• Title/Summary/Keyword: SALT REDUCTION

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Synthesis of Nanostructured Fe-Co Alloy Powders from Metal Salts

  • Lee, Young-Jung;Lee, Jea-Sung;Seo, Young-Ik;Kim, Young-Do
    • Journal of Powder Materials
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    • v.13 no.5 s.58
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    • pp.336-339
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    • 2006
  • Magnetic properties of nanostructured materials are affected in complicated manner by their microstructure such as pain size (or particle size), internal strain and crystal structure. Thus, studies on the synthesis of nanostructured materials with controlled microstructure are necessary fur a significant improvement in magnetic properties. In the present work, nanostructured Fe-Co alloy powders with a grain size of 50 nm were successfully fabricated from the powder mixtures of (99.9% purity) $FeCl_2$ and $CoCl_2$ by chemical solution mixing and hydrogen reduction.

Polarographic Study of Nitrosophenylhydroxylamine (Polarography에 依한 Nitrosophenylhydroxylamine에 關한 硏究)

  • Jung-Eui Hwang;Chong-Jae Chung;Moo-Young Son
    • Journal of the Korean Chemical Society
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    • v.13 no.4
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    • pp.303-307
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    • 1969
  • The ammonium salt of Nitrosophenylhydroxylamine "called cupferron", is a well-known analytical reagent, which precipitates a great number of metal ions in acid medium. The electrode reduction velocities of cupferron at droping mercury electrode in various supporting electrolytes were measured by Delahay method. The free energy of activation and transfer coefficient for a given electrode reaction are computed from the corresponding current-voltage curve. The number of electrons involved in the rate determining step of the reduction of cupferron is calculated for solutions of various pH.

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Perchlorate Removal by Perchlorate Reducing Bacteria Consortium in a Continuous Bioreactor (연속생물반응기에서 perchlorate 환원 세균에 의한 perchlorate의 제거)

  • Ryu, Hee-Wook
    • KSBB Journal
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    • v.27 no.1
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    • pp.28-32
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    • 2012
  • In this study, the treatment ability of the wastewater containing perchlorate by non-salt tolerant perchlorate reducing bacterial consortium (N-PRBC) was evaluated in a continuous stirred tank bioreactor (CSTR). To obtain the optimal operating condition the bioreactor was operated with the different wastewater empty bed retention time (EBRT). The treatment performance in the bioreactor could be maintained at 100 $mg-ClO_4{^-}L^{-1}$ up to a EBRT of 3 h, and the removal capacity in the CSTR was about 3.3 times higher than that in a batch operation. With a decrease from 9 h to 2 h in a EBRT, the volumetric perchlorate reduction rate was increased from 11.1 $mg-ClO_4{^-}L^{-1}h^{-1}$ to 50.0 $mg-ClO_4{^-}L^{-1}h^{-1}$, and the specific perchlorate reduction rates were increased from 3.01 $mg-ClO_4{^-}g-DCW^{-1}h^{-1}$. In conclusion, the treatment capacities in a CSTR were much better than those obtained in a batch operation.

Dyeing of Cotton with Rosemary Extract (로즈마리 추출물틀 이용한 면의 염색)

  • 신윤숙;오유정
    • Journal of the Korean Society of Clothing and Textiles
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    • v.26 no.3_4
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    • pp.485-491
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    • 2002
  • Dyeing properties of rosemary colorants on cotton fabrics were investigated. Effect of dyeing conditions on dye uptake and effect of mordanting and cationizing on dye uptake, color change and colorfastness were explored. Also, antimicrobial activity of rosemary colorants was ascertained and further effect of cationizing on antimicrobial activity was investigated. Affinity of rosemary colorants to cotton fiber was considerably low, and its isotherm adsorption curve was Freundlich type, indicating that hydrogen bonding was involved in the adsorption of rosemary colorants to cotton fiber. The cotton fabrics showed generally high colorfastness except fastness to washing and light. The cationized cotton with Cationon UK(quarterly ammonium salt) showed higher dye uptake and shorter dyeing time, compared with the untreated cotton. The cationized cotton showed good colorfastness to washing, perspiration and rubbing. Antimicrobial activity of rosemary colorfastness was confirmed. The cationized cotton itself showed high bacterial reduction rate. For cationized and dyed samples, as dye uptake increased, bacterial reduction rate was decreased slightly.

Attempts on the Preparation of Lithium Trialkoxyborohydrides. Stability and Stereoselective Reduction of Cyclic Ketones

  • Cha, Jin-Soon;Kim, Jin-Euog;Lee, Jae-Cheol;Yoon, Mal-Sook
    • Bulletin of the Korean Chemical Society
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    • v.7 no.1
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    • pp.66-69
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    • 1986
  • The reaction of potassium trialkoxyborohydrides of varying steric requirements with lithium chloride in tetrahydrofuran(THF) was examined in detail to establish the generality of this synthesis of the corresponding lithium trialkoxyborohydrides. The metal ion exchange reaction between potassium triisopropoxyborohydride and lithium chloride in THF proceeded instantly at room temperature and the corresponding lithium salt was very stable toward disproportionation. However, for R = s-Bu, t-Bu and 2-methylcyclohexyl, with increasing steric requirement, the lithium derivatives were unstable and thus dissociated into $(RO)BH_3^-\;and\; (RO)_4B^-$. The stereoselectivity of lithium triisopropoxyborohydride(LIPBH) in the reduction of representative cyclic ketones was examined and compared with that of the potassium derivative.

