• Title/Summary/Keyword: S/OH

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Effects of Dipsacus asper on Free Radical Scavenging and Lowdensity Lipoprotein Oxidation (속단의 유리기소거활성 및 저밀도지방단백질 산화에 미치는 영향)

  • Park Hae-Sun;Yang Ki-Sook
    • YAKHAK HOEJI
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    • v.50 no.1
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    • pp.47-51
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    • 2006
  • The roots of Dipsacus asper are used in traditional Chinese medicine as an analgesic, enhancement of liver activity, an anti-inflammatory agent and the treatment of fractures. In order to investigate the antioxidative activity, Dipsaci Radix was extracted with MeOH and fractionated with $CHCl_3$, EtOAc, BuOH and water. MeOH ex. and its solvent fractions were determined on the free radical scavenging activity by DPPH method and antioxidative activity on low density lipoprotein oxidation. The EtOAc and BuOH fractions showed antioxidative activities and from their fractions, two compounds were isolated and identified as hederagenin 3-O-${alpha}$-L-arabino pyranoside (compound 1) and O-${\alpha}$-L-arabinopyranosyl hed-eragenin 28-O-${\beta}$-D-glucopyranosyl ($1{\to}6$)-${\beta}$-D-glucopyranosyl ester (compound 2). Saponin glycoside, compound I showed anti-oxidative activity.

Sulfate Resistance of Portland CementMatrices (포틀랜드시멘트계 경화체의 황산염저항성)

  • 문한영;이승태;김홍삼
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.04a
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    • pp.714-717
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    • 2000
  • To consider sulfate resistance of cement pastes and motars for 3 types of portland cements which have different $C_3A$ contents an silicate ratio($C_3S/C_2S$), they were immersed in 5% sodium sulfate solution for 400 days. SEM analysis and ($Ca(OH)_2$ contents of cement pastes, and compressive strength and length change of cement mortars, were performed to investigate the effects of ($C_3$ and ($Ca(OH)_2$ contents. According to the results of this study, low heat portland cement pastes, and compressive strength and length change of cement mortars, were performed to investigate the effects of C3A and ($Ca(OH)_2$ contents. According to the results of this study, low heat portland cement had a good sulfate resistances because of a small quantity of gypsum and ettringite due to less ($Ca(OH)_2$ contents. However, ordinary portland cement had an adverse result. This was also confirmed by SEM analysis.

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Biomimetic Deposition of Apatite on Zr-1Nb and Ti-6Al-4V

  • Kim, J.;Choi, Y.C.;Kim, H.S.;Hong, S.I.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1089-1090
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    • 2006
  • Biomimetic apatite deposition behaviors on Zr-1Nb and Ti-6Al-4V plate with various surface conditions were examined. Both alloys were polished with abrasive papers to have different roughness and some of them were treated in NaOH before exposition in simulated body fluid. NaOH treatment was found to enhance the deposition rate of apatite on Ti-6Al-4V significantly. On the other hand, the deposition rate of Zr-1Nb was not influenced by NaOH treatment. Without NaOH treatment, the polished Zr-1Nb with abrasive paper was found to induce more apatite nucleation than the polished Zr-6Al-4V.

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Donor Number of Mixed MeOH Solvents Using a Solvatochromic Cu(Ⅱ)-Complex (분광용매화 구리(II) 착물에 의한 메탄올 이성분 혼합용매들의 Donor Number)

  • Seoung-Kyo Yoo;Jin Sung Kim;Yeol Sakong
    • Journal of the Korean Chemical Society
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    • v.36 no.6
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    • pp.796-801
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    • 1992
  • An empirical Lewis basicity, DN, for eight mixed methanol solvents has been measured by the solvatochromic behavior of the [Cu(tmen)(acac)]$CIO_4$. The change of DN in mixed methanol solvents is not correlated with composition of the mixtures and divided into three groups: (1) dipolar aprotic solvents contribute mainly to the solvation of solute (MeOH-DMSO, MeOH-PY, MeOH-DMF), (2) two components of mixture contribute equally to the solvation of solute (MeOH-MeCN, MeOH-dioxane, MeOH-AC) and (3) methanol contributes entirely to the solvation of solute (MeOH-DCE, MeOH-TCE). The relationship between DN and Kamlet-Taft's $B_{KT}$ for mixed methanol solvents was found to agree well. These DN values also were a useful factor to analysis of reactivity for mixed methanol solvents.

