• 유변학
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• 제9권2호
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• pp.73-80
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• 1997

분말 입자 형태가 다른 2가지 스테인레스 강(SUS 316L)분말과 조성이 다른 2가지의 결합제를 이용하여 분말충전율의 변화를 가지도록 제조된 5가지 분말사출재에 대한 Bagley 보정 실험을 실시하여 Bagley 보정값에 대한 온도, 분말충전율, 분말 입자 형태 그리고 결 합제의 영향을 조사하였다. Bagley 보정값을 구하기 위한 자료 처리를 하는 과정에서 길이 가 긴 모세관(L/D=60) 의 압력손실이 Thixotropy에 의해서 감소한 현상을 발견하였다. 이는 모세관 점성측정기를 이용한 분말사출제의 점도 측정시 길이가 긴모세관의 사용이 바람직하 지 못하다는 것을 나타낸다. 분말사출재의 Bagley 보정값에 대한 온도와 결합제의 영향은 매우 미약하게 나타났는데 특히 결합제의 영향은 거의 나타나지 않는 것을 발견하였다. 분 말충전율과 분말 입자 형태의 Bagley 보정값에 대한 영향은 매우 크게 나타났으며 분말충 전율이 증가할수록 Bagley 보정값이 증가하고 분말 입자의 형태가 불규칙한 분말을 사용한 분말사출재의 보정값이 구형의 분말에 비해 높은 보정값을 나타냈다. 실험결과에 대한 고찰 결과, 분말사출재의 모세관 입출구에서 압력손실의 주 원인은 분말 이자간 마찰과 충돌이라 고 판단되었다.

• Korea-Australia Rheology Journal
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• 제19권4호
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• pp.227-232
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• 2007

The use of various shearing apparatuses to study the phase behavior of poly(styrene-b-isoprene) diblock copolymer micelles is described. A DMTA rheometer was modified so that one can apply oscillatory shear and obtain the scattering pattern along the shear gradient direction. A cone and plate shear cell was designed to access scattering along the shear vorticity direction, and both oscillatory and steady shear can be applied. The most popular way to employ steady shear on relatively low viscosity fluids is to use a Couette cell, because a high shear rate can be readily achieved without disturbing the sample by overflow. In this work, oscillatory shear was used to obtain a single crystal-like scattering pattern, and thereby to examine the mechanism of the thermotropic transition between face-centered cubic (fcc) and body-centered cubic (bcc) lattices. By applying the steady shear, the response of the fcc lattices to various shear rates is discussed.

• Korea-Australia Rheology Journal
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• 제12권3_4호
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• pp.181-186
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• 2000

Rheological Properties of polypropylenes having different molecular structures (linear polypropylene (PPL) and branched one (PPB)) were studied. Both the extensional flow and oscillatory shear flow properties were checked. Especially, the melt strength of polypropylenes having various shear history were investigated by using in-house-made Rheometer (called SMER). Compared to linear polypropylene, the branched polypropylene shows enhanced melt strength during extensional flow due to the retarded relaxation of molecules. When the slope of melt tension was plotted against take up speed of melt strand, the characteristic peak was observed in case of branched polypropylene, while the linear polypropylene shows only monotonously decreasing pattern. This entanglement was partially disrupted by physical forces such as shear during melt extrusion. However, the melt strength of PPB after multiple extrusion is still higher than PPL, implying the loss of elasticity during multiple extrusion is not so comprehensive. On dynamic experiments, PPB shows typical shear thinning behavior and the tangent delta of PPB is lower than PPL, reflecting high elasticity of PPB.

• Korea-Australia Rheology Journal
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• 제16권3호
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• pp.153-160
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• 2004

Open microcellular foams having small-sized cell and good mechanical properties are desirable for many practical applications. As an effort to reduce the cell size, the microcellular foams combining viscosity improvers into the conventional formulation of styrene and water system were prepared via high internal phase emulsion polymerization. Since the material properties of foam are closely related to the solution properties of emulsion state before polymerization, the flow behavior of emulsions was investigated using a controlled stress rheometer. The yield stress and the storage modulus increased as viscosity improver concentration and agitation speed increased, due to the reduced cell size reflecting both a competition between the continuous phase viscosity and the viscosity ratio and an increase of shear force. Appreciable tendency was found between the rheological data of emulsions and the cell sizes of polymerized foams. Cell size reduction with the concentration of viscosity improver could be explained by the relation between capillary number and viscosity ratio. A correlative study for the cell size reduction with agitation speed was also attempted and the result was in a good accordance with the hydrodynamic theory.

