• Bulletin of the Korean Chemical Society
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• v.33 no.1
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• pp.60-64
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• 2012

Silver(I) [bis(alkylthio)methylene]malonates were synthesized from the reaction of silver nitrate and potassium [bis(alkylthio)methylene]malonates. The structures of the Ag complexes were characterized with nuclear magnetic resonance (NMR), inductively coupled plasma atomic emission spectrometry (ICP-AES) and elemental analysis. Ag nanoparticles (NPs) were obtained from the decomposition of the Ag complexes in 1,2-dichlorobenzene at $110^{\circ}C$ without an additional surfactant. The average sizes of the Ag NPs are in the range of 5.1-6.3 nm and could be controlled by varying the length of the alkyl chain. The optical properties, crystalline structure and surface composition of Ag NPs were characterized with ultraviolet-visible (UV-visible) spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), gas chromatography-mass spectrometry (GC-MS), X-ray Photoelectron Spectroscopy (XPS) and thermal gravimetric analysis (TGA).

• Bulletin of the Korean Chemical Society
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• v.35 no.2
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• pp.407-414
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• 2014

Polyacrylonitrile (PAN) copolymers with different methyl acrylate (MA) contents were synthesized via solution polymerization and used as precursors for high-performance PAN ultrafine fibrids. The chemical structures of the copolymers were characterized using Fourier-transform infrared spectroscopy and $^{13}C$ nuclear magnetic resonance spectroscopy. Their particle sizes and aspect ratios increased with increasing viscosity, and the degree of crystallinity increased with decreasing concentration of copolymer solution. In contrast, their peak temperature and heat of exotherm increased with decreasing concentration of the copolymer solution. The aromatization indices (AIs) of the fibrids increased with increasing heat-treatment time; however, the AIs decreased when the heat-treatment temperature was higher than the onset temperature of the copolymers. On the other hand, the crystal sizes of the fibrids decreased with increasing concentration of the copolymer solution when the MA content was held constant.

• Journal of Surface Science and Engineering
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• v.24 no.4
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• pp.215-221
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• 1991

Microstructure evolution during low temperature vapor deposition exhibits wel-developed columnar structure mainly owing to geometrical shadowing effect of surface roughness. It is concluded that this structure is concided with many theoretical models suggested so far. In case of aluminum nitride film deposition consisted of etching and nitriding step employing ECR plasma, the rougher the surface before etching, the finer and more cone-and-whisker structure can be developed. In turn, this fine structure affects the formation and growth of columnar as well as offers many sites available for mechanical lock-up. Conclusively, the formation of well-defined columnar structures depends on the initial surface roughness.

• Journal of the Korean Chemical Society
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• v.13 no.1
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• pp.89-95
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• 1969

The structural investigations on the adducts, formed from dichloroketene with cyclopentadiene, methyl and ethylcyclopentadiene, have been carried out by means of infrared and nuclear magnetic resonance spectroscopy and also by their chemical behaviors. It was confirmed by this study that the adducts were formed by 1, 2-cycloaddition reaction and had the fundamental structure of bicyclo [3. 2. 0]-7,7-dichloro-2-heptene-6-one. These results were well agreed with the hypothesis that a diradical intermediate was formed as the first step in 1, 2-cycloaddition. The reaction mechanism for the process in which tropolones were formed from these adducts was also discussed.

• Imaging Science in Dentistry
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• v.32 no.4
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• pp.231-234
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• 2002

The odontogenic myxoma is an infiltrative benign tumor of bone that occurs almost exclusively in the jaw bones and comprises 3% to 6% of odontogenic tumors. This neoplasm is thought to arise from the primitive mesenchymal structures of a developing tooth, including the dental follicle, dental papilla, or periodontal ligament. Radiographically the odontogenic myxoma may produce several patterns: unicystic, multilocular, pericoronal, and radiolucent-radiopaque, making the differential diagnosis difficult. In this report, two cases of the odontogenic myxoma in the jaw bones are presented. The first case involved only the mandible, while the second case involved the maxilla. Both cases presented extensive multilocular radiolucencies characteristic of odontogenic myxoma.

