• Title/Summary/Keyword: Rotational relaxation

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Improving High-resolution Impedance Manometry Using Novel Viscous and Super-viscous Substrates in the Supine and Upright Positions: A Pilot Study

  • Wong, Uni;Person, Erik B;Castell, Donald O;von Rosenvinge, Erik;Raufman, Jean-Pierre;Xie, Guofeng
    • Journal of Neurogastroenterology and Motility
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    • v.24 no.4
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    • pp.570-576
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    • 2018
  • Background/Aims Swallows with viscous or solid boluses in different body positions alter esophageal manometry patterns. Limitations of previous studies include lack of standardized viscous substrates and the need for chewing prior to swallowing solid boluses. We hypothesize that high-resolution impedance manometry (HRiM) using standardized viscous and super-viscous swallows in supine and upright positions improves sensitivity for detecting esophageal motility abnormalities when compared with traditional saline swallows. To establish normative values for these novel substrates, we recruited healthy volunteers and performed HRiM. Methods Standardized viscous and super-viscous substrates were prepared using "Thick-It" food thickener and a rotational viscometer. All swallows were administered in 5-mL increments in both supine and upright positions. HRiM metrics and impedance (bolus transit) were calculated. We used a paired two-tailed t test to compare all metrics by position and substrate. Results The 5-g, 7-g, and 10-g substrates measured 5000, 36 200, and 64 $700mPa{\cdot}sec$, respectively. In 18 volunteers, we observed that the integrated relaxation pressure was lower when upright than when supine for all substrates (P < 0.01). The 10-g substrate significantly increased integrated relaxation pressure when compared to saline in the supine position (P < 0.01). Substrates and positions also affected distal contractile integral, distal latency, and impedance values. Conclusions We examined HRiM values using novel standardized viscous and super-viscous substrates in healthy subjects for both supine and upright positions. We found that viscosity and position affected HRiM Chicago metrics and have potential to increase the sensitivity of esophageal manometry.

Effect of Neutron irradiation in $Fe_{81}B_{13.5}_Si{3.5}C_2$Amorphous Ribbon (비정질 $Fe_{81}B_{13.5}_Si{3.5}C_2$ 리본의 중성자 조사에 따른 자기적 특성변화)

  • 김효철;홍권표;김철기;유성초
    • Journal of the Korean Magnetics Society
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    • v.10 no.2
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    • pp.49-52
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    • 2000
  • The changes of magnetic properties in neutron irradiated F $e_{81}$ $B_{13.5}$S $i_{3.5}$ $C_2$ amorphous ribbon were studied by X-ray diffraction, hysteresis loop, temperature dependence of magnetization and complex permeability. The fluences of thermal ( $n_{th}$) and fast ( $n_{f}$) neutron were 6.95$\times$10$^{18}$ $n_{th}$ c $m^{-2}$ and 4.56$\times$10$^{16}$ $n_{f}$c $m^{-2}$ , respectively. The changes of XRD Profiles were not observable at the neutron irradiated sample. The complex permeability spectra showed that the permeability from domain wall motion decreased due to the increase of pinning force against domain motion by the neutron irradiation, and the relaxation frequency of rotational magnetization moved to higher frequency region. The measurement of hysteresis loop showed the increase of magnetic softness, related to rotational magnetization, but saturation magnetization was decreased in neutron irradiation sample. The Curie temperature was decreased in the neutron irradiated sample.e.e.e.

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Determination of Correlation Times of New Paramagnetic Gadolinium MR Contrast Agents by EPR and 17O NMR

  • Kim, Hee-Kyung;Lee, Gang-Ho;Kim, Tae-Jeong;Chang, Yong-Min
    • Bulletin of the Korean Chemical Society
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    • v.30 no.4
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    • pp.849-852
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    • 2009
  • The work describes EPR and 17O NMR measurements followed by theoretical calculation of the rotational correlation time $({\tau}_R)$, the water residence time $({\tau}_m)$, and the longitudinal electronic spin relaxation time $(T_{le})$(T_1e) for two new gadolinium complexes 1 and 2 of the type [$Gd(L)(H_2O)$] (L = tranexamic esters) in order to investigate their efficiency as a paramagnetic contrast agent (PCA). Of three correlation times, τR plays a major and predominant role to the unusually high relaxivity of 1 and 2 as compared with that of clinically approved MR CAs such as [$Gd(DTPA)(H_2O)]2‐ (Magnevist${\circledR}$), [Gd(DTPA-BMA)(H2O)] (Omniscan${\circledR}$), and $[Gd(DOTA)(H_2O)]^-$ (Dotarem${\circledR}$). The presence of bulky tranexamic ester in the ligand seems to be responsible for the conformational rigidity, which in turn causes such great an increase in ${\tau}_R$.

