• 제목/요약/키워드: Reverse Diffusion

검색결과 95건 처리시간 0.024초

막분리 기술을 위한 액체염료 제조에 관한 연구 (Preparation of Storage-Stable Liquid Dyes by Membrane Separation Technology)

  • 조정희;이정학
    • 공업화학
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    • 제3권2호
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    • pp.349-359
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    • 1992
  • 염료속에 함유된 무기염(NaCl, $Na_2SO_4$)의 선택적 제거를 위해 역확산과 역삼투를 결합한 방법과 nanofiltration(NF)을 각각 이용하였다. 역확산에 의한 염의 제거율은 염의 종류에 따라 1회(one pass)에 1~30%를 나타냈으며 염과 염료의 분리비는 10~500의 매우 큰 값을 갖는 반면 염료의 손실율은 0.3% 이하였다. 염료용액을 순환시킬수록 음이온인 $Cl^-$ 이온의 제거율이 증가하고 양이온인 $Na^+$ 이온의 제거율이 감소하는 도난투석현상이 관찰되었다. 또한 공급용액의 유속이 염의 제거에 미치는 영향을 살펴보았다. 역확산에 의해 염이 제거된 염료를 평판형 역삼투막을 사용하여 농축하였으며 $Cl^-$ 이온의 배제율을 solution-diffusion 모델식에 적용하였다 2회의 Diafiltration(DF)을 수행한 NF에서도 역확산에서와 마찬가지로 도난투석에 의해 $Cl^-$ 이온의 배제율 감소와 음배제율을 관찰하였다. 특히 두번째 DF에서 도난투석의 효과는 더욱 크게 나타났다.

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공기중 유기용제 측정을 위한 활성탄섬유 확산포집기와 3M 확산포집기의 시료포집효율에 대한 연구 (Sampling efficiencies of the activated carbon fiber and 3M diffusive samplers for organic vapors)

  • 변상훈;오세민;이창하
    • 한국산업보건학회지
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    • 제7권1호
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    • pp.21-31
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    • 1997
  • Toluene, n-hexane, and methyl ethyl ketone(MEK) were exposed to the activated carbon fiber(ACF) and 3M(Model 3500) diffusive samplers under low and high humidity levels. In order to evaluate these two samplers, the sampling capacity, sampling rate, reverse diffusion, and storage stability were obtained. At low humidity level($8{\pm}3%RH$), the adsorption amount of all three organic vapors to the ACF diffusive sampler showed a positive linear relationship up to 8 hours. However, at high humidity level($90{\pm}5%RH$), n-hexane and MEK maintained a positive linear relationship up to 1.5 hrs, but decreased in their adsorption amounts afterwards. On the other hand, the adsorption amount of n-hexane, MEK, and toluene to 3M diffusive sampler showed almost a positive linear relationship up to 8 hours at both humidity levels. At low humidity level, there was almost no reverse diffusion for both 3M and ACF diffusive samplers. However, when the ACF diffusive sampler was used at high humidity level, there was about 52.63% of MEK sample loss and about 92.59% of n-hexane sample loss. The storage stabilities of the ACF and 3M diffusive samplers were both relative stable except for MEK. In the case of MEK, the difference between the analysis of the organic vapor right after the sampling and that of 3 weeks later at room temperature was 45% for the ACF diffusive sampler and 18% for the 3M diffusive sampler. Since the storage stability of the samples stored in a refrigerator was relatively stable, they need to be refrigerated until the analysis is done.

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진공 Hot Press법에 의한 TiNi/6061Al 지적 복합재료의 확산층 형성거동 (Behavior of Diffusion Layer Formation for TiNi/6061Al Smart Composites by Vacuum hot Press)

  • 박광훈;박성기;신순기;이준희
    • 한국재료학회지
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    • 제12권12호
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    • pp.955-961
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    • 2002
  • 2.7vol%TiNi/6061 Al composites with TiNi shape memory alloy as reinforcement were fabricated by vacuum hot press. It was investigated by OM, SEM, EPMA and XRD analysis for the behavior of diffusion layer formation on various heat treatment condition. Thickness of diffusion layer was increased proportionally according to heat treatment time. The layer was formed by the mutual diffusion of TiNi and Al. The diffusion rate from TiNi fiber to Al matrix was faster than that of reverse diffusion path. The more diffused layer was formed in Al matrix. The diffusion at interface layer was consisted of $A1_3$Ti, $Al_3$Ni analyzed by EPMA, XRD results.

