• Title/Summary/Keyword: S-MMA

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The Preparation of Multi-walled CNT-PMMA Nanocomposite

  • Seo, D.W.;Yoon, W.J.;Park, S.J.;Jo, M.C.;Kim, J.S.
    • Carbon letters
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    • v.7 no.4
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    • pp.266-270
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    • 2006
  • Multi-walled carbon nanotube-poly methyl methacrylate (MWNT/PMMA) nanocomposite has been prepared by in situ polymerization of MMA dispersed with MWNTs. The MWNTs were functionalized by nitric acid and sulfuric acid treatment, and this was confirmed by FTIR spectrometer. The solution mixture of MWNTs and MMA was partially polymerized at $80^{\circ}C$, followed by the addition of AIBN and polymerization at $50^{\circ}C$. The MWNT-PMMA composite was prepared by casting the pre-polymer on the glass plate, and the optical properties have been studied using UV-vis spectrometer. The acid treated MWNTs were well dispersed in MMA with fairly good dispersion stability, while flocculation and sedimentation was observed from raw MWNTs in MMA.

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Efficacy of Living Donor Liver Transplantation in Patients with Methylmalonic Acidemia

  • Jang, Jae Guk;Oh, Seak Hee;Kim, Yu Bin;Kim, Seo Hee;Yoo, Han-Wook;Lee, Beom Hee;Namgoong, Jung-Man;Kim, Dae Yeon;Kim, Ki-Hun;Song, Gi-Won;Moon, Deok-Bog;Hwang, Shin;Lee, Sung-Gyu;Kim, Kyung Mo
    • Pediatric Gastroenterology, Hepatology & Nutrition
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    • v.24 no.3
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    • pp.288-294
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    • 2021
  • Purpose: Despite aggressive medical and nutritional management, patients with methylmalonic acidemia (MMA) often suffer from multi-organ damage. Early deceased donor liver transplantation (DDLT) has emerged as an intervention to prevent disease progression. We investigated the efficacy of living donor LT (LDLT) with a potential carrier of MMA and a small volume of graft in patients with MMA as an alternative to DDLT. Methods: Of five patients (three male, two female; median age 5.7 years; range, 1.3-13.7 years), four underwent carrier LDLT, while one underwent non-carrier auxiliary LDLT. All patients received pre- and post-LT continuous renal replacement therapy and were provided with minimal restriction diet according to serum MMA level after LT. MMA levels in the serum and urine, the incidence of metabolic crisis, and clinical findings before and after LT were compared. Results: The survival rate was 100% during 2.2 years of follow up period after LT. In all five cases, MMA titer in the serum after transplantation decreased with less restrictive diet. Metabolic crisis was not observed during the follow-up period. In addition, no patient showed progression of severe renal impairment requiring hemodialysis. Progression of delayed cognitive development was not observed. Social functioning with improved neuropsychiatric development was observed. Conclusion: This study showed that LDLT achieved improved quality of life with less restrictive diet, therefore it could be a feasible alternative option to DDLT for the treatment of patients with MMA, even with an auxiliary LT.

Flexural Properties of Heat-Treatment Samama (Anthocephalus macrophyllus) Wood Impregnated by Boron and Methyl Metacrylate

  • CAHYONO, Tekat Dwi;DARMAWAN, Wayan;PRIADI, Trisna;ISWANTO, Apri Heri
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.1
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    • pp.76-85
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    • 2020
  • This study was conducted to analyze the application of boron compounds, methyl methacrylate (MMA), and heat treatment (HT) on changes in the density, moisture content, and flexural properties of samama (Anthocephalus macrophyllus) wood. Samama wood was impregnated with borax (BX) and boric acid (BA) using a pressure method at 5 atm for 4 h. Afterwards, the wood was impregnated with MMA at the same pressure and duration. Finally, the samama wood was given HT at 90 ℃ and 180 ℃. The results indicate that there was a weight gain of 93.4% in the wood impregnated using BA and MMA monomer and HT at 90 ℃. Consequently, the wood's density increased by 82.3%. Increased MOE and MOR percentages of 32.2% and 29.4%, respectively, were also found. HT at 180 ℃ degraded the wood components and MMA, and consequently, the density, MOE, and MOR also decreased. The wood impregnated by BX, BA, and MMA, and subjected to HT also had decreased moisture content (MC). This research recommends that the application of boron (BX, BA) should be combined with an MMA monomer and HT at 90 ℃ as an alternative method to improve samama wood quality. If darker color is preferable, HT should be conducted at 180 ℃.