Adaptive Switching Filtering Algorithm for SAP noise (SAP 잡음 제거를 위한 적응적 스위칭 필터링 알고리즘)

  • Kim, Donghyung
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.18 no.1
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    • pp.25-35
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    • 2022
  • The SAP(salt-and-pepper) noise changes the pixel value to the maximum and minimum values of the dynamic region of the pixel. For this reason, unlike white Gaussian noise, SAP noise can predict the ratio of noise relatively easily. Because the condition of the neighboring pixels that can be referenced changes according to the noise ratio, it is necessary to apply different noise reduction methods according to the noise ratio. This paper proposes an adaptive switching filtering algorithm which can eliminates the SAP noise. It consists of two phases. It first detects the location of the SAP noise and calculates the noise ratio. After that, the image is reconstructed using different methods depending on which of the three sections the calculated noise ratio belongs to. As a result of the experiment, the proposed method showed superior objective and subjective image quality compared to the previous methods such as MF, AFSWMF, NAMF and RWMF.

Electrochemical extraction of uranium on the gallium and cadmium reactive electrodes in molten salt

  • Valeri Smolenski;Alena Novoselova
    • Nuclear Engineering and Technology
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    • v.56 no.1
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    • pp.42-47
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    • 2024
  • The electrochemical extraction of uranium in ternary low melting LiCl-KCl-CsCl eutectic on inert and reactive electrodes via different electrochemical techniques was investigated. It was established that the electrochemical reduction process of U(III) ions on the inert W electrode was irreversible and proceeded in one stage. On reactive liquid Ga and liquid Cd electrodes the reduction of uranium ions took place with the considerable depolarization with the formation of UGa2, UGa3 and UCd11 intermetallic compounds. Thermodynamic characteristics of uranium compounds and alloys were calculated. The conditions for the extraction of uranium from the electrolyte in the form of alloys on both liquid reactive electrodes via potentiostatic electrolysis were found.

Development of low-carbon eco-friendly concrete using super-sulfated cement (고황산염 시멘트를 활용한 저탄소 친환경 콘크리트 개발)

  • Ki, Jun-Do;Lee, Sang-Hyun;Kim, Young-Sun;Jeon, Hyun-Soo;Seok, Won-Kyun;Yang, Wan-Hee
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.199-200
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    • 2023
  • Eco-friendly concrete contains only 5% of cement yet achieves equal or greater strength compared to conventional concrete, reducing salt-attack impact and hydration heat by more than 30% and ensuring higher construction quality for underground structures. Furthermore, eco-friendly concrete can reduce up to 90% of carbon dioxide emissions compared to traditional concrete, enabling a reduction of approximately 6,000 tons of carbon emissions for 1,000 of apartment units construction. This is equivalent to planting around 42,000 trees

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Evaluation of Boar Sperm Viability by MTT Reduction Assay in Beltsville Thawing Solution Extender

  • Byuna, J.W.;Choo, S.H.;Kim, H.H.;Kim, Y.J.;Hwang, Y.J.;Kim, D.Y.
    • Asian-Australasian Journal of Animal Sciences
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    • v.21 no.4
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    • pp.494-498
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    • 2008
  • MTT (3-(4, 5-dimethyl thiazol-2-yl)-2, 5-diphenyl tetrazolium bromide) reduction assay is a method that validates the viability of an active cell. Dehydrogenase in mitochondria converts yellow colored insoluble tetrazolium salt to purple colored water-soluble formazan. Sperm also have mitochondria in the midpiece, therefore sperm viability could be evaluated by MTT reduction assay. Several studies have already demonstrated the capability of application of the MTT reduction assay to sperm of several species in Hepes-BSA buffer. Because most liquid semen was diluted in extender like BTS (Beltsville Thawing Solution), Modena or Androhep when it is used or transferred, semen needed another dilution in Hepes-BSA buffer to assess sperm viability. In this study, we evaluated boar sperm viability especially in BTS extended semen and compared the efficiency of this test with eosin-nigrosin staining. We used the fresh BTS extended semen from a local A.I center. Semen sample was diluted to $3.0{\times}10^7$ sperms/ml in BTS. The rates of formazan production were measured in 96-well microtiter plates immediately and 1h after incubation at $17^{\circ}C$ using a spectrophotometer at wave length 560 nm. Simultaneously, split samples of the same semen were tested, using eosin-nigrosin staining to compare the efficiency of the MTT assay of sperm viability in BTS. The correlation between the results of these tests was calculated using Student-t test and ANOVA. The results revealed a strong correlation between the results of MTT reduction rate and the results that were simultaneously determined by eosin-nigrosin staining at 1 h. In conclusion, the MTT reduction test was an effective and simple method to validate sperm viability and it could be used as a simple tool to evaluate sperm viability in the local A.I center and laboratory.

An Electrochemical Reduction of TiO2 Pellet in Molten Calcium Chloride (CaCl2 용융염에서 TiO2 펠렛의 전기화학적 환원반응 특성)

  • Ji, Hyun-Sub;Ryu, Hyo-Yeol;Jeong, Ha-Myung;Jeong, Kwang-Ho;Jeong, Sang-Mun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.2
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    • pp.97-104
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    • 2012
  • A porous $TiO_2$ pellet was electrochemically converted to the metallic titanium by using a $CaCl_2$ molten salt system at $850^{\circ}C$. Ni-$TiO_2$ and graphite electrodes were used as cathode and anode, respectively. The electrochemical behaviour of $TiO_2$ pellet was determined by a constant voltage control electrolysis. Various reaction intermediates such as $CaTiO_3$, $Ti_2O$ and $Ti_6O$ were observed by XRD analysis during electrolysis of the pellet. Once $TiO_2$ pellet was converted to a porous metallic structure, the porous structure disappeared by sintering and shrinking with increasing the reaction time at high temperature.