• Title/Summary/Keyword: Room temperatures

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EXCITED-STATE INTRAMOLECULAR PROTON TRANSFER IN DICOUMAROL, A $CH_2$-BRIDGED DIMER OF 4-HYDROXYCOUMARIN

  • Cho, Dae-Won
    • Journal of Photoscience
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    • v.2 no.1
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    • pp.13-18
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    • 1995
  • The steady-state emission spectra of dicoumarol (DC) in ethanol and EPA have been examined at various temperatures (77-298 K). At room temperature, a fluorescence spectrum of DC in ethanol shows a emission maximum at 350 nm. In EPA a Stokes-shifted emission band appears around 470 nm in addition to the 350 nm emission, and its intensity is enhanced as temperature decreases. This emission is attributed to a zwitterionic tautomer of DC formed by a single excited-state intramolecular proton transfer (ESIPT) along the internal hydrogen-bonding. The fluorescence lifetimes have been measured at 350 and 450 nm as a function of temperature. The fluorescence decay at 350 nm is single exponential at any temperature, whereas the one at 450 nm becomes biexponential at temperatures below 250 K. These results are discussed in terms of a conformational change followed by the ESIPT. The activation energy barrier for the conformational change has been determined to be 3.7 $\pm$ 0.2 kJ/mole.

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Flexural strength of concrete-galvalume composite beam under elevated temperatures

  • Maryoto, Agus;Lie, Han Ay;Jonkers, Hendrik Marius
    • Computers and Concrete
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    • v.27 no.1
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    • pp.13-20
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    • 2021
  • In this paper, the elevated temperature on a concrete-galvalume composite beam's flexural strength based on the numerical and experimental methods is investigated. The strategy is to perform modeling and simulation of the flexural test based on finite element method (FEM) at room temperature and validate its results to experimental data at the same temperature. When the numerical model was proven valid, the model was utilized to simulate the effect of elevated temperatures on the composite element. The study concludes that the flexural strength of the beam decreases at higher temperature. Additionally, it was shown that cracking moments is susceptible to temperature fluctuation and the failure modes are sensitive concerning the elevated temperature.

The Effect of Substrate Temperature on Tribological and Electrical Properties of Sputtered Carbon Nitride Thin Film (스퍼터링 질화탄소 박막의 트라이볼로지 및 전기적 특성의 기판 온도 영향)

  • Park, Chan Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.1
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    • pp.33-38
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    • 2021
  • Using facing target magnetron sputtering (FTMS) with a graphite target source, carbon nitride thin films were deposited on silicon and glass substrates at different substrate temperatures to confirm the tribological, electrical, and structural properties of thin films. The substrate temperatures were room temperature, 150℃, and 300℃. The tribology and electrical properties of the carbon nitride thin films were measured as the substrate temperature increased, and a study on the relation between these results and structural properties was conducted. The results show that the increase in the substrate temperature during the fabrication of the carbon nitride thin films increased the hardness and elastic modulus values, the critical load value was increased, and the residual stress value was reduced. Moreover, the increase in the substrate temperature during thin-film deposition was attributed to the improvement in the electrical properties of carbon nitride thin film.

Two Way Set Temperature Control Impact Study on Ground Coupled Heat Pump System Energy Saving (양방향 설정온도 제어에 따른 지중연계 히트펌프 시스템의 에너지 절감량 평가 연구)

  • Kang, Eun-Chul;Lee, Euy-Joon;Min, Kyong-Chon
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.10 no.2
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    • pp.7-12
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    • 2014
  • Government has recently restricted heating and cooling set temperatures for the commercial and public buildings due to increasing national energy consumption. The goal of this paper is to visualize a future two way indoor set temperature control impact on building energy consumption by using TRNSYS simulation modeling. The building was modelled based on the twin test cell with the same dimension. Air source ground coupled heat pump performance data has been used for modeling by TRNSYS 17. Daejeon weather data has been used from Korea Solar Energy Society. The heating set temperature in the reference room is $24^{\circ}C$ as well as the target room set temperature are $23^{\circ}C$, $22^{\circ}C$, $21^{\circ}C$ and $20^{\circ}C$. The cooling set temperature of the reference room is also $24^{\circ}C$ as well as the target room set temperature of $25^{\circ}C$, $26^{\circ}C$, $27^{\circ}C$ and $28^{\circ}C$. For the air source heat pump system, heating season energy consumption is $35.52kWh/m^2y$ in the reference room. But the heating energy consumption in the target room is reduced to 7.5% whenever the set temperature decreased every $1^{\circ}C$. The cooling energy consumption in the reference room is $4.57kWh/m^2y$. On the other hand, the energy consumption in the target room is reduced to 22% whenever the set temperature increased every $1^{\circ}C$ by two way controller. For the geothermal heat pump system, heating energy consumption in the reference room is reduced to 20.7%. The target room heating energy consumption is reduced to 32.6% when the set temperature is $22^{\circ}C$. The energy consumption in the target room is reduced to 59.5% when the set temperature is $26^{\circ}C$.

Sliding We3f Properties for 5%Co-5%V-1%Nb High Speed Steel by Powder Metallurgy at High Temperature (5%Co-5%V-1%Nb 분말고속도공구강의 고온 미끄럼마모특성)

  • 이한영;김용진;배종수
    • Tribology and Lubricants
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    • v.19 no.3
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    • pp.151-158
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    • 2003
  • In metal cutting at the tool-chip interface, friction generates considerable amount of heat. Thus, the knowledge of wear properties of cutting tool material in high temperature has been as one of important factors in need of clarification. The authors presented the wear properties of 5%Co-5%V-1%Nb high speed steel, fabricated by powder metallurgy, in room temperature in previous articles. The objective of this paper is to clarify the effects of temperature on its wear properties. Wear tests in sliding conditions under various temperatures have been conducted using the pin-on-disc type wear test machine. The results indicate that the wear properties of 5%Co-5%V-1%Nb high speed steel in high temperature as well as in room temperature are excellent. It may be deduced that the oxide layer formed on worn surface at high temperature is stable enough to prevent wear due to the high temperature strength of its matrix.

