• Elastomers and Composites
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• 제35권3호
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• pp.215-226
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• 2000

Cure characteristics of carbon black-filled rubber compounds with different rubber composition were studied using a rheometer. The carbon black-filled rubber compounds with single, binary, and ternary rubber compositions of natural rubber (NR), styrene-butadiene rubber (SBR), and butadiene rubber (BR) were used. Delta-torques of the NR/BR- and SBR/BR-based compounds with a high BR content were higher than those of the single rubber-based compounds. For ternary rubber-based compounds, the delta-torques of the compounds were lower when the difference in the rubber content ratios was small than when it was big. Scorch and optimum cure times of the rubber compounds became shorter by increasing the content of NR in the compounds while those became longer by increasing the SBR content. Cure rates of the rubber compounds increased with a decrease of the SBR content in the rubber compounds. Reversion ratios decreased with an increase of the SBR content in the rubber compounds.

• Elastomers and Composites
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• 제33권2호
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• pp.75-82
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• 1998

The purpose of this experimental study was to investigate the effects of vulcanization condition on the properties of reinforced rubbers. Rubber reinforcing ability of carbon black was more efficient than other fillers, but tensile properties were not affected by vulcanization condition while vulcanization condition affected the physical properties of rubber compounds with silica and silane treated slica. It was found that silica and silane treated silica filled rubber compounds showed good dynamic properties, rebound, heat build-up, 0 and $60^{\circ}C$ tan $\delta$ compared with carbon black filled rubber compounds. Carbon black filled rubber compounds were higher than silica and silane treated silica filled rubber compounds in total crosslinking density by vulcanization condition. By analysis of crosslinking type, polysulfide crosslinking was the highest in the carbon black filled rubber compounds with decreasing the ratio of sulfur to accelerator, monosulfide crosslinking was the highest in the silane treated silica filled compounds with in-creasing the ratio of sulfur to accelerator.

• Macromolecular Research
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• 제9권1호
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• pp.37-44
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• 2001

A premixing effect for the properties of carbon black-filled rubber compounds was investigated using biblends of natural rubber (NR), styrene-butadiene rubber (SBR), and butadiene rubber (BR). Degree of mixing of the biblends was controlled by preblending time of 0.0, 2.5, and 5.0 min. Mooney viscosities of the compounds decreased by increasing the preblending time. Of three carbon black-filled compounds of NR/SBR, NR/BR, and SBR/BR compounds, only the SBR/BR blends showed a specific cure characteristics depending on the preblending time. For the bound rubber composition, the NR content was higher than SBR and BR. The difference in the rubber composition ratio of the bound rubber became smaller with increasing the preblending time. Physical properties of the vulcanizates such as hardness, modulus, tensile property, abrasion loss, and tans were also compared. Differences in properties of the compounds were discussed with miscibility of the dissimilar rubbers and degree of mixing.

• Macromolecular Research
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• 제8권2호
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• pp.73-79
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• 2000

The influence of mastication of natural rubber (NR) on properties of carbon black-filled NR compounds was studied. Variations of viscosities of the masticated NR and the carbon black-filled NR compound by heating were also investigated. The viscosities of the compounds decreased by increasing the mastication time of the raw rubber. The viscosities of the masticated NR and the compounds increased by increasing the heating time. This was explained by the combination reaction between functional groups in the rubber. The viscosity increment of the masticated rubber and the compounds by heating became larger with increased mastication time. Cure rate of the compound became faster by increasing the mastication time. Modulus of the vulcanizate made of the rubber masticated for a long time was higher than that of the vulcanizate made of the rubber masticated for a short time while elongation at break of the former was shorter than that of the latter. This was explained by the content of bound rubber and chain length of the rubber molecules.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 한국소성가공학회 2007년도 춘계학술대회 논문집
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• pp.209-212
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• 2007

Rubber compounds have high viscoelastic property. One of the viscoelastic behaviors during profile extrusion is the swelling of extrudate. In this study, die swell of rubber compounds at the capillary die have been investigated through an experiment and computer simulation. They have been performed using fluidity tester in experiment and commercial CFD code, Polyflow in computer simulation. Die swell of rubber compounds for relaxation time at several modes under same conditions with the experiment were predicted using non-linear differential viscoelastic model, Phan-Thien-Tanner (PTT) model. The simulation was analyzed compared with the experiment. Viscoelastic behaviors for pressure, velocity and shear rate distribution were analyzed at the capillary die. It is concluded that the PTT model successfully represented the amount of the optimal die swell of rubber compounds for relaxation time at different modes.

