• Title/Summary/Keyword: S2-

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Fabrication of large scale $Cu_2$S/CdS solar cells prepared by spray pyrolysis (Spray pyrolysis 방법에 의한 넓은 면적의 $Cu_2$S/CdS 태양전지의 제작)

  • 차덕준;고정곤;정상조;남승재;김광윤;전용기
    • Journal of the Korean Vacuum Society
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    • v.5 no.4
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    • pp.341-347
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    • 1996
  • We fabricated the effective $Cu_2S$/CdS solar cells with large area by a spray pyrolysis method. In preparation process, we investigated the process parameters which directly influenced the efficiency of solar cell, such as the grid contact for electrodes, the temperature condition of CdS spray and the junction characteristics of $Cu_2S$ layer, by scanning electron microscope(SEM), x-ray diffraction(XRD) and temperature dependent optical absorption and photoconductivity. The $Cu_2S$/CdS solar cell with area of 1$\textrm{cm}^2$ showed the efficient of 3.15% under air mass 2(AM2) spectrum irradiation with 75mW/$\textrm{cm}^2$.

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Synthesis of $\pi$-Allyl-type Cobalt, Palladium, Platinum Complexes Having a $C_2$-Chiral Ligand ($C_2$ 손대칭 리간드를 배위하는 $\pi$-Allyl-Cobalt, Palladium, Platinum 착물의 생성)

  • Uhm, Jae Kook;Lee, Jong O;An, Hee Won
    • Journal of the Korean Chemical Society
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    • v.42 no.2
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    • pp.177-183
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    • 1998
  • By the reactions of a $C_{2}$-chiral ligand, (+)-11S,12S-bis[2,2'-(diphenylphosphino)benzanilido]-9,10-dihydro-9,10-ethanoanthracene(6) with $[\pi-allyl chloroplatinum(II)]_4$, and $CpCo(CO)_2$ respectively, three new complexes, ($\pi$-allyl)platinum(II)(+)-11S,12S-bis[2,2'-(diphenylphosphino)benzanilido]-9,10-dihydro-9,10-ethanoanthracene perchlorate(1), ($\pi$-allyl)platinum(II)(+)-11S,12S-bis[2,2'-(diphenylphosphino)benzanilido]-9,10-dihydro-9,10-ethanoanthracene chloride(2), ($\eta^5$-cyclopentadienyl)cobalt(I)-(+)-11S,12S-bis[2,2'-(diphenylphosphino)benzanilido]-9,10-dihydro-9,10-ethanoanthracene(3) were prepared. $\eta^3$-Cyclohexenyl)palladium(II)1,2-bis(diphenylphosphino)ethane perchlorate(4) was obtained by the reaction of ($\eta^3$-cyclohexenyl)palladium(II) chloride dimer with a symmetric ligand, 1,2-bis(diphenylphosphino)ethane and lithium perchlorate. These complexes were identified by NMR-, IR-, and Mass-Spectrophotometers and elemental analyzer.

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Climate Change Impacts on Paddy Irrigation Requirement in the Nakdong River Basin (기후변화가 낙동강 권역의 논 관개용수 수요량에 미치는 영향)

  • Chung, Sang-Ok
    • Journal of The Korean Society of Agricultural Engineers
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    • v.51 no.2
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    • pp.35-41
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    • 2009
  • The impacts of climate change on paddy irrigation requirements for Nakdong river basin in Korea have been analyzed. The HadCM3 model outputs for SRES A2 and B2 scenarios and International Water Management Institute $10'{\times}10'$ pixels observed data were used with kriging method. Maps showing the predicted spatial variations of changes in climate parameters and paddy irrigation requirements have been produced using the GIS. The results showed that the average growing season temperature was projected to increase by $2.2^{\circ}C$ (2050s A2), $0.0^{\circ}C$ (2050s B2), $3.7^{\circ}C$ (2080s A2) and $2.9^{\circ}C$ (2080s B2) from the baseline (1961-1990) value of $21{\circ}C$. The average growing season rainfall was projected to increase by 15.2% (2050s A2), 24.2% (2050s B2), 41.4% (2080s A2) and 16.7% (2080s B2) from the baseline value of 900 mm. Average volumetric irrigation demands were projected to decrease by 3.7% (2050s A2), 7.0% (2050s B2), 10.2% (2080s A2) and 1.4% (2080s B2) from the baseline value of $1.25{\times}10^9\;m^3$. These results can be used for the agricultural water resources development planning in the Nakdong river basin for the future.