Identification of a novel frameshift mutation (L345Sfs*15) in a Korean neonate with methylmalonic acidemia

  • Kim, Young A;Kim, Ji-Yong;Kim, Yoo-Mi;Cheon, Chong Kun
    • Journal of Genetic Medicine
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    • v.14 no.2
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    • pp.80-85
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    • 2017
  • Methylmalonic acidemia (MMA) is an autosomal recessive metabolic disorder characterized by an abnormal accumulation of methylmalonyl-CoA and methylmalonate in body fluids without hyperhomocysteinemia. Cardiac disease is a rarely known lethal complication of MMA, herein, we report a Korean neonate diagnosed with MMA on the basis of biochemical and genetic findings, who developed cardiomyopathy, resulting in sudden death. The patient presented vomiting and lethargy at 3 days of age. Initially, the patient had an increased plasma propionylcarnitine/acetylcarnitine concentration ratio of 0.49 in a tandem mass spectrometry analysis and an elevated ammonia level of $537{\mu}mol/L$. Urine organic acid analysis showed increased excretion of methylmalonate. Subsequent sequence analysis of the methylmalonyl-CoA mutase (MUT) gene revealed compound heterozygous mutations c.323G>A (p.Arg108His) in exon 1 and c.1033_1034del (p. Leu345Serfs*15) in exon 4, the latter being a novel mutation. In summary, this is the first case of MMA and cardiomyopathy in Korea that was confirmed by genetic analysis to involve a novel MUT mutation.

Preliminary Investigation into the Use of Methyl Methacrylate(MMA)-Based Materials for Road Repair (메틸 메타크릴레이트 기반 도로 보수재 개발을 위한 기초 연구)

  • Ji, Sung-Jun;Pyeon, Su-Jeong;Choi, Byung-Cheol;Kim, Jae-Hwan;Kim, Do-Su;Nam, Jeong-Soo
    • Journal of the Korea Institute of Building Construction
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    • v.24 no.1
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    • pp.35-42
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    • 2024
  • This research explores the potential of methyl methacrylate(MMA) as a material for road repair applications. It specifically examines two MMA formulations, referred to as type A and type B, in relation to their performance on concrete substrates. The evaluation criteria included drying time, tensile bond strength, and resistance to alkali. The condition of the substrate surface was varied across three curing environments: constant temperature and humidity(R), immersion in water(W), and immersion in water with chloride ions(N). The findings indicate that type B MMA exhibits a quicker drying time and superior resistance to alkali compared to type A. While type A demonstrated greater tensile bond strength, it failed to maintain adhesion with the concrete base. Based on the parameters tested in this study, type B MMA emerges as the more favorable option for road repair contexts. Nonetheless, the study underscores the necessity for additional testing on asphalt substrates to fully assess the material's durability and applicability for long-term road maintenance.

Ultra Thin Film Encapsulation for Flexible OLED (플렉시블 유기 EL 소자를 위한 초박막 보호층)

  • Lim, J.S.;Shin, P.K.;Lim, K.B.;Song, J.H.;Kim, C.Y.;Lee, B.S.;Jeung, Y.S.;Lim, H.C.
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1412-1413
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    • 2006
  • In this research, an organic thin 13 passivation layer was newly adopted to prefect the organic layer from ambient moisture and oxygen. As the organic thin film passivation layer, poly methyl methacrylate thin films (ppMMA) were deposited using a plasma polymerization technique. In order to their passivation performance for OLEDs, water vapor transmission rate (WVTR) of the ppMMAs were analyzed and luminance-current-voltage (L-I-V)/luminance-time (L-T) characteristics of the OLEDs with and without ppMMA passivation layer were investigated. The OLEDs had a structure of ITO/TPD (HTL)/Alq3(EML&ETL)/Al. The OLED with ppMMA passivation layer showed improved L-T performance than that of without ppMMA passivation layer.

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APICAL MICROLEAKAGE OF MTA WITH 4-META/MMA & TBB RESIN AS A ROOT-END FILLING MATERIAL (MTA와 4-META/MMA & TBB레진 혼합 재료의 치근단 미세누출에 관한 연구)

  • Kim, Jin-Cheol;Kim, Mi-Ri;Ko, Hyun-Jung;Yang, Won-Kyung
    • Restorative Dentistry and Endodontics
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    • v.34 no.4
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    • pp.371-376
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    • 2009
  • We evaluated in vitro microleakage of Mineral Trioxide Aggregate (MTA) powder with 4-methacryloxyethyl trimellitate anhydride (4-META) / methyl methacrylate (MMA) & tri-n-butylborane (TBB) resin as a retrograde filling material by using methylene blue dye method. Fifty-two single rooted, extracted teeth were instrumented and obturated with gutta percha and AH plus sealer. The apical 3mm of each root was resected and 3mm deep ultrasonic root end preparation was done. External surface of roots was coated with nail varnish. Prepared teeth were randomly divided into five groups; Negative control: completely covered with nail varnish; Positive control: coated with nail varnish except for apical foramen; Group 1 (retrofilled with Portland cement); Group 2 (retrofilled with MTA); Group 3 (retrofilled with MTA powder mixed with 4-META/MMA & TBB resin). Immediately after completion of root-end filling, all specimens were submerged in methylene blue dye for 72 hours in $37^{\circ}C$incubator. The roots were longitudinally sectioned and measured for extent of dye penetration by three different examiners under microscope (${\times}$10). The results were statistically analyzed using one way ANOVA and Turkey's HSD test. No leakage was evident in negative control and complete leakage in positive control group. Group 3 showed significantly less leakage than group 1 and 2 (p < 0.01). There was no significant difference between group 1 and 2 (p > 0.01). It was concluded that MTA powder with 4-META/MMA & TBB resin was excellent in reducing initial apical microleakage.

