• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.17 no.6
• /
• pp.661-667
• /
• 2004

The control of tilt angle for nematic liquid crystal (NLC) with negative and positive dielectric anisotropy on the rubbed homeotropic polyimide (PI) using baking method by hot plate equipment was investigated. LC tilt angle decreased with increasing baking temperature and time. Especially, the low LC tilt angle of positive type NLC (Δ$\varepsilon$＞0) on the rubbed homeotropic PI surface by increasing temperature and time was measured. The tilt angle of positive type NLC(Δ$\varepsilon$＞0) is smaller than that of the negative type (Δ$\varepsilon$＞0) on rubbed PI with increasing baking temperature and time. We consider that the tilt angle of NLC is decreased due to increasing the steric interaction between horizon component of permittivity $\varepsilon$ = of NLC and the stress of polymer side chain by high temperature. As the increase of baking temperature, we obtain that AFM (atomic force microscope) image of rubbed PI surface using Hot-plate method has formed better solid micro-groove structure than oven method.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2002.04b
• /
• pp.121-123
• /
• 2002

Fast response characteristics of twisted nematic liquid crystal display (TN-LCD) cell with different nematic liquid crystals (NLCs) and cell gap on a rubbed polyimide (PI) surface were studied. High transmittance and fast response time of the TN-LCD on the rubbed PI surface were achieved by using high birefringence ($\Delta$ n) and low cell gap. It is considered that the transmittance and response time of the TN-LCD on the rubbed PI surface decreased as $\Delta$ nd decrease.

• Proceedings of the KIEE Conference
• /
• 1995.11a
• /
• pp.414-416
• /
• 1995

We have studied the effect of the mesogenic core of nematic liquid crystals (NLCs) for polar (out-of-plane tilt) anchoring strength on rubbed polyimide (PI) films. The order of polar anchoring strength for NLCs on rubbed PI films is 5CB > PCH5 > CCH5. This order is the same for all rubbing strengths investigated. From these results, we suggest that the polar anchoring strength strongly depends on the polarizability of the NLCs.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.11 no.4
• /
• pp.306-313
• /
• 1998

To elucidate the liquid crystal(LC) molecules alignment mechanism, it is important to determine the molecular orientation of the rubbed polymer surface molecules that directly contact with LC molecules. In this work, the molecular orientation on a rubbed surface of polyimide (SE-3310, Nissan) film has been studied by polarized FTIR absorption spectroscopy. It has been found that molecular chain on the rubbed surface of polymide film are oriented along the rubbing direction and are tilted up on an average by 5.0$^{\circ}$. In the SHG(Second Harmonic Generation) measurement, the pretilt angle of molecular chain on the poylmide fim was 4.6$^{\circ}$ fro, the surface plane. And the pedit angle of liquid crystal (ZLI-2293, Merck) molecules measured by crystal rotation method was 5.4$^{\circ}$in the same rubbing condition.

• Korean Journal of Optics and Photonics
• /
• v.24 no.2
• /
• pp.77-85
• /
• 2013

The precision of retardation measurement has been improved upto $3{\sigma}$ <0.005 nm after improvements are made to the conventional transmission ellipsometer. Improvements are made such that, i) the polarizer module instead of the sample stage is rotated, ii) the light source is replaced, iii) the starting points of two rotating modules are accurately synchronized, and iv) the fine background retardation is compensated. Together with the newly introduced RVD (Retardation Vector Difference) method, the improved instrument is successfully applied to characterize the ultra small optical birefringence of the rubbed polyimide alignment layer, after the residual retardation due to glass substrate whose magnitude is about 1.0 nm is properly subtracted. It is verified that the net retardation of the alignment layer ranges from 0.05 nm to 0.15 nm.

• Proceedings of the KIEE Conference
• /
• 1997.07d
• /
• pp.1577-1578
• /
• 1997

We have studied the effect of the rubbing fabric for liquid crystal alignment and pretilt angle generation in nematic liquid crystals (NLC), 4-cyano-4-n-penthylbiphenyl (5CB), on rubbed polyimide (PI) surfaces. The pretilt angle of 5CB for nylon and rayon fabric is larger than that of cotton fabric in weak rubbing on rubbed PI surfaces. We conclude that the pretilt angle of 5CB is strongly related to the rubbing fabrics on rubbed PI surfaces.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1996.05a
• /
• pp.105-108
• /
• 1996

We have studied the anisotropic dispersion force effects for surfaces alignment of liquid crystals (LCs) on rubbed polystyrene (PS) surfaces by unidirection. In microphotographs of the textures, we obtained the nematic (N) LCs are shown to align in both direction parallel and Perpendicular to the rubbing for region up to medium rubbing, however to align in the direction perpendicular to the rubbing for strong rubbing legion. We suggest that the anisotropic dispersion force is very important rather than macro-surface groove effect to uniform alignment of LCs. We also measured the temperature dependence of extrapolation length of 5CB on rubbed PS surfaces for strong rubbing. It is shown that the polar anchoring strength of 5CB is very weak on rubbed PS surface compared to the rubbed polyimide (Pl) surface.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1998.06a
• /
• pp.263-266
• /
• 1998

In this study, the effect of the crystallinity of polyimide (Pl) and the birefringence of the nematic liquid crystal (NLC) for pretilt angle generation on rubbed PI surface containing thiophenylene moieties has been demonstrated. The induced optical retardation produced in rubbed Pl surfaces decreases on increasing the imidization temperature. We suggest that the pretilt angle of 4-cyano-4'-n-pentybiphenyl (5CB) depends on the crystallinity of the rubbed Pl. The order of pretilt angle in NLCs is 5CB>PCH5$\geq$CCH5 at rubbing strength(RS)=150mm (medium rubbing) on rubbed PI surfaces. We suggest that on rubbed Pl surfaces the pretilt angle increases with increasing number of phenylrings in the NLC core.

• Korean Journal of Optics and Photonics
• /
• v.26 no.4
• /
• pp.195-202
• /
• 2015

We developed a reflection ellipsometer so that one can measure the extremely small optical anisotropy of a rubbed polyimide alignment layer, without being disturbed by the residual anisotropy of the substrate. The optical anisotropy of the alignment layer was measured as rubbing strength was increased, and the measured anisotropy was compared to the retardation obtained by using a transmission-type ellipsometer, to confirm the reliability of our reflection ellipsometer. With this measured anisotropy we could verify the formation of an alignment layer by rubbing, and could quantitatively evaluate the formation of the alignment layer.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2001.11a
• /
• pp.337-340
• /
• 2001

The control of high pretilt angle for nematic liquid crystal (NLC) with negative dielectric anisotropy on the rubbed blending polyimide (homeotropic and homogeneous alignment) surface were studied. High NLC pretilt angle generated on the blending polyimide (homeotropic polyimide and SE-7492 surface was measured and the NLC pretilt angle increases with blending ratio and rubbing strength. However, the NLC pretilt angle generated on the blending polyimide (homeotropic polyimide and SE-150 surface was not varied. The high pretilt angle the NLC using blending polyimide surface can be achieved.