MORITA EQUIVALENCE FOR HOMOGENEOUS C*-ALGEBRAS OVER LOWER DIMENSIONAL SPHERES

  • Park, Chun-Gil
    • Journal of the Chungcheong Mathematical Society
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    • v.19 no.2
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    • pp.111-121
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    • 2006
  • All d-homogeneous $C^*$-algebras $T^d$ over $\prod^{s_4}S^4{\times}\prod^{s_2}S^2{\times}\prod^{s_3}S^3{\times}\prod^{s_1}S^1$ are constructed. It is shown that $T^d$ are strongly Morita equivalent to $C(\prod^{s_4}S^4{\times}\prod^{s_2}S^2{\times}\prod^{s_3}S^3{\times}\prod^{s_1}S^1)$.

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Crystal Structure and Magnetic Properties of $(LaS)_xCrS_2(x{\approx}1.20)$ ($(LaS)_xCrS_2(x{\approx}1.20)$의 결정구조와 자기적 특성)

  • Jo, Nam-Ung;Yu, Gwang-Su;Jeong, Hyeong-Jin
    • Korean Journal of Materials Research
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    • v.4 no.6
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    • pp.704-709
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    • 1994
  • The $(LaS)_xCrS_2(x \approx 1.20$) of the incommensurate misfit layer was systhesized from reactant mixture of$La_S_3$,Cr and S at 1273K. Powder X-ray diffration of $(LaS)_xCrS_2(x \approx 1.20$) was indexed as a complex structure consisted with a monoclinic LaS-sublattice, a triclinic $CrS_{2}$-sublattice and their superlattice. The temperature dependence of sublattice dimension was investigated by the X-ray diffraction analysis at low temperature. The magnetic susceptibility of $(LaS)_xCrS_2(x \approx 1.20$) was measured between 77K and room temperature using a Faraday balance method. $(LaS)_xCrS_2(x \approx 1.20$) was paramagnetic on a $\sigma$-H plot at room temperature. The observed effective magnetic moment( p dr) was in fair agreement with the value calculated by spin-only contribution for $Cr^{3+}$ and spin and orbital contribution for $La^{3+}$.

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Enhanced Photoelectrochemical Reaction of MoS2 Nanosheets Vertically Grown on TiO2 Nanowires (MoS2 나노시트의 TiO2 나노선에 수직 성장을 통한 광전기화학반응 향상)

  • Seo, Dong-Bum;Kim, Eui-Tae
    • Korean Journal of Materials Research
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    • v.31 no.2
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    • pp.92-96
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    • 2021
  • We report the growth and enhanced photoelectrochemcial (PEC) water-splitting reactivity of few-layer MoS2 nanosheets on TiO2 nanowires. TiO2 nanowires with lengths of ~1.5 ~ 2.0 ㎛ and widths of ~50~300 nm are synthesized on fluorine-doped tin oxide substrates at 180 ℃ using hydrothermal methods with Ti(C4H9O)4. Few-layer MoS2 nanosheets with heights of ~250 ~ 300 nm are vertically grown on TiO2 nanowires at a moderate growth temperature of 300 ℃ using metalorganic chemical vapor deposition. The MoS2 nanosheets on TiO2 nanowires exhibit typical Raman and ultraviolet-visible light absorption spectra corresponding to few-layer thick MoS2. The PEC performance of the MoS2 nanosheet/TiO2 nanowire heterostructure is superior to that of bare TiO2 nanowires. MoS2/TiO2 heterostructure shows three times higher photocurrent than that of bare TiO2 nanowires at 0.6 V. The enhanced PEC photocurrent is attributed to improved light absorption of MoS2 nanosheets and efficient charge separation through the heterojunction. The photoelectrode of the MoS2/TiO2 heterostructure is stably sustained during on-off switching PEC cycle.