Carbon and Cobalt Diffusion in Liquid Phase Sintering of WC-Co with Gradient Composition

  • Park, Dong-Kyu;Kim, Ki-Won;Jung, Woo-Hyun
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.635-636
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    • 2006
  • In this study, the diffusion behaviors of C and Co in liquid phase sintering of WC-Co system were investigated whether these two components diffused in the same direction in case of having opposite gradient each other with not being $\eta$ phase. The green compacts with controlled compositions in not being of $\eta$ phase and gradient composition which one is WC-5Co-1.2%C, the other is WC-XCo-0.2%C (where X = 5, 10, 15, 20, 25) were sintered at $1350^{\circ}C$ and $1400^{\circ}C$ and then the diffusion behaviors of C and Co were investigated by analyses of compositional change, also determined for microstructure and microhardness. Also, same testing was carried out on the specimens with dual layers sintered in upright and reverse positions to evaluate the effect of gravity on the diffusion in liquid Co. From the results of this study, we can find the fact that the direction of diffusion for C and Co in WC-Co system during liquid phase sintering was different and the effect of gravity for the liquid was insignificant. Also other physical properties were changed on the diffusion of elements.

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Polyamide 역삼투막의 투과성능과 막 이동 모델의 해석 (Interpretation of Permeation Characteristics and Membrane Transport Models Through Polyamide Reverse Osmosis Membrane)

  • 김노원;김영길;이용택
    • 멤브레인
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    • 제14권1호
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    • pp.75-84
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    • 2004
  • 폴리아미드계 역삼투 분리막의 투과성능을 비교하기 위하여 NaCl과 NaOCl을 함유하는 혼합용액을 공급수로 사용하여 연속운전과 단속운전 하에서 실험하여 보았다. 이 결과를 가지고 막 이동 모델의 선택적 적용이 가능함을 제시하고자 하였으며 투과 성능 분석 결과, 용액 확산 모델과 선흡착-모세관이동 모델이 운전 모드에 따라 상대적으로 유용함을 볼수 있었다. 연속 운전에서는 선흡착-모세관이동 모델을, 단속 운전에서는 용액 확산 모델을 따름을 알 수 있었다 NaOCl에 의한 표면 변화를 SEM 사진을 통하여 확인 할 수 있었다. 연속운전 후의 막은 염소 투과 결과 표면에서 부분적인 ridge and valley 구조가 나타났으며 단속 운전 후의 막은 표면 전반에서 변성이 일어난 것을 볼 수 있었다.

Effects of Electrostatic Discharge Stress on Current-Voltage and Reverse Recovery Time of Fast Power Diode

  • Bouangeune, Daoheung;Choi, Sang-Sik;Cho, Deok-Ho;Shim, Kyu-Hwan;Chang, Sung-Yong;Leem, See-Jong;Choi, Chel-Jong
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제14권4호
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    • pp.495-502
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    • 2014
  • Fast recovery diodes (FRDs) were developed using the $p^{{+}{+}}/n^-/n^{{+}{+}}$ epitaxial layers grown by low temperature epitaxy technology. We investigated the effect of electrostatic discharge (ESD) stresses on their electrical and switching properties using current-voltage (I-V) and reverse recovery time analyses. The FRDs presented a high breakdown voltage, >450 V, and a low reverse leakage current, < $10^{-9}$ A. From the temperature dependence of thermal activation energy, the reverse leakage current was dominated by thermal generation-recombination and diffusion, respectively, at low and high temperature regions. By virtue of the abrupt junction and the Pt drive-in for the controlling of carrier lifetime, the soft reverse recovery behavior could be obtained along with a well-controlled reverse recovery time of 21.12 ns. The FRDs exhibited excellent ESD robustness with negligible degradations in the I-V and the reverse recovery characteristics up to ${\pm}5.5$ kV of HBM and ${\pm}3.5$ kV of IEC61000-4-2 shocks. Likewise, transmission line pulse (TLP) analysis reveals that the FRDs can handle the maximum peak pulse current, $I_{pp,max}$, up to 30 A in the forward mode and down to - 24 A in the reverse mode. The robust ESD property can improve the long term reliability of various power applications such as automobile and switching mode power supply.

코히어런트 화염면 모델을 이용한 스트레치 층류 확산 화염의 수치 계산 (Calculation of Stretched Laminar Diffusion Flame Using the Coherent Flame Sheet Model)

  • 정진은;진영욱
    • 한국자동차공학회논문집
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    • 제8권1호
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    • pp.17-22
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    • 2000
  • The transient process simplified by the 1-D stretched laminar flame formed at the fuel-oxidizer interface was investigated using the coherent flame sheet model. Under the combustion environment of high temperatures and pressures the results show that the time required to reach the steady state was relatively short compared to the reverse of strain rate. Hence the employment of the tabulation of precalculated steady-flame results in the calculation of turbulent diffusion flames using the coherent flame sheet model is concluded valid, Also upstream temperatures were found to have only a minor effect on the nondimensional flame temperature and nondimensional fuel even through the letter is sensitive to pressure changes.

