• Title/Summary/Keyword: Resistance of $Cl^-$ penetration

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A Studyon the Properties of Polymer-Modified Mortar Using Asphalt Emulsion (아스팔트 에멀젼을 혼입한 폴리머 시멘트 모르터의 특성에 관한 연구)

  • Jean, Woo-Sung;Song, Hun;Jo, Young-Kug;Soh, Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.375-380
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    • 1997
  • The purpose of this study is to examine the properties of polymer-modified mortars using asphalt emulsion. The polymer-modified mortars using asphalt emulsion with various asphalt-cement ratios are prepared, and tested for flexural and compressive strengths, water absorption and permeability, carbonation, Cl ion penetration and chemical resistance. From the test results, the flexural and compressive strengths, water absorption and permeability, carbonation and Cl ion penetration depths of polymer-modified mortars using asphalt emulsion tend to be decreased with increasing asphalt-cement ratio, and chemical resistance is improved. It is evident that polymer-modified mortars using asphalt emulsion having an excellent properties as a waterproof and finish materials can be produced.

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An experimental study on surface performance improvement of concrete influencing on resistance to chloride (콘크리트의 표면성