• Title/Summary/Keyword: Reverse rate coefficients

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Expansion of the equilibrium constants for the temperature range of 300K to 20,000K

  • Kim, Jae Gang
    • International Journal of Aeronautical and Space Sciences
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    • v.17 no.4
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    • pp.455-466
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    • 2016
  • Chemical-kinetic parameters of the equilibrium constants to evaluate the reverse rate coefficients in the shock layer of a blunt body and the expanding flows are derived for the temperature range from 300 K to 20,000 K. The expanded equilibrium constants for the chemical reactions of the dissociation, ionization, associative ionization, and neutral and charge exchange reactions of the atmospheric species and carbon materials are proposed in the present work. In evaluating the equilibrium constants, the inter-nuclear potential energies of the molecular species are calculated by the analytical potential function of the Hulburt-Hirschfelder model, and the parameters of the analytical model are determined from the semi-classically calculated RKR potentials. The electronic states and energies of the atoms are calculated by the electronic energy grouping model, and the rovibrational states and energies of each electronic states of the molecules are evaluated by the WKB method. The expanded equilibrium constants for 31 types of the reactions are provided for the best curve-fit functions, and the recombination reaction rate coefficients evaluated from the present equilibrium constants are compared with existing measured values.

Scaling predictions in seawater reverse osmosis desalination

  • Hchaichi, Houda;Siwar, Saanoun;Elfil, Hamza;Hannachi, Ahmed
    • Membrane and Water Treatment
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    • v.5 no.3
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    • pp.221-233
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    • 2014
  • Simulations were conducted to predict supersaturation along Reverse Osmosis (RO) modules for seawater desalination. The modeling approach is based on the use of conservation principles and chemical equilibria equations along RO modules. Full Pitzer ion interactive forces model for concentrated solutions was implement to calculate activity coefficients. An average rejection rate for all ionic species was considered. Supersaturation has been used to assess scaling. Supersaturations with respect to all calcium carbonate forms and calcium sulfate were calculated up to 50% recovery rate in seawater RO desalination. The results for four different seawater qualities are shown. The predictions were in a good agreement with the experimental results.

Numerical Study on Reverse Flow Charcteristics in an Axial Compressor Cascade (축류압축기 익렬에서의 역류 유동 특성에 대한 수치적 연구)

  • Sohn, Chang-Hyun;Longley, John Peter
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.5
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    • pp.615-622
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    • 2000
  • Numerical simulation is performed with Denton's code to get pressure loss coefficients in wide range of reverse flow incidence(from -90 degree to +85 degree) for an axial compressor cascade. As a results, it is found that the pressure loss coefficient is increased with incidence and there exist critical incidence which corresponds to the maximum pressure loss coefficient. Pressure loss coefficient with bigger incidence than its critical value is decreased. The effect of increasing incidence in a cascade extremely reduce the mass flow rate by the large flow separation region. Consequently this effect reduce the portion of dynamic pressure in the total pressure loss and beyond the critical incidence the pressure loss coefficient decrease.

INFLUENCE OF HALL CURRENT AND HEAT SOURCE ON MHD FLOW OF A ROTATING FLUID IN A PARALLEL POROUS PLATE CHANNEL

  • VENKATESWARLU, M.;UPENDER REDDY, G.;VENKATA LAKSHMI, D.
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.22 no.4
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    • pp.217-239
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    • 2018
  • This paper examined the MHD and thermal behavior of unsteady mixed convection flow of a rotating fluid in a porous parallel plate channel in the presence of Hall current and heat source. The exact solutions of the concentration, energy and momentum equations are obtained. The influence of each governing parameter on non dimensional velocity, temperature, concentration, skin friction coefficient, rate of heat transfer and rate of mass transfer at the porous parallel plate channel surfaces is discussed. During the course of numerical computation, it is observed that as Hall current parameter and Soret number at the porous channel surfaces increases, the primary and secondary velocity profiles are increases while the primary and secondary skin friction coefficients are increases at the cold wall and decreases at the heated wall. In particular, it is noticed that a reverse trend in case of heat source parameter.