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입계확산처리된 Nd-Fe-B 소결자석에서 Dy의 확산에 미치는 Cu와 Al 분말의 혼합 효과 (Effect of Cu/Al powder mixing on Dy diffusion in Nd-Fe-B sintered magnets treated with a grain boundary diffusion process)

  • 이민우;장태석
    • 한국분말재료학회지
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    • 제23권6호
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    • pp.432-436
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    • 2016
  • We investigate the microstructural and magnetic property changes of $DyH_2$, $Cu+DyH_2$, and $Al+DyH_2$ diffusion-treated NdFeB sintered magnets with the post annealing (PA) temperature. The coercivity of all the diffusion-treated magnets increases with increasing heat treatment temperature except at $910^{\circ}C$, where it decreases slightly. Moreover, at $880^{\circ}C$, the coercivity increases by 3.8 kOe in Cu and 4.7 kOe in Al-mixed $DyH_2$-coated magnets, whereas this increase is relatively low (3.0 kOe) in the magnet coated with only $DyH_2$. Both Cu and Al have an almost similar effect on the coercivity improvement, particularly over the heat treatment temperature range of $790-880^{\circ}C$. The diffusivity and diffusion depth of Dy increases in those magnets that are treated with Cu or Al-mixed $DyH_2$, mainly because of the comparatively easy diffusion path provided by Cu and Al owing to their solubility in the Nd-rich grain boundary phase. The formation of a highly anisotropic $(Nd,\;Dy)_2Fe_{14}B$ phase layer, which acts as the shell in the core-shell-type structure so as to prevent the reverse domain movement, is the cause of enhanced coercivity of diffusion-treated Nd-Fe-B magnets.

An Efficient Image Encryption Scheme Based on Quintuple Encryption Using Gumowski-Mira and Tent Maps

  • Hanchinamani, Gururaj;Kulkarni, Linganagouda
    • International Journal of Contents
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    • 제11권4호
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    • pp.56-69
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    • 2015
  • This paper proposes an efficient image encryption scheme based on quintuple encryption using two chaotic maps. The encryption process is realized with quintuple encryption by calling the encrypt(E) and decrypt(D) functions five times with five different keys in the form EDEEE. The decryption process is accomplished in the reverse direction by invoking the encrypt and decrypt functions in the form DDDED. The keys for the quintuple encryption/decryption processes are generated by using a Tent map. The chaotic values for the encrypt/decrypt operations are generated by using a Gumowski-Mira map. The encrypt function E is composed of three stages: permutation, pixel value rotation and diffusion. The permutation stage scrambles all the rows and columns to chaotically generated positions. This stage reduces the correlation radically among the neighboring pixels. The pixel value rotation stage circularly rotates all the pixels either left or right, and the amount of rotation is based on chaotic values. The last stage performs the diffusion four times by scanning the image in four different directions: Horizontally, Vertically, Principal diagonally and Secondary diagonally. Each of the four diffusion steps performs the diffusion in two directions (forward and backward) with two previously diffused pixels and two chaotic values. This stage ensures the resistance against the differential attacks. The security and performance of the proposed method is investigated thoroughly by using key space, statistical, differential, entropy and performance analysis. The experimental results confirm that the proposed scheme is computationally fast with security intact.

이차이온질량분석기의 깊이 분포도를 이용한 동선의 열적 확산에 대한 연구 (Study of Thermal Diffusion in the Copper Wire Using SIMS Depth Profiling)

  • 박종진;홍태은;조영진;서영일;문병선;박종찬;박혁규;이정식
    • 한국화재소방학회논문지
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    • 제22권5호
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    • pp.43-47
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    • 2008
  • 최근에 이차이온질량분석기(Secondary Ion Mass Spectrometry)를 이용한 1 2차 용융흔 구별에 관한 연구가 많은 관심을 끌고 있다. 동선의 깊이 분포에 따른 $^{12}C^-$, $^{63}Cu^-$, $^{18}O^-$, $^{35}Cl^-$ 이차 이온을 검출하기 위해 Cs+ 일차 이온빔을 사용하였고, 본 논문에서는 과전류에 의한 동선의 열적 확산에 대해 분석하였다. 분석결과 PVC 절연피복이 덮인 동선이 보다 더 깊이 탄소와 염소가 확산함을 보였으나, 산소는 절연피복이 덮이지 않은 동선이 더 깊이 확산된 것을 보였다.