Low Temperature Plastic Hardening Constitutive Equation for Steels of Polar Class Vessels (빙해선박 강재의 저온 소성경화 구성방정식)

  • Min, Dug-Ki;Heo, Young-Mi;Cho, Sang-Rai
    • Journal of the Society of Naval Architects of Korea
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    • v.49 no.3
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    • pp.227-231
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    • 2012
  • In this study, a plastic hardening constitutive equation for steels of polar class vessels at low temperature is proposed. The equation was derived using the experimental data obtained from tensile tests at room and low temperatures. Tensile tests at low temperature are both costly and time consuming because an expensive cold chamber is necessary and it takes too much time to cool down a specimen to set temperature. Using the proposed plastic hardening constitutive equation the plastic hardening characteristics of steels for polar class vessels at low temperature can be easily predicted from the tensile test results at room temperature.

Electrical Properties of Low-Temperature Sintered BaTiO3 Added with Lead Germanate (Lead Germanate를 첨가하여 저온소결한 반도성 BaTiO3의 전기적 성질)

  • 윤상옥;정형진;윤기현
    • Journal of the Korean Ceramic Society
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    • v.28 no.6
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    • pp.451-456
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    • 1991
  • Electrical properties of 0.15 mol% Y2O3 doped semiconducting BaTiO3 ceramics have been investigated as functions of Pb5Ge3O11 contents (from 0.25 mol% to 2.5 mol%) and sintering temperatures (from 1150$^{\circ}C$ to 1300$^{\circ}C$). The low-temperature sintered BaTiO3 ceramics above 1150$^{\circ}C$ show increase of Curie temperature due to the diffusion of Pb+2 ions, and their PTCR effects decrease. As the sintering temperature increases the room temperature resistance decreases due to the growth of the grain, but the room temperature resistance increases with the increase of the Pb5Ge3O11 contents by the formation of thick insulating layers at the grain boundary.

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Studies on Semisolid Infant Foods( ll ) - Storage Stability of The Home -Prepared Infant Foods - (반고체 이유보충식(離乳補充食)에 관한 연구(硏究) (II) -가정용(家庭用) Formula의 저장성(貯藏性)-)

  • Yoon, Suk-Kyong;Lee, Young-Chun
    • Journal of Nutrition and Health
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    • v.18 no.1
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    • pp.55-62
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    • 1985
  • The storage stability of the developed Formula of infant foods was investigated. The results are summarized as follows : When formula A and B were stored at room temperature and refrigeration temperature, there was no remarkable changes in consistency. In frozen state, formula A showed more stability in consistency than formula B and formula A could be stored for 6 months without problems due to retrogradation of starch. The heat treatment of both A and B resulted in the increase of a-value, while L-and b-value showed no such change. But from the 4th month at room temperature, and 5th to 6th month at refrigeration appeared an increase in a -value, hence the browning reaction, while frozen samples did not show noticeable changes in surface color. The heat treatment also caused an increase in POV on both formula. The extent of changes in POV during storage varied with storage temperatures and samples.

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High Temperature Wear Behavior of Plasma-Sprayed Zirconia-Alumina Composite Coatings (플라즈마 용사된 알루미나-지르코니아 복합체의 고온 마모.마찰 거동)

  • 김장엽;임대순;안효석
    • Tribology and Lubricants
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    • v.12 no.3
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    • pp.33-38
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    • 1996
  • High temperature wear behaviors of plasma-sprayed ZrO$_{2}$-$Y_{2}O_{3}$ composite coatings were investigated for high temperature wear resistance applications. The composite powders containing 20, 50, 80 vol% of alumina for plasma spray were made by spray drying method. Wear tests with composite coated specimens were performed at temperature ranges from room temperature to 800$^{\circ}$C. Wear tests were also carried out with heat treated specimens at room temperature. The microstructural change of coatings and the worn surface were examined by SEM and XRD. Sharp increase of wear loss at high temperature wear test was observed in specimens containing 50 and 80 vol% alumina. Similar trend was observed in the heat treated coatings. The measured residual stress was increased with increased alumina contents and heat treating temperatures. Residual stress induced during heat treatment appeared to be responsible to the observed harmful effect of alumina additions on the high temperature wear.

The Effect of Barium Sulfate on the Structural Transformations in Tricalcium Silicate (3CaO.$SiO_2$의 구조전이에 미치는 $BaSO_4$의 영향)

  • 서일영;최상흘
    • Journal of the Korean Ceramic Society
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    • v.11 no.2
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    • pp.17-21
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    • 1974
  • Miscibility of barium sulfate in tricalcium silicate was investigated by firing 3CaCO3·SiO2 mixture containing barium sulfate at 1530℃. Added amount of barium sulfate to the mixture was zero to 5 mole % with intervals of 1 mole %. Lattice parametres were also calculated. Results were as follow; 1) Dissolution of barium sulfate in tricalcium silicate does not alter the symmetry in room temperature, but influences it's polymorphic transition forms, temperatures and thermal effects; modification triclinic Ⅱ is stabilized in room temperature. 2) Barium sulfate dissolves about up to 2 mole % in tricalcium silicate and more than this amount, tricalcium silicate formation is inhibited. 3) Unit cell volume of tricalcium silicate is slightly decreased with dissolution of barium sulfate, mainly because of contraction in c axis.

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