 - Sirolan LTD Process from ICI)

  • 윤일남
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2001.11a
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    • pp.3-11
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    • 2001
  • Fundamental studies at the CSIRO division of Wool technology and ICI on the diffusion of dyes into wool〔1,2〕have let to development of a new approach to wool dyeing. In this method, the cell membrane complex of wool is modified before dyeing by treatment under mildly alkaline conditions with a special chemicals. Wool pretreated with ethoxylated quaternary ammonium salt has an increased rate of dyebath exhaustion and dye penetration early in the dyeing cycle. This enables the treated material to be dyed below the boil for a similar time to the conventional cycle. This technique can be used on untreated and shrinkresist-treated wool and wool/nylon blends. In addition to good macro-levelness and excellent coverage of tippiness, the low temperature dyeing process give higher exhaustion levels of dyestuffs and insect-resist agent and hence cleaner effluent liquors, compared with conventional dyeing process. Low Temperature Dyeing process cause significantly less fiber damage than conventional way. The reduction in damage is reflected in improved processing performance of the dyed wool.

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Inhibition of Rebar Corrosion by Carbonate and Molybdate Anions

  • Tan, Y.T.;Wijesinghe, S.L.;Blackwood, D.J.
    • Corrosion Science and Technology
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    • v.16 no.4
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    • pp.167-174
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    • 2017
  • Bicarbonate/carbonate and molybdate anions have been characterized for their inhibitive effect on pitting corrosion of carbon steel in simulated concrete pore solution by using electrochemical tests such as electrochemical impedance (EIS) and linear polarization (LP). It was revealed that bicarbonate/carbonate has a weak inhibitive effect on pitting corrosion that is approximately one order of magnitude lower compared to hydroxide. Molybdate is effective against pitting corrosion induced by the concentration of chloride as low as 113 mM and can increase the pitting potential of a previously pitted sample to the oxygen evolution potential by the concentration of molybdate as much as 14.6 mM only. The formation of a $CaMoO_4$ film on the surface hinders the reduction of dissolved oxygen on the steel surface, reducing corrosion potential and increasing the safety margin between corrosion potential and pitting potential further. In addition, pore-plugging by $FeMoO_4$ as a type of salt film within pits increases the likelihood of repassivation.

Preparation and Stabilization of Ag Nanoparticles in 1-Amino-4-methylpiperazine

  • Park, Heon-Soo;Shin, Ueon-Sang;Kim, Hae-Won;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.32 no.1
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    • pp.273-276
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    • 2011
  • Uniform Ag nanoparticles (< 10 nm) were effectively prepared in 1-amino-4-methylpiperazine as a solvent with multiple functions including reduction and stabilization. An Ag-complex such as $Ag_2(ehac)_2(eha)_2$ (ehac = 2-ethylhexylammonium carbamate; eha = 2-ethylhexylamine) was used as an Ag-precursor, whereas the usage of a salt such as $AgNO_3$ showed the formation of Ag nanoparticles in larger and irregular size (30 - 500 nm). The Ag nanoparticles (< 10 nm) prepared by using the Ag-complex could also be effectively stabilized by 1-amino-4-methylpiperazine. Transmission electron micrographs confirmed that the Ag particles were spherical and in the nanometer size.