• Journal of Welding and Joining
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• v.32 no.3
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• pp.102-107
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• 2014

Boiler equipment in power plant is always being operated in harsh conditions and severely exposed to the extreme environment of high temperature. Therefore periodically the state of devices should be checked, diagnosed, and analyzed to ensure the reliability of the equipment. Traditionally, such a diagnosis is based one or two physical properties of the sample taken from the equipment like hardness, microstructure, etc.. However, to enhance the confidence of the diagnosis, it is necessary to synthesize those properties together. This paper is to propose such a synthetic procedure for SA213-T12(1Cr-0.5Mo) which was developed to be used in $565^{\circ}C$ below condition. Creep test and accelerated degradation test were performed simultaneously, and the physical properties such as microstructure, tensile strength, yield strength, hardness, and indentation properties were measured. This paper proposes a method of determining the remaining life by quantitative comparison. It will provide the basis of evaluating life assessment more objective and reliable.

• Korean Chemical Engineering Research
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• v.61 no.3
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• pp.419-425
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• 2023

This paper presents the research results of analyzing the high-temperature corrosion characteristics of three currently commercialized heat exchanger tube materials under actual operating conditions of a biomass power plant. In order to precisely analyze the high-temperature corrosion characteristics of these materials, a high-temperature corrosion evaluation device was installed in the power plant equipment, which allows for adjusting the surface temperature of the heat exchanger tubes. Experiments were conducted for approximately 300 hours under various temperature and operating conditions. In this study, the commercialized heat exchanger tube materials used were SA213T12, SA213T22, and SA213T91 alloys. In order to objectively analyze the high-temperature corrosion characteristics of each material, an international standard-based process to remove corrosion products was applied to obtain the weight change of the specimens, and the average thickness loss and corrosion rate were derived. Thus, the high-temperature corrosion results for each condition were quantitatively compared and analyzed. In addition, in order to increase the reliability of the high-temperature corrosion evaluation method introduced in this study, the surface and cross-sectional corrosion of the specimens were confirmed by using scanning electron microscopy and energy-dispersive X-ray analysis. Based on these analysis results, it was found that the corrosion resistance of the commercial heat exchanger materials increases as the content of chrome and nickel in the composition increases. Additionally, it was found that the corrosion phenomenon is rapidly accelerated as the surface temperature increases. Finally, the replacement period (lifetime) of the heat exchanger tubes under each condition could be inferred through this study.

• Clean Technology
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• v.24 no.4
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• pp.339-347
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• 2018

In order to cope with environmental problems and climate change caused by fossil fuels, renewable energy supply is increasing year by year. Currently, waste energy accounts for 60% of renewable energy production. However, waste has a lower calorific value than fossil fuels and contains various harmful substances, which causes serious problems when applied to power generation boilers. In particular, the chlorine in the waste fuel increases slagging and fouling of boiler heat exchangers, leading to a reduction in thermal efficiency and the main cause of high temperature corrosion, lowering facility operation rate and increasing operating cost. In this study, the high temperature corrosion experiments of superheater materials (ASME SA213/ASTM A213 T2, T12 and T22 alloy steel) by alkali chlorides were conducted, and their corrosion characteristics were analyzed by the weight loss method and SEM-EDS. Experiments show that the higher the temperature and chloride content, the more corrosion occurs, and KCl further corrodes the materials compared to NaCl under the same condition. In addition, the higher the chromium content of the material, the better the corrosion resistance to the alkali chlorides.

• Journal of Welding and Joining
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• v.28 no.1
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• pp.41-46
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• 2010

The low alloy-steel material(1.0Cr-0.5Mo, SA213T12), which has widely been used for the waterwall tube in the conventional power plant, do not have enough creep rupture strength for waterwall tubes of the Ultra-supercritical(USC) boilers. According to this reason, the high-strength low alloy-steel(2.25Cr-1.0Mo, SA213T22) has newly been adopted for the waterwall tube in the USC boilers. This paper presents failure analysis on weld-joint of the waterwall tubes in USC boilers. Visual inspections were performed to find out the characteristics of the fracture. Additionally both microscopic characteristics and hardness test were carried out on failed tube samples. Failures seem to happen mainly because the welding process has not been conducted strictly.(preheating, P.W.H.T and so forth). Thus, this paper has the purpose to describe the main cause of the poor welding process and to explain how to prevent similar failures in those weld-joints.