• Korea-Australia Rheology Journal
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• 제16권3호
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• pp.129-134
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• 2004

The aggregation characteristics of red blood cells (RBCs) were measured using a newly developed light-transmission slit rheometer. Conventional methods of RBC disaggregation such as the rotational Couette system were replaced with a pressure-driven slit flow system with a vibrational mechanism. Using a vibration generator, one can disaggregate the RBC aggregates stored in the slit. While shear stress decreases exponentially, instantaneous pressure and the transmitted light intensity were measured over time. Applying an abrupt shearing flow after disaggregation caused a rapid elongation of the RBCs followed by loss of elongation with the decreasing shear stress. While the shear stress is further decreasing, the RBCs start to re-aggregate and the corresponding transmitted intensity increases with time, from which the aggregation indices can be obtained using a curve-fitting program.

• International Journal of Industrial Entomology and Biomaterials
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• 제27권1호
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• pp.180-184
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• 2013

Recently, silk sericin has attracted the attention of researchers owing to its useful properties as a biomaterial including 1) good wound healing and cell activities, 2) fast gelation character, and 3) high water retention property. In the present study, silk sericin was prepared using different extraction times in hot water and the effect of extraction time on the rheological properties of sericin solutions and gels was examined. It was found that the production yield of sericin increased with extraction time. The shear viscosity of sericin solutions and gels decreased with increasing extraction time due to a decrease in sericin molecular weight. When the sericin solution transformed to a gel, the viscosity increased and the shear thinning behavior was more evident. In addition, the shear stress measurements indicated that the slip between the sericin samples and the measuring plate of the rheometer was increased by the gelation of sericin. The compression strength of sericin gel could be increased remarkably (by more than 100 fold) by preparation using the freezing and thawing method.

• 한국인쇄학회:학술대회논문집
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• 한국인쇄학회 2007년도 추계 학술논문 발표회
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• pp.1-12
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• 2007

The rheological properties of an ink relate to its performance on the press and to the printing quality. So it is necessary to analyze the relationship between printability and the rheological properties of ink. Transfer rate of ink is one of the important factor deciding print quality. And it is concerned with rheological properties of ink. Thus, in this study, according to the molecular weight of rosin modified phenolic resin the rheological properties of ink were measured by rotational rheometer and then transfer equation of ink, density and gloss were mesured in order to examine the printability of ink.

• 한국식생활문화학회지
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• 제12권5호
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• pp.561-565
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• 1997

This study was done to develop the standard recipe for nutritious cowpea starch based grape jelly. The effects of grape juice concentration (4, 8, 12%) and 0.2% calcium addition were evaluated on textural and sensory properties of grape jelly through the instrumental analysis using rheometer and sensory evaluation. Instrumental analysis showed that hardness, chewiness and gumminess of grape jelly was incerased significantly In jelly made of higher concentration of grape juice, and also in 0.2% calcium containing jelly. According to sensory evaluation, higher grape juice contains jelly showed advantages in preference of color and overall quality. Calcium addition increased sourness in sensory score. Overall, 12% grape juice and 0.2% calcium containing jelly was most preferable, which means calcium fortified cowpea starch based grape jelly was successful try for nutritious and practical food for elementary school foodservice.

• Advances in concrete construction
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• 제5권3호
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• pp.183-199
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• 2017

This paper reports an experimental study into the rheological behaviour of Smart Dynamic Concrete (SDC). The investigation is aimed at quantifying the effect of the varying amount of mineral admixtures on the rheology, setting time and compressive strength of SDC containing natural sand and crushed sand. Ordinary Portland cement (OPC) in conjunction with the mineral admixtures was used in different replacement ratio keeping the mix paste volume (35%) and water binder ratio (0.4) constant at controlled laboratory atmospheric temperature ($33^{\circ}C$ to $35^{\circ}C$). The results show that the properties and amount of fine aggregate have a strong influence on the admixture demand for similar initial workability, i.e., flow. The large amounts of fines and lower value of fineness modulus (FM) of natural sand primarily increases the yield stress of the SDC. The mineral admixtures at various replacement ratios strongly contribute to the yield stress and plastic viscosity of SDC due to inter particle friction and cohesion.

• Elastomers and Composites
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• 제17권4호
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• pp.215-225
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• 1982

The purpose of this study is to get comparitive results on the combined accelerator systems comprised of MBT, MBTS, DPG and CBS with TMTD, TMTM and Zn-MDC to SBR compound. Vulcanization characterstics and physical properties of the combined accelerators have been studied by means of the Mooney viscometer, the Monsanto disc rheometer, tensile testing machine, aging chamber and so on. According to the test results, DPG, MBT and Zn-MDC system have show faster Mooney scorch time and optimum cure time than other systems. The Vulcanizate comprise of DPG, MBT and TMTD accelerator system has taken adventage of tensile strength, elongation, 100% modulus, resilience, compresion set.