Consideration on $H_2S$ Sensing Mechanism of CuO-$SnO_2$ Thick Film through the Analysis of the Temperature-Electrical Resistance Characteristics (온도-전기저항 특성 해석을 통한 CuO-$SnO_2$ 후막 소자의 $H_2S$ 감지기구 고찰)

  • 유도준;준타마키;박수잔;노보류야마조에
    • Journal of the Korean Ceramic Society
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    • v.33 no.4
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    • pp.379-384
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    • 1996
  • The H2S sensing mechanism of CuO-SnO2 was confirmed by analyzing the electrical-resistance variation with temperature under an H2S atmosphere. While the resistance of CuO-SnO2 thick film at N2+H2S atmosphere was almost invariant with change in temperature it increased with increasing temperature for air +H2S atmos-phere. This behavior was analyzed using an equation derived from a basic assumption based on the H2S sensing mechanism proposed before. the experimental results are sufficiently explained with the equation derived which showed that the H2S sensing mechanism was reasonable. The equation also gave a detailed analysis and physical meaning to the behavior of the resistance variation with change in H2S concentration.

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Antigenic Pproperties of preS2 Region of Hepatitis B Virus Envelope Proteins (B형 간염바이러스 표면단백질 중 preS2 부위의 항원적 특성)

  • 이기녕;이상철;권기선;정홍근;유명희
    • Korean Journal of Microbiology
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    • v.28 no.1
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    • pp.6-12
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    • 1990
  • The preS2 wequence of an adr hepatitis B virus was cloned and expressed in Escherichia coli as a $\beta$-galactosidase fusion polypeptide. Recombinant preS2 product interacted with the preS2-specific monoclonal antibody H8 which was induced by surface antigen particles isolated from a Korean gepatitis patient. The H8 showed only a minor cross-reactivity with recombinant preS2 product of adw2 subtype. Determination of nucleotide sequence of the adr preS2 revealed that twelve amino acid residue substitutions between adr and adw2 subtype sequences. The antigenic determinant to H8 must include some of these differences.

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Stereospecific Coordination of 2,2$^\prime$-Diaminobiphenyl in the Square Planar Platinum(Ⅱ) Comdlexes

  • Jun, Moo-Jin;Choi, Sung-Rack
    • Bulletin of the Korean Chemical Society
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    • v.5 no.6
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    • pp.237-240
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    • 1984
  • 2,2'-Diaminobiphenyl platinum (II) complexes of optically active trans-1,2-diaminocyclohexane and 1,2-diaminopropane, [Pt(S,S-chxn)(dabp)]Cl2, [Pt(R,R-chxn)(dabp)]$C_{12}$, [Pt(S-pn)(dabp)]$C_{l2}$, and [Pt(R-pn)(dabp)]Cl2, where S,S-chxn and R,R-chxn are, respectively, S and R isomers of trans-1,2-diaminocyclohexane, and S-pn and R-pn are, respectively, S and R isomers of 1,2-diaminopropane, and dabp the 2,2'-diaminobipheny, have been prepared. The dabp ligand has been found to take the $=delta$ conformation in the S,S-chxn and S-pn platinum (II) complexes, while it takes the $\lambda$ conformation in the R,R-chxn and R-pn platinum (II) complexes.

The Quality characteristics of sponge cake added with the ingredients of Sagoonja-Tang (사군자탕(四君子湯) 재료를 첨가한 스폰지 케이크의 품질특성)

  • Nam, Hae-Young
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.4
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    • pp.1066-1075
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    • 2017
  • This study was carried out to determine the functional works and basic ingredients of Sagoonja-Tang on sponge cake. The experimental groups consisted of 6% mixtures of five (Ed-confirm the number) kinds powders : S1 for Sagoonja-Tang powder, S2 for Panax ginseng, S3 for Poria cocos, Koidz, S4 for Atractylodes macrocephala, and S5 for Glycyrrhiza uralensis Fisch. The volume of sponge cake somewhat decreased after adding the ingredients, and the volume differences in order from highest to lowest, were control>S1>S3>S2>S4>S5. In the microbiological quality test, viable cell counts were high in control groups of sponge cake, and the numbers of viable cell for control sponge cake reached to $9{\times}10^7CFU/g$ on the 7th day of storage, and decreased to $2.5{\times}10^5CFU/g$ on the 10th day of storage. All sponge cakes added with ingredient's powder showed pretty low viable cell counts. Especially, the group S5 showed the lowest counts of $1.2{\times}10^2CFU/g$ on the 7th day of storing. In the texture analyses of sponge cake, All groups showed higher degree of hardness, gumminess and chewiness than SC. The antioxidative activity of the Sagoonja-Tang's ingredients was measured. The POV value measured was S5>S4>S3>S2 >S1>control in order of highest to lowest. In sensory test, the overall acceptability of sponge cake was from highest to lowest S3>SC S2>S1>S5>S4.