Prediction of Phosphorus Transport from Sediment and Development of Phophorus Control Technology - I. Prediction of Phosphorus Transport from Sediment (저질토로부터의 인의 용출거동 예측 및 제어기술 개발 - I. 저질토로부터의 인의 용출거동 예측)

  • Lee, Jung-Yub;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.13 no.2
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    • pp.89-94
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    • 1999
  • In this study small glass columns with 2.5cm inner diameter and 24.5cm length were used as many as the sample numbers to study the effects of initial pH, temperature, dissolved oxygen concentration, and sediment depth on the release of phosphorus from lake sediment. No phosphorus release occurred at $10^{\circ}C$ with all pHs, and release rate at $25^{\circ}C$ was higher than that at $35^{\circ}C$ with pH 4 and reverse trends were observed at pH 7 and 10. Under all conditions, DO concentrations were decreased and equilibrium was obtained after 4-8 days when phosphorus release started and the Do concentrations were less than 1 mg/l. Sediment depth had little effect on phosphorus release rate. It was found that relation between released SRP(Soluble Reactive Phosphorus) concentration and time was zero order reaction and reaction rate coefficients were obtained. The amount of phosphorus release from lake sediment can be predicted by considering these k values.

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Determination of Ginseng Saponins by Reversed-Phase High Performance Liquid Chromatography (역상 고속액체크로마토그라피를 이용한 홍삼 사포닌의 정량)

  • Kim, Cheon-Suk;Kim, Se-Bong
    • Korean Journal of Medicinal Crop Science
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    • v.9 no.1
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    • pp.21-25
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    • 2001
  • Major saponins in ginseng were analysed using reverse phase high performance liquid chromatography with binary mobile phase gradient control system instead of normal phase column. The optimum condition were as following : reverse phase column; ${\mu}{\beta}ondapak\;C_{18}$ column (Waters, $3.9mm{\times}300\;mm,\;5{\mu}m$), methyl cyanaide/water binary mobile phase gradient control system, solvent flow rate; 1.5 ml/min, and UV($203{\mu}m$ ) detector. The complete separation of ginsenoside $Rb_1,\;Rb_2,\;Rc,\;Rd,\;Re,\;Rf\;and\;Rg_1$ was achieved within 55 min. The Regression coefficients of the calibration curves for seven ginsenosides were 0.99.

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A Study on the Flow Characteristics inside a Glove Valve for Ships (선박용 글로브 밸브의 유동특성에 관한 연구)

  • Bae, Ki-Hwa;Park, Jea-Hyoun;Kang, Sang-Mo
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.1
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    • pp.110-118
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    • 2008
  • It is essential for the valid design of a marine flow-control valve to exactly know its flow characteristics. The present study has numerically investigated the flow characteristics inside a marine throttle-type globe valve using a kind of commercial CFD code, CFX10.0, with an adoption of the SST (Shear-Stress Transport) turbulence model. To validate the numerical approach, the flow coefficients are compared with the experimental ones. Results show that the globe valve is effective in the control of flow rate according to the opening ratio in case of the forward-direction flow, whereas it is effective in the flow shutoff in case of the reverse-direction flow. Around the inlet of the valve, a recirculation region is formed due to the blunt body shape, the turbulence intensity becomes strengthened and then an abrupt pressure loss occurs.

Determination of Ginseng Saponins by Reversed-Phase High Performance Liquid Chromatography (역상 고속 액체크로마토그래피를 이용한 인삼 사포닌의 분석)

  • Jeong, Seung-Il;Kim, Choen-Suk;Lee, No-Woon;Choi, Kang-Ju;Lee, Yong-Gu;Kim, Il-Kwang
    • Analytical Science and Technology
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    • v.11 no.6
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    • pp.436-439
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    • 1998
  • Ginseng saponins were analysed using reversed-phase high performance liquid chromatography with several columns. The optimum conditions were as following : reverse phase column; Novapak $C_{18}$ ODS column ($3.9mm{\times}150mm$, $5{\mu}m$), acetonitrile/water binary mobile phase gradient controller system, solvent flow rate; 1.5 mL/min, and UV (203 nm) detector. The complete separation of ginsenoside $Rb_1$, $Rb_2$, Rc, Rd, Re, Rf and $Rg_1$ was achieved within 50 min. The regression coefficients of the calibration curves for seven ginsenosides were 0.98~0.99.