Sliced Multi-modulus Blind Equalization Algorithm

  • Abrar, Shafayat;Axford, Roy A. Jr.
    • ETRI Journal
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    • v.27 no.3
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    • pp.257-266
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    • 2005
  • Many multi-modulus blind equalization algorithms (MMA) have been presented in the past to overcome the undesirable high misadjustment exhibited by the well-known constant modulus algorithm. Some of these MMA schemes, specifically tailored for quadrature amplitude modulation (QAM) constellations, have also been proved to fix the phase offset error without needing any rotator at the end of the equalizer stage. In this paper, a new multi-modulus algorithm is presented for QAM signals. The contribution lies in the technique to incorporate the sliced symbols (outcomes of decision device) in the multi-modulus-based weight adaptation process. The convergence characteristics of the proposed sliced multi-modulus algorithm (S-MMA) is demonstrated by way of simulations, and it is shown that it gives better steady-state performance in terms of residual inter-symbol interference and symbol-error rate. It has also been shown that the proposed algorithm exhibits lesser steady-state misadjustment compared to the best reported MMA.

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The Role of MMA and EGDMA in Enhancing the Mechanical Properties of PMMA Composites (PMMA 복합재의 기계적 특성 향상을 위한 MMA 및 EGDMA의 역할 연구)

  • Aqila Che Ab Rahman;Shiyoung Yang;Sooman lim
    • Journal of Integrative Natural Science
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    • v.17 no.2
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    • pp.53-58
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    • 2024
  • This study explores the enhancement of mechanical properties in Polymethyl Methacrylate (PMMA) composites through the incorporation of Methyl Methacrylate (MMA) and Ethylene Glycol Dimethacrylate (EGDMA). Utilizing Digital Light Processing (DLP) technology, we conducted a series of experiments to analyze the impact of varying concentrations of MMA and EGDMA on PMMA. The results indicate that while MMA demonstrates non-linear and variable mechanical strength across different PMMA concentrations, EGDMA consistently improves mechanical strength as PMMA concentration increases. This consistent enhancement by EGDMA suggests a stable and predictable reinforcement effect, which is critical for applications requiring high mechanical strength. Our comparative analysis highlights that EGDMA is a more effective additive than MMA for optimizing the mechanical performance of PMMA composites. Specifically, EGDMA's ability to provide uniform reinforcement across various PMMA concentrations makes it ideal for high-strength applications. These findings are significant for material scientists and engineers focused on the design and development of advanced PMMA-based materials. In conclusion, this research underscores the importance of selecting appropriate additives to enhance the mechanical properties of PMMA composites. The superior performance of EGDMA in reinforcing PMMA suggests its potential for broader applications in fields such as automotive, construction, medical devices, and 3D printing. This study provides valuable insights that can guide future research and development in high-performance composite materials, paving the way for innovative applications and improved material efficiency.

A Study on the Preparation and Resist Characterization of the Plasma Polymerized Thin Films (플라즈마중합막의제작과레지스트 특성에 관한 연구)

  • 이덕출;박종관;한상옥;김종석;조성욱
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.43 no.5
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    • pp.802-808
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    • 1994
  • The purpose of this paper is to describe an application of plasma polymerized thin film as an electron beam resist. Plasma polymerized thin film was prepared using an interelectrode capacitively coupled gas-flow-type reactor, and chosen methylmethacrylate(MMA)and methylmethacrylate-tetrameth-yltin(MMA-TMT) as a monomer. This thin films were also delineated by the electron-beam apparatus with an acceleration voltage of 30kV and an expose dose ranging from 20 to 900$\mu$C/cmS02T. The delineated pattern in the resist was developed with the same reactor which is used for polymerization using an argon as etching gas. The growth rate and etching rate of the thin film is increased with increasing of discharge power. Thin films by plasma polymerization show polymerization rate of 30~45($\pm$3) A/min, and etching rate of 440($\pm$30) A/min during Ar plasma etching at discharge power of 100W. In apparently lower than that of conventional PMMA, but the plasma-etching rate of PP(MMA-TMT) was higher than that of PPMMA.

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