Passive suppression of helicopter ground resonance instability by means of a strongly nonlinear absorber

  • Bergeot, Baptiste;Bellizzi, Sergio;Cochelin, Bruno
    • Advances in aircraft and spacecraft science
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    • v.3 no.3
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    • pp.271-298
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    • 2016
  • In this paper, we study a problem of passive suppression of helicopter Ground Resonance (GR) using a single degree freedom Nonlinear Energy Sink (NES), GR is a dynamic instability involving the coupling of the blades motion in the rotational plane (i.e. the lag motion) and the helicopter fuselage motion. A reduced linear system reproducing GR instability is used. It is obtained using successively Coleman transformation and binormal transformation. The analysis of the steadystate responses of this model is performed when a NES is attached on the helicopter fuselage. The NES involves an essential cubic restoring force and a linear damping force. The analysis is achieved applying complexification-averaging method. The resulting slow-flow model is finally analyzed using multiple scale approach. Four steady-state responses corresponding to complete suppression, partial suppression through strongly modulated response, partial suppression through periodic response and no suppression of the GR are highlighted. An algorithm based on simple criterions is developed to predict these steady-state response regimes. Numerical simulations of the complete system confirm this analysis of the slow-flow dynamics. A parametric analysis of the influence of the NES damping coefficient and the rotor speed on the response regime is finally proposed.

The Equilibrium between Dilatant and Thixotropic Flow Units

  • 방정환;김남정;최상원;김응렬;한상준
    • Bulletin of the Korean Chemical Society
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    • v.17 no.3
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    • pp.262-268
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    • 1996
  • Flow properties of all suspensions are controlled by their flow units. The factors effecting on the flow units are the characteristics of the particle itself (surface properties, particle sizes, particle shapes and etc.), the electrostatic interactions among the particles and the influences of the medium in the suspensions. Here, we studied the transition between the flow units with shear rate which can be added to the above factors. For the concentrated starch-water suspensions, by using the Couette type rotational viscometer, we confirmed that at low shear rate, dilatancy is appeared, but it is transformed to thixotropy with increasing shear rate. In order to explain this fact, we derived the following flow equation, representing the transition from dilatancy to thixotropy with shear rate, by assuming the equilibrium between the flow units. f = X1β1s./α1 + 1/(1+Kexp(c0s.2/RT))((1-X1)/α2)sinh-1{(β2)0 s. exp(c2s.2/RT)} + K exp(c0s.2/RT)/(1+K exp(c0s.2/RT))((1-X1)/α3)sinh-1{(β3)0 s. exp(-c3s.2/RT)} By applying this flow equation to the experimental flow curves for the concentrated starch-water suspensions, the flow parameters were obtained. And, by substituting the obtained flow parameters to the flow equation, the theoretical flow curves were reproduced. Also, Ostwald curve was represented by applying the flow equation, and the applicability for stress relaxation was discussed.

Rheological Measurement of Fiber Spinnability of PVA Solution Dopes in DMSO

  • Chae, Dong-Wook
    • Textile Coloration and Finishing
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    • v.22 no.3
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    • pp.187-193
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    • 2010
  • The effects of molecular weight (MW) and concentration on the rheological properties of poly(vinyl alcohol) (PVA) solutions in dimethyl sulfoxide (DMSO) were investigated at $30^{\circ}C$. Ubbelohde viscometer and rotational rheometer were employed for dilute and concentrated regime, respectively. In the dilute regime, the Mark-Houwink exponent ($\alpha$) of the solutions determined from three different MWs proved 0.73. The critical concentration (C*), in which the entanglement and overlap of polymer molecules began to take place, decreased with increasing the MW of PVA. Huggins constant ($K_H$) values ranged from 0.33 to 0.45 over the MW examined. In the log-log plot of $\eta_{sp}$ versus [$\eta$]C, the PVA with higher degree of polymerization (DP) gave a greater slope exhibiting the inflection point in the vicinity of C*. In the dynamic viscosity ($\eta'$) curve, the PVA solutions of DP 1700 presented Newtonian fluid behavior over most of the frequency range examined. However, the lower Newtonian flow region reduced with increasing the DP. As the PVA concentration increased, $\eta'$ was increased and the onset shear rate for pseudoplasticity was decreased. In the Cole-Cole plot, PVA solutions showed almost a single master curve in a slope of ca. 1.65 regardless of the DP. However, the increase of the concentration from 8 to 12 wt% for PVA solutions of DP 5000 decreased the slope from 1.73 to 1.57. In the tan $\delta$ curve, the onset frequency for sol-gel transition was shifted from 154 to 92 rad/s with increasing the DP from 3300 to 5000 and from 192 to 46 rad/s with increasing the concentration from 8 to 12 wt%. In addition, longer relaxation time ($\lambda$) was observed with increasing the DP and concentration.