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A Prognosis Evaluation after Iliac Bone Graft in Cleft Alveolus Patients (치조열 환자의 장골이식술 후 예후 평가)

  • Hong Jin-Ho;Soh Byung-Soo;Baik Jin-Ah;Shin Hyo-Keun
    • Korean Journal of Cleft Lip And Palate
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    • v.4 no.2
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    • pp.69-78
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    • 2001
  • Alveolar cleft exists in 75% of cleft patients, In alveolar cleft patients, alar base is widening, palatal fistular formation, maxillary growth disturbance & tooth loss of adjacent area is raised, Alveolar bone grafting, especially iliac bone grafting, is a general treatment method. As operation timing, bone grafting is classified with primary, early secondary, secondary, & late secondary, Here we report cleft width, marginal bone height, bone resorption rate, grafted shape & bone densities after secondary iliac bone grafting was done in the Dept. of oral and maxillofacial surgery of chonbuk national university hospital. We compared cleft width to bone resorption rate and grafted shape. Also, alveolar bone densities of grafted and contralateral site was compared with Emago 3 package? (Oral Diagonostic System, The Netherlands), The data obtained were analyzed using Spearman's rho coefficients and sign test with SPSS for window, The results were obtained as follows. 1. As alveolar cleft width is increase, bone resorption rate is, too. This relation showed significant difference(P<.01). 2, In proximal & distal area, alvolar cleft width and bone graft contour after bone grafting had a reverse proportional difference. It was not significant difference(P>.05). 3. After 3 month, in bone density results by using Emago 3 package? with periapical standard view, occlusal view & panoramic view, differences between grafted bone and alveolar bone of contralateral site didn't show a significant difference(P>.05). Thus, differences of bone densities in the alveolar bones didn't exist.

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The Relationship of the Expressions of Stress-related Markers and Their Production Performances in Korean Domestic Chicken Breed (닭의 스트레스 연관 표지인자들의 발현도와 생산능력 간의 상관 분석)

  • Park, Ji Ae;Cho, Eun Jung;Choi, Eun Sik;Hong, Yeong Ho;Choi, Yeon Ho;Sohn, Sea Hwan
    • Korean Journal of Poultry Science
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    • v.43 no.3
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    • pp.177-189
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    • 2016
  • This study was conducted to verify the relationships between the expression values of stress-related markers and their production performances in 25 strains of Korean domestic chicken breeds. For stress response markers, the amount of telomeric DNA; expression levels of heat shock protein (HSP)-70, $HSP-90{\alpha}$, and $HSP-90{\beta}$; and comet scores were analyzed. Production performances were measured by the survival rate, body weights, days at first egg laying, egg weight and hen housed egg production. The results showed that the production traits and values of stress-related markers showed significant differences between strains. In general, the stress response of pure bred chickens with heavy weights was relatively high, while that of hybrid chickens with light weights was relatively low. The correlation coefficients between telomere contents and body weights showed that there were weak negative relationships. However, the correlations of telomere content with the survival rate and egg production were weakly positive after 20 weeks old. The expression levels of HSP genes and DNA damage rate (comet scores) were positively correlated to body weight, but were negatively correlated to the survival rate and egg production. The results implied that increasing body weight was associated with increasing HSPs expression and the DNA damage rate was associated with decreasing telomere content. In addition, increasing HSPs expression and the DNA damage rate decreased the survival rate and egg production, but the relationships with the telomere content was the reverse. Correlations among the stress-related markers showed that there were significant correlation coefficients between all of the marker values. HSPs expression was negatively correlated to the telomere content, while it was positively correlated to the DNA damage rate. There was a highly negative correlation between the telomere content and DNA damage rate. In conclusion, increasing the HSP values and DNA damage rate can promote telomere reduction, which led to a decrease in disease resistance and robustness of the chicken. Thus, increasing the stress response was verified to adversely affect the laying performance and viability of chickens.