• Title/Summary/Keyword: Rod shaped

검색결과 378건 처리시간 0.032초

대기 분위기의 알루미나 도가니 내에서 Zn 분말의 산화에 의해 합성된 ZnO 나노분말 (ZnO Nano-Powder Synthesized through a Simple Oxidation of Metallic Zn Powder in Alumina Crucible under an Air Atmosphere)

  • 이근형
    • 대한금속재료학회지
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    • 제48권9호
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    • pp.861-866
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    • 2010
  • Tetrapod-shaped ZnO crystals were synthesized through a simple oxidation of metallic Zn powder in air without the presence of any catalysts or substrates. X-ray diffraction data revealed that the ZnO crystals had wurtzite structure. It is supposed that the growth of the tetrapod proceeded in a vapor-solid growth mechanism. As the amount of the source powder increased, the size of the tetrapod decreased. The tip morphology of the tetrapod changed from a needle-like shape to a spherical shape with the oxidation time. ZnO crystals with rod shape were fabricated via the oxidation of Zn and Sn mixture. Sn played an important role in the formation of ZnO crystals with different morphology by affecting the growth mode of ZnO crystals. The cathodoluminescent properties were measured for the samples. The strongest green emission was observed for the rod-shaped ZnO crystals, suggesting that the crystals had the high density of oxygen vacancies.

A case report of secondary infection by Vibrio splendidus associated with gas bubble disease in syngnathid fishes (Syngnathus schlegeli and Hippocampus haema)

  • Kang, Gyoungsik;Choi, Kwang-Min;Joo, Min-Soo;Woo, Won-Sik;Park, Chan-Il
    • Fisheries and Aquatic Sciences
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    • 제25권1호
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    • pp.40-48
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    • 2022
  • Seahorses, which have been cultivated since the 2000s, are economically very important. Gas bubble disease (GBD) is a significant concern in the cultivation of seahorses; therefore, this study aimed to determine the cause of GBD-induced death in two species of Syngnathidae (Syngnathus schlegeli and Hippocampus haema). Rod-shaped bacteria were observed histopathologically and identified as Vibrio splendidus by conventional and real-time PCR analyses. The lethality of V. splendidus varies depending on the host's immune status, and the disease can be prevented through water quality management or improvement of the breeding environment. In this study, the GBD lesions (gas bubbles) were observed at 12℃, 8.0 mg/L of dissolved oxygen, 30 ppt of salinity, and pH 7.7. In addition, rod-shaped bacteria, infiltration of inflammatory cells, and extensive serous exudate were confirmed in the lesions where gas bubbles were found. PCR analysis was able to detect V. splendidus, possibly a secondary infection of the immunocompromised syngnathid fish. Understanding the risk of immunity control and the correlation between these lesions and causal agents will be of great help to the aquaculture industry and the ornamental fish market.

Analysis of microstructural characteristics and components of red and yellow ink pigments used in permanent makeup

  • Hyun Sook Jin;Byung Soo Chang
    • Applied Microscopy
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    • 제52권
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    • pp.3.1-3.8
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    • 2022
  • Our purpose in this study is to analyze the microstructural characteristics and constituent elements of inorganic substances added to the yellow ink and red ink pigments used in permanent makeup. We observed the microstructural properties of inorganic pigments added to the ink using a scanning electron microscopy (SEM) and analyzed the constituent elements of the inorganic pigment particles using an energy dispersive X-ray spectroscopy (EDX). In red wine-colored ink, cubic titanium dioxide with a diameter of 110 to 200 nm was the major component, and rod-shaped iron oxide was rarely observed. Most of the ingredients of taupe yellow ink were rod-shaped yellow iron oxide, and a small amount of cubic titanium dioxide was observed. Red wine-colored ink and taupe yellow ink contained lumps composed of titanium dioxide particles. In red wine-colored ink, lumps were formed by agglomeration. However, we observed that the surface of the lump composed of titanium dioxide in the taupe yellow ink had a smooth surface caused by external physical compression. The titanium dioxide particle mass which found in taupe yellow ink in this study is an artificial product. When this mass accumulates in the dermis, it may cause a color mismatch. Therefore, permanent makeup using fine pigments should be free of foreign substances that may cause trouble in the skin. In addition, there is a need to improve the quality of the ink so that the required color can be safe and long lasting in the dermis.

PP의 결정형성에 대한 조사가교와 LDPE 함량의 영향 (Effect of irradiation and LDPE content on crystal formation of PP)

  • 프러산터 다할;김연철
    • 한국산학기술학회논문지
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    • 제15권6호
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    • pp.4039-4045
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    • 2014
  • 전자선 조사 폴리프로필렌과 블랜드의 결정화 거동은 고분자 가공시 중요한 변수중 하나이다. 저밀도폴리에틸렌(linear low density polyethylene, LDPE) 함량에 따라 폴리프로필렌(polypropylene, PP)/LDPE 블렌드를 이축압출기를 이용하여 제조하였다. 조사에 의한 가교반응을 용이하게 하기위해 가교조제로 trimethylolpropane-trimetacrylate (TMPTMA)를 PP/LDPE 블렌드 제조시 첨가하였다. PP/LDPE 블랜드의 조사가교 효율에 대한 LDPE 함량의 영향을 평가하였다. 조사시료의 비등온 결정화과정과 결정구조를 DSC, X-선회절분석(X-ray diffraction, XRD), 그리고 편광현미경(polarized optical microscope, POM)을 이용하여 분석하였다. 조사 후 시료의 용융온도가 감소하는 것은 조사에 의한 PP 사슬의 절단에 의한 것으로 판단된다. Ozawa 지수, n이 4일 때 구형, 3일 때 디스크형, 2일 때 로드형의 결정구조를 나타낸다. Ozawa 분석 결과, 순수 PP의 n 값은 3.8, 30 wt%의 LDPE를 포함하는 시료의 n은 2.3을 나타내었다. LDPE 첨가와 조사에 의해 PP의 결정구조가 구형에서 disk나 rod형으로 변화하는 것을 Ozawa 분석과 POM을 통해 확인하였다. XRD 스펙트럼의 $16.1^{\circ}$에서 나타나는 ${\beta}$ 형 결정구조가 조사 후 시편에서 사라지는데, 이는 가교결합에 의한 것으로 해석할 수 있다.

경상남도 사천시 진주층에서 산출되는 막대기형 스트로마톨라이트 (Rod-shaped Stromatolites from the Jinju Formation, Sacheon, Gyeongsangnam-do, Korea)

  • 최종걸
    • 한국지구과학회지
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    • 제28권1호
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    • pp.54-63
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    • 2007
  • 경상남도 사천시의 백악기 육성퇴적층인 진주층에서는 다양한 종류(막대기형, 멍울형, 층형, 작은 기둥형)의 스트로마톨라이트(stromatolite)가 산출된다. 세계적 산출 경향과는 달리 막대기형 스트로마톨라이트가 대량으로 발견되었다. 이는 나뭇가지에 부착 서식하던 미세조류에 의하여 탄산염 광물이 침전하여 동심원 모앙의 엽층리를 형성하여 생성된 구조이다. EPMA를 이용하여 구성광물, 속성작용, 풍화과정의 진행을 확인했다 일반적인 스트로마톨라이트는 내지성 화석이지만 막대기형 스트로마톨라이트는 외지성 화석으로도 산출될 수 있다는 점에서 특이하다. 전형적인 스트로마톨라이트의 미세 엽층리는 막대기의 포위 부분에 있으며, 여기서 최소 두 종류의 사상체 남조세균(평균 $2.2{\mu}m$$7.8{\mu}m$ 녹조류(평균 $32.3{\mu}m$ 발견하였으며, 이 때 남조세균은 피막 건설자이고, 녹조류는 피막 보조자로 판단되었다. 일부 박테리아에서는 세포사를 발견할 수 있었다.

선형폭발성형탄(LEFP) 충격에 의한 WHA 관통자의 관통성능 감소에 관한 수치해석 연구 (Numerical Analysis on Penetration Reduction of a WHA Penetrator by an Impact of Linear Explosively Formed Penetrator(LEFP))

  • 주재현;최준홍;구만회;김동규
    • 한국군사과학기술학회지
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    • 제20권3호
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    • pp.384-392
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    • 2017
  • A linear explosively formed penetrator(LEFP) is a modification of the explosively formed penetrator(EFP). An EFP is axisymmetric and has a dish-shaped liner while LEFP has a rectangular-shaped liner with curved cross section. Upon detonating LEFP forms laterally wide projectile like blade, leaving a long penetration hole on the target. On the other hand, a long-rod tungsten heavy alloy(WHA) penetrator is one of the major threats against most of the ground armored vehicles. In this paper, the feasibility of using an LEFP in protecting against a long-rod WHA penetrator by colliding LEFP into the threat was investigated through a set of numerical simulations. In this study, a scale-down WHA penetrator with length to diameter ratio(L/D) of 10.7 and 7.0 mm diameter was used to represent a long-rod WHA penetrator. LS-DYNA and Multi-Material ALE technique were employed for the simulation. For estimation of the protection effect by LEFP, residual penetration depths into RHA by the threat were compared according to various impact locations against the threat.

