• 한국응용과학기술학회지
• /
• 제26권4호
• /
• pp.473-482
• /
• 2009

Titanium dioxide particles are used as cosmetics, pigments, photocatalysts, adsorbents, catalytic supports, and sensors. The $TiO_2$ particles were prepared by the precipitation in TTIP/Solvent mixtures and calcined at different temperatures. The resulting materials were characterized by XRD and SEM testing techniques. The $TiO_2$ particles phase composition was determined by XRD ranging from amorphous to crystalline anatase and rutile largely proportional to the calcination temperature.

• Fibers and Polymers
• /
• 제5권2호
• /
• pp.105-109
• /
• 2004

The synthesis of titanium dioxide nanofibers with 200-300nm diameter was presented. The new inorganic-organic hybrid nanofibers were prepared by sol-gel processing and electrospinning technique using a viscous solution of titanium isopropoxide (TiP)/poly(vinyl acetate) (PVAc). Pure titanium dioxide nanofibers were obtained by high temperature calcination of the inorganic-organic composite fibers. SEM, FT-IR, and WAXD techniques were employed to characterize these nanofibers. The titanium dioxide nanostructured fibers have rougher surface and smaller diameter compare with PVAc/TiP composite nanofibers. The anatase to rutile phase transformation occurred when the calcination temperature was increased from $600^{\circ}C$ to $1000^{\circ}C$.

• 한국세라믹학회지
• /
• 제30권2호
• /
• pp.101-106
• /
• 1993

Effects of CaO on microwave dielectric properties of (Ba, Pb)O-Nd2O3-TiO2 ceramic ystem were investigated. As the content of CaO increases, the sintered bulk density decreases due to the decrease of sinterability. However, with increasing the sintering tmperature, the relative dielectric constants increases. This has been attributed on the formation of the 2nd phase inclusion, TiO2(rutile). The Q values increase due to the compensation effect of Ca ions up to 1 wt%, and then decrease due to the interfacial relaxation effects. The temperature coefficient of resonance frequency increases to a positive direction with increasing the amounts of CaO.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2002년도 춘계학술대회 논문집 디스플레이 광소자 분야
• /
• pp.61-64
• /
• 2002

A novel ceramic synthesis technique, combustion synthesis, is explored to produce a orange-emitting $SnO_{2}:Eu^{3+}$ phosphors. This technique involves a reaction of metal salts with a citric acid as an organic fuel. The variation of the ratio of citric acid to metal introduces change in reaction temperature and atmosphere of the combustion reaction, which in turn influences crystallinity and luminescence properties of the final products seriously. And, the heat treatment of the as-synthesized product increases its luminescence intensity. Especially, the samples treated at above $1100^{\circ}C$ show a orange-emission peak, which is attributed to the formation of single phase and well-crystallized $SnO_{2}:Eu$ oxides in the rutile structure

• 대한전자공학회:학술대회논문집
• /
• 대한전자공학회 2008년도 하계종합학술대회
• /
• pp.381-382
• /
• 2008

We investigated the properties of DSSC by $TiO_2$-blocking layer formed at several annealing temperatures. At $300^{\circ}C$ and $600^{\circ}C$ anatase and rutile phase of $TiO_2$ were formed, respectively. The characteristics of DSSC was improved by blocking layer annealed at $600^{\circ}C$.

• 산업기술연구
• /
• 제21권A호
• /
• pp.273-278
• /
• 2001

In this study, we prepared nano-sized $TiO_2$ particles for various process variables by the diffusion flame reactor and we collected $TiO_2$ particles by thermophoresis. It is found that the size of $TiO_2$ particles increases, as the flame temperature or the inlet $TiCl_4$ concentration increase or the total gas flow rate decreases. We investigated the photo-degradation of phenol wish the prepared $TiO_2$ particles. We found the optimum amounts of $TiO_2$ photocatalysts for our experimental apparatus and investigated the photo-degradation efficiencies of phenol, changing the process variables such as size of $TiO_2$ photocatlysts, phase ratio of rutile/anatase, concentration of phenol, input ratio of $O_2$. Degradation efficiencies of phenol were almost 95% in 15 minutes for the standard conditions of our experiments.

• 한국정보디스플레이학회:학술대회논문집
• /
• 한국정보디스플레이학회 2002년도 International Meeting on Information Display
• /
• pp.831-834
• /
• 2002

A novel ceramic synthesis technique, combustion synthesis, is explored to produce an orange-emitting $SnO_2:Eu^{3+}$ phosphors. This technique involves a reaction of metal salts with a citric acid as an organic fuel. The variation of the ratio of citric acid to metal introduces change in reaction temperature and atmosphere of the combustion reaction, which in turn influences crystallinity and luminescence properties of the final products significantly. And the heat treatment of the as-synthesized product improved the CL intensity of the products. Especially, the sample treated at above 1100 $^{\circ}C$ shows an orange-emission, which is attributed to the formation of single phase and well-crystallized $SnO_2$:Eu in rutile structure.

• 한국방사성폐기물학회:학술대회논문집
• /
• 한국방사성폐기물학회 2005년도 Proceedings of The 6th korea-china joint workshop on nuclear waste management
• /
• pp.329-337
• /
• 2005

Synroc which comprises hollandite-rich ($Ba_{1-x}Cs_{2x}\;(Al_yTi_{2-y})\;Ti_{6}O_{16},\;75wt\%$), perovskite ($Ca_{1-x}Sr_xTiO_3,\;15wt\%$) and rutile ($TiO_2,\;10wt\%$) is devised for the immobilization of Sr/Cs (1:3, wt$\%$) separated from HLW liquid. Especially, hollandite-rich Synroc with different contents of Al element is fabricated, and its mineral phase assemblage and microstructure are determined by using XRD and SEM/EDS. The durability test is carried out by using MCC-1 method, leachate is analyzed by using ICP/MS and ICP/ AES. The results indicate that hollandite-rich Synroc variants is a suitable host for Immobilization of Sr/Cs separated from HLW liquid.

• 한국세라믹학회지
• /
• 제36권12호
• /
• pp.1335-1341
• /
• 1999

The electrical conductivity ($\sigma$) of TiO2 doped with 0.05-4.0mol% Nb2O5 was measured in the oxygen partial pressure range of 10-17 to 100 atm and temperature range of 1100 to 130$0^{\circ}C$ to investigate the electrical properties and defect types. The oxygen partial pressure dependence of the electrical conductivity (log$\sigma$/logPo2) above 110$0^{\circ}C$ was divided into the four regions. From these experimental results the following defect regions were proposed ; 1) Magneli phase(extended defect) 2) reduced rutile region where intrinsic defect predominates 3) nearly stoichiometric region which is independent on the oxygen partical pressure and 4) overstoichiometric region which is not observed in pure TiO2 The electrical conductivity of Nb-doped TiO2 depended on the doping content the oxygen partial pressure and the measuring tem-perature.

• Elastomers and Composites
• /
• 제50권2호
• /
• pp.132-137
• /
• 2015

A self actuated photocatalyst $Weltouch^{(R)}$ used to the remove the odor gases generated in the foaming process of shoes insole was prepared by sol-gel method and studied its property. Specially, with mixing $Weltouch^{(R)}$ in the foaming process of shoes insole, the physical functionality such as specific gravity, hardness, elongation, compression set was studied. The physical functionality of shoes insole was no variation by added $Weltouch^{(R)}$. The odor gases generated in the foaming process of shoes insole was detected to be reduced to 60~80% by self actuated photocataylst $Weltouch^{(R)}$ even in the dark conditions, which was observed for both anatase and rutile phase.