• Proceedings of the Optical Society of Korea Conference
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• 1991.06a
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• pp.172-176
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• 1991

4d 전이원소인 rhodium을 phosphate 유리에 첨가하여 광흡수 및 photoluminescence 스펙트럼을 측정하였다. 이로써 rhodium 이온의 tunable solid state laser용의 광활성 이온으로서의 가능성을 조사하였다.

• Journal of the Korean Chemical Society
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• v.45 no.1
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• pp.25-30
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• 2001

A selective kinetic fluorimetric method for the determination of trace rhodium(Ⅲ), based on the catalytic effect of rhodium(Ⅲ) on the oxidation of nile blue by periodate have been studied. The effects of pH and concentrations of nile blue, sodium periodate, trioctyl phosphine oxide(TOPO) and temperature were investigated. The calibration curve for rhodium(Ⅲ) ion was linear over the range from 100 ng/mL to 0.1 ng/mL and the detection limit was 0.01 ng/mL under the optimal experimental conditions. Effects of interferences from several cations and anions for the determination of rhodium(Ⅲ) were also investigated.

• Transactions of Materials Processing
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• v.27 no.4
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• pp.244-249
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• 2018

Rhodium is a representative platinum group material. Rhodium is used in several industrial fields including jewelry, chemical reaction catalyst, electric component etc. In recently, ultra-fine rhodium wire has been applied to the pins of probe card used to test a semiconductor. In this study, in order to produce a fine rhodium wire with the diameter of $50{\mu}m$, a fine rhodium wire drawing process was designed. After design of the fine wire drawing process by using a uniform reduction ratio theory, finite element analysis was performed. Finally, fine wire drawing experiment was performed to verify the effectiveness of the designed process.

• Nuclear Engineering and Technology
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• v.37 no.6
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• pp.605-610
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• 2005

A method to estimate the relative sensitivity of a self-powered rhodium detector for an upcoming cycle is developed by combining the rhodium depletion data from a nuclear design with the site measurement data. This method can be used both by nuclear power plant designers and by site staffs of Korean standard nuclear power plants for determining which rhodium detectors should be replaced during overhauls.

• Korean Journal of Optics and Photonics
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• v.4 no.2
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• pp.220-225
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• 1993

This is the first reported observation of absorption and emission of glasses with a 4d transition metal ion(rhodium). The optical absorption and photoluminescence spectra, and the lifetimes of rhodium ions in phosphate glasses are interpreted on the basis of strong-field scheme of Sugano-Tanabe diagram. We conclude that rhodium ion is present in its divalent form. $^2 E{\rightarrow}^2 T_1$ and $^2 E{\rightarrow}^2 T_2$ transitions are superimposed and observed at 460 nm. Whereas $^2 T_1{\rightarrow}^2 E$ and $^2 T_1{\rightarrow}^2 E$ transitions are observed at 650 nm and 580 nm, respectively.

• Nuclear Engineering and Technology
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• v.33 no.2
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• pp.121-131
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• 2001

An investigation of the sensitivity depletion laws for rhodium SPNDs was performed to reduce the uncertainty of the sensitivity depletion laws used in Combustion Engineering (CE) reactors and to develop calculational tools that provide the sensitivity depletion laws to interpret the signal of the newly designed rhodium SPND into the local neutron flux. The calculational tools developed in this work are computer programs for a time-dependent neutron flux distribution in the rhodium emitter during depletion and for a time-dependent beta escape probability that a beta particle generated in the emitter escapes into the collector. These programs provide the sensitivity depletion laws and show the reduction of the uncertainty by about 1 % compared to that of the method employed by CE in interpreting the signal into the local neutron flux. A reduction in the uncertainty by 1 % in interpreting the signal into the local neutron flux reduces the uncertainty tv about 1 % in interpreting the signal into the local power and lengthens the lifetime of the rhodium SPND by about 10% or more.

• Archives of Pharmacal Research
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• v.1 no.1
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• pp.1-6
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• 1978

Rhodium (II) (isobutyrate)$_{4}L_2$, an antinumor drug, was shown to reactr with nucleic acid base derivatives, A, G, U and C in chloroform solution. When these derivatives were treated with one of novel metal compounds, rhodium carboxylate in chloroform solution, a fairly strong complex formation was observed by spectroscopic techniques. The characteristic of these complex was that binding occured at the two axial positions of rhodium (II) (isobutyrate)$_{4}L_2$ to the NH or )$NH_2$ group of the base in the ligands.

• Bulletin of the Korean Chemical Society
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• v.28 no.11
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• pp.1919-1920
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• 2007

• Applied Biological Chemistry
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• v.40 no.6
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• pp.588-592
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• 1997

The new type ligand, bisphosphonites, were easily prepared through ligand exchange reaction of bis (diethylamino)phosphine with diols. These bisphosphonites reacted with $(COD)^2Rh^+BF_4\;^-$ to corresponding bisphosphonite-rhodium(I) comlexes, of which X-ray crystallography was for the first time investigated. This organometallic compound was applicated in hydroformylation reaction as catalyst, and proved to be very effective one.

• Bulletin of the Korean Chemical Society
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• v.29 no.9
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• pp.1787-1789
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• 2008