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A frame detection method for DVB-S2x superframe receivers based on beam-hopping satellite transmission (빔-호핑 위성 전송 기반의 DVB-S2x 슈퍼프레임 수신기를 위한 프레임 검출 기법)

  • Oh, Jonggyu;Oh, Dukgil
    • Proceedings of the Korean Society of Broadcast Engineers Conference
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    • 2017.11a
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    • pp.24-27
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    • 2017
  • 본 논문에서는 빔-호핑 위성 전송 기반의 DVB-S2x 슈퍼프레임 수신기를 위한 프레임 검출 기법을 제안한다. 제안하는 검출 기법은 2 체배 오버샘플링 레이트에서(over-sampling rate)에서 동작을 수행하며, 슈퍼프레임의 헤더를 구성하는 start of super-frame (SOSF)과 super frame format indicator (SFFI)를 모두 이용하여 하드웨어 복잡도를 줄이면서도 견고하게 프레임을 검출할 수 있다.

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Posture and Low Back Pain (일반적인 자세가 요통에 미치는 영향에 대한 고찰)

  • Jung, Mun-Boung;Lee, Geoun-Sung;Kang, Eun-Mi;Oh, Kyeong-Seok
    • Journal of Korean Physical Therapy Science
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    • v.3 no.4
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    • pp.207-214
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    • 1996
  • Main cause of low back pain is a poor posture. Most low back pains are due to a poor posture. The poor posture induces muscle tension and finaliy low back pain. The poor posture arehabitually trained from the childhood by the environmetal factors. In general, maintaining good posture during working and sleeping hours are the first line of defence against back pam. (1) Supine posture is the easiest posture that relaxes and fixes muscles. Supine posture is thus a starting position for on exercise. Lying down releases the weight pressures of head and shoulder and thus body can be relaxed and extended which are helpful for treating back pain. However, supine posture can increase the pressure in ribcage posture aspect and disphragram due to visceral oragans. (2) Sitting in one position for a long time results in fatigue and relaxation of spinal muscies. Finally, body strength is weakened and sitting posture will become poor. If this poor posture continues for a longer time, pain will be accompanied due to overelongation of muscle ligaments. The habitual poor posture could induce intervertebral disc distortion. If the intervertebral disc is damaged, sitting in one position or movement causes pain. (3) Abnormal lumbar curve induces the tention of abdominal muscle and paravertebral muscle groups as well as tention of lower limb muscle group connected to pelvis. For a person with weak body strength, muscle relaxation increases curvature in lumbar, chest and cervical regions. This will induce a pelvic anterior tilting of the imaginary line between A. S. I. S. and P. S. I. S. Hip joint extensor muscle acts on releasing the pelvic anterior tilting. Contrections of hamstring muscle and femoral muscle recover the imaginary line between A.S.LS. and P.S.I.S. from pelvic anterior tilting. thus, contraction of rectus abdominis muscle are required to maintain the normal lumbar curve.

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Electrochemical and Fluorescent Properties of Ferrocenyl Chalcones Containing 1-Naphthalenyl Group: X-ray Crystal Structure of Fc-C(O)CH=CH-(1-Naph)

  • Suh, Woo-Young;Jeon, Hyo-Kyung;Lee, Ji-Yeon;Lim, Chae-Mi;Lee, Su-Kyung;Noh, Dong-Youn
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.443-448
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    • 2012
  • Ferrocenyl chalcones (Fc-C(O)CH=CH-Ar: Fc-Ar) with mono- and di-1-naphthalenyl moieties (Fc-1Naph and Fc-d1Naph) were prepared and spectroscopically characterized. The enone bridge was in the s-cis conformation and the $\pi$-electrons on the C=C bond were further delocalized on the bridge. The naphthalenyl moiety deviates greatly from the enone-Cp plane by $26.9(1)^{\circ}$. Cyclic voltammetry measurements for Fc-1Naph exhibit one reversible cycle for the redox of the ferrocenyl moiety at a lower potential, and one irreversible oxidation peak at the higher potential region. For Fc-d1Naph, the cyclic voltammogram is more featureless. Fluorescence properties for both compounds are active in polar solvents with $\lambda_{em}$ = 500 nm (EtOH) and $\lambda_{em}$ = 512 nm (MeOH) for Fc-1Naph and $\lambda_{em}$ = 496 nm (EtOH) and $\lambda_{em}$ = 508 nm (MeOH) for Fc-d1Naph. The intensity of Fc-d1Naph is more than twice than that of Fc-1Naph. The fluorescence properties for both compounds are inactive in the less polar solvents such as $CH_3CN$, $CH_2Cl_2$ and $CHCl_3$.