• Transactions of Materials Processing
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• 제16권4호
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• pp.260-265
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• 2007

Rubber compounds have high viscoelastic property. One of the viscoelastic behaviors during profile extrusion is the swelling of extrudate. In this study, die swells of rubber compounds at the capillary die have been investigated through experiment and computer simulation. Experiments and simulations have been performed using fluidity tester and commercial CFD code, Polyflow respectively. Die swells of rubber compounds in a capillary die were predicted using non-linear differential viscoelastic model, Phan-Thien-Tanner(PTT) model for various relaxation times and relaxation modes. The results of simulation were compared with the experiments. Pressure and velocity distribution, and circulation flows at the comer of capillary die have been investigated through computer simulation. It is concluded that the PTT model successfully represented the amount of the die swell of rubber compounds for various relaxation times at different modes.

• Elastomers and Composites
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• 제53권4호
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• pp.195-201
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• 2018

Three kinds of rubber compounds were prepared, and their underwater acoustical properties were investigated for anechoic coating. Dynamic mechanical properties of the rubber compounds were measured using a dynamic mechanical analyzer and extended to 100 kHz using time-temperature superposition. The sound speed, reflection coefficient, and attenuation constant were calculated. Silicone rubber showed the lowest reflection coefficient, and nitrile rubber showed the highest attenuation constant. The acoustic properties of nitrile rubber compounds with various compositions were investigated. The sound speed, reflection coefficient, and transmission coefficient of the nitrile rubber in the frequency range of 200-1000 kHz were measured in a water-filled tank.

• Elastomers and Composites
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• 제33권1호
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• pp.44-51
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• 1998

The purpose of this experiments were investigated on the physical properties of rubber com-pounds containing two types carbon black. Bound rubber and interaction coefficient for com-pounds with pure carbon black were higher than those for the compounds with dual phase carbon black. Slightly higher values in 300% modulus and tensile strength indicated that the ratio of rubber-filler bound to rubber-rubber bound of pure carbon black were higher than those of com-pounds with dual phase carbon black. It was founded that dynamic properties, that is rebound, heat build-up, 0 & $60^{\circ}C$ tan $\delta$, and cut and chip loss of compounds with dual phase carbon black were better than those of compounds with pure carbon black, but abrasion property of dual phase carbon black was lower than those of pure carbon black because of low reinforcing ability.

• Applied Chemistry for Engineering
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• 제29권4호
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• pp.399-404
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• 2018

This study compared the tackiness and adhesion of different tire tread compounds and rubber cements before and after vulcanization. The tackiness of natural rubber (NR) cement was the highest for all tread compounds before vulcanization, and the decrease in tackiness of NR cements over time was smaller than that of synthetic rubber cements. The tackiness before vulcanization was affected by the glass transition temperature of the rubber used in the cement and the decrease in tackiness over time of NR was smaller compared to that of using the synthetic rubber. The adhesion of NR-based cements after vulcanization was high for NR tread compounds but low for synthetic rubber tread compounds. On the contrary, the adhesion of emulsion (SBR) and solution SBR cements was high on all tread compounds which was shown to be higher when the rate of vulcanization of cement rubber was lower.

• Elastomers and Composites
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• 제55권3호
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• pp.176-183
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• 2020

Silica-styrene butadiene rubber (Silica-SBR) compounds have been used in the preparation of tire treads. The silica dispersibility of silica-SBR compounds is related to the processability, mechanical properties, and wear resistance of tires. Recently, in order to improve the silica dispersibility of the silica-SBR compounds, the wet masterbatch (WMB) process was introduced, which is a method of mixing rubber in the water phase. We aimed to improve the silica dispersibility of the silica-SBR compounds by preparing a silica dispersant applicable to the WMB process. For this purpose, cellulose, 2-hydroxyethyl cellulose, and cellulose acetate were employed as a silica dispersant. The silica dispersibility of the compounds was measured by a moving die rheometer. Improvement in the processability of silica-SBR compounds was evaluated by the Mooney viscometer. The wear resistance of silica-SBR compounds using a cellulose dispersant was improved by up to 29%.