고분해능 전자현미경을 이용한 Mg-6 wt%Zn-1 wt%Y 합금의 석출거동에 관한 연구 (HRTEM Study of Precipitation Behavior in Mg-6 wt%Zn-1 wt%Y Alloy)

  • 백상열;이갑호;김택수
    • 한국재료학회지
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    • 제18권7호
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    • pp.362-366
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    • 2008
  • The precipitation behavior in Mg-6 wt%Zn-1 wt%Y alloy annealed at different temperatures of $200^{\circ}C$ and $400^{\circ}C$ has been characterized by high resolution transmission electron microscope. When the alloy is annealed at $200^{\circ}C$ for 6 hr, the plate- and the rod-shaped ${\beta}_2'$ phases are precipitated in the matrix. The orientation relationship of plate-shaped precipitates with the matrix exhibits a [$11{\bar{2}}0]{\beta}_2$ || [$10{\bar{1}}0$]Mg, $(0001){\beta}_2'$ || (0001)Mg. While the rod-shaped precipitates have two kinds of the orientation relationships with the matrix, i.e. $[11{\bar{2}}0]{\beta}_2'$||[0001] Mg, $(0001){\beta}_2'||(11{\bar{2}}0)$ Mg and $[11{\bar{2}}0]{\beta}_2'$||[0001] Mg, $({\bar{1}}106){\beta}_2'||(10{\bar{1}}0)$ Mg. With increasing annealing time at $200^{\circ}C$ the ${\beta}_1'$ phases are also precipitated in the matrix and the orientation relationship exhibits a $[010]{\beta}_1'$ || [0001]Mg, $(603){\beta}_1'$ || ($01{\bar{1}}0$)Mg between the ${\beta}_1'$ precipitate and the matrix. The icosahedral phases are precipitated in the alloy annealed at $400^{\circ}C$ and exhibit a $[I2]_I$ || [0001]Mg relationship with the matrix.

Zn과 Cu 혼합 분말의 열 증발에 의하여 생성된 ZnO 결정의 형상 변화 및 발광 특성 (Morphological Change and Luminescence Properties of ZnO Crystals Synthesized by Thermal Evaporation of a Mixture of Zn and Cu Powder)

  • 이근형
    • 한국재료학회지
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    • 제28권10호
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    • pp.578-582
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    • 2018
  • ZnO crystals with different morphologies are synthesized through thermal evaporation of the mixture of Zn and Cu powder in air at atmospheric pressure. ZnO crystals with wire shape are synthesized when the process is performed at $1,000^{\circ}C$, while tetrapod-shaped ZnO crystals begin to form at $1,100^{\circ}C$. The wire-shaped ZnO crystals form even at $1,000^{\circ}C$, indicating that Cu acts as a reducing agent. As the temperature increases to $1,200^{\circ}C$, a large quantity of tetrapod-shaped ZnO crystals form and their size also increases. In addition to the tetrapods, rod-shaped ZnO crystals are observed. The atomic ratio of Zn and O in the ZnO crystals is approximately 1:1 with an increasing process temperature from $1,000^{\circ}C$ to $1,200^{\circ}C$. For the ZnO crystals synthesized at $1,000^{\circ}C$, no luminescence spectrum is observed. A weak visible luminescence is detected for the ZnO crystals prepared at $1,100^{\circ}C$. Ultraviolet and visible luminescence peaks with strong intensities are observed in the luminescence spectrum of the ZnO crystals formed at $1,200^{\circ}C$.

수열합성법에 의한 정렬된 ZnO 나노로드 구조의 합성 (Synthesis of Aligned ZnO Nanorod Arrays via Hydrothermal Route)

  • 구진희;이병우
    • 한국표면공학회지
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    • 제49권5호
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    • pp.472-476
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    • 2016
  • The nano-array of the vertically aligned rod-like particles grown on ZnO coated glass-substrates was obtained via hydrothermal process. ZnO thin film coatings were prepared on the glass substrates using a MOD (metallorganic deposition) dip-coating method with zinc chloride dihydrate as starting material and 2-ethylhexanol as solvent. ZnO nanorods were synthesized on the seeded substrates by hydrothermal method at $80^{\circ}C$ using zinc-nitrate hexahydrate as a Zn source and sodium hydroxide as a mineralizer. Under the hydrothermal condition, the rod-like nanocrystals were easily attaching on the already ZnO seeded (coated) glass surface. It has been shown that the hydrothermal synthesis parameters are key factors in the nucleation and growth of ZnO crystallites. By controlling of hydrothermal parameters, the ZnO particulate morphology could be easily tailored. Rod-shaped ZnO arrays on the glass substrates consisted of elongated crystals having 6-fold symmetry were predominantly developed at high Zn precursor concentration in the pH range 7~11.

주행시 궤도차량 바닥판의 위상최적설계에 관한 연구 (A Study on Topology Optimization of the Tracked Vehicle Bottom Plate under Traveling Loading)

  • 황영진;김종범;이석순;최창곤;손재흥
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 춘계학술대회
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    • pp.558-563
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    • 2003
  • The tracked vehicle travel on off rod and on rod. So the tracked vehicle need a sufficient stiffness and a lightweight. In this study we performed FEA for the track vehicle and performed topology optimization based on the results of FEA. The displacements of road wheel are used as displacement constraint for topology optimization. We performed topology optimization with the control of the frame size which is the results of topology optimization and suggested the shaped of the tracked vehicle bottom plate of topology optimization

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