• Bulletin of the Korean Chemical Society
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• v.30 no.7
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• pp.1559-1562
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• 2009

The influence of hot pressing on the pore structures of Nafion membranes was investigated by observing the Nafion before and after hot pressing with $^1H$ nuclear magnetic resonance (NMR) spectroscopy. The freezing point depression and chemical shift data of water in the Nafion indicated the presence of two different pore size ranges in Nafion. Hot pressing mainly reduced the sizes and number of the big pores. The reduction of water uptake and proton conductivity after hot pressing was explained by this variation of pore size and number. We demonstrated the potential application of chemical shift data and NMR cryoporometry experiments to measure the relative pore sizes, on a nano scale, and numbers.

• Smart Structures and Systems
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• v.13 no.5
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• pp.755-773
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• 2014

The natural frequency of a bridge is an important parameter in many engineering applications such as bridge seismic design and modal-based bridge health monitoring. The natural frequency of a bridge vibrating alone may differ from that vibrating along with a vehicle. Although such vehicle-induced variability in bridge frequency is revealed in several experimental and numerical simulation studies, few attempts have been made on the theoretical descriptions. In this study, both theoretically and experimentally, the variability in the bridge frequency induced by a parked vehicle is verified, and is therefore suggested to be considered in bridge-related engineering, especially for those cases with near vehicle-bridge resonance conditions or with large vehicle-to-bridge mass ratios. Moreover, the variability ranges could be estimated by an analytical formula presented herein.

• Smart Structures and Systems
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• v.20 no.5
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• pp.583-593
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• 2017

This research deals with the nonlocal temperature-dependent dynamic buckling analysis of embedded sandwich micro plates reinforced by functionally graded carbon nanotubes (FG-CNTs). The material properties of structure are assumed viscoelastic based on Kelvin-Voigt model. The effective material properties of structure are considered based on mixture rule. The elastic medium is simulated by orthotropic visco-Pasternak medium. The motion equations are derived applying Sinusoidal shear deformation theory (SSDT) in which the size effects are considered using Eringen's nonlocal theory. The differential quadrature (DQ) method in conjunction with the Bolotin's methods is applied for calculating resonance frequency and dynamic instability region (DIR) of structure. The effects of different parameters such as volume percent of CNTs, distribution type of CNTs, temperature, nonlocal parameter and structural damping on the dynamic instability of visco-system are shown. The results are compared with other published works in the literature. Results indicate that the CNTs have an important role in dynamic stability of structure and FGX distribution type is the better choice.

• Smart Structures and Systems
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• v.25 no.1
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• pp.37-45
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• 2020

This paper aims at enlightening the properties, computational and implementation issues related to Kalman filter based state estimation algorithms and sliding mode observers, by applying them for estimating the states of a smart structure system. The Kalman based estimators considered in this work are Kalman filter and information filter and, the sliding mode observers considered are Utkin observer and higher order sliding mode observer. A fourth order linear time invariant model of a piezo actuated beam is used in this work. This structure is embedded with four number of piezo patches, of which two act as sensors, one as disturbance actuator and the other as control actuator. The performance of the state estimation algorithms is evaluated through simulation, for the first two vibrating modes of the piezo actuated structure, when the structure is maintained at first mode and second mode resonance.

• Archives of Pharmacal Research
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• v.21 no.5
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• pp.591-594
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• 1998

The structural analogues of cumambrin B(1, 2, 3, 4) were isolated from the flower of Chrysnathemum boreale Makino. The structures of compounds were determined by two-dimensional $^{1}H-^{1}H$ COSY and $^{13}C-^{1}H$ COSY spectra with the aid of homonuclear and heteronuclear double resonance experiment. The stereochemistry of compounds has been verified from single crystal X-ray diffraction of cumambrin A(2). the antimicrobial activities of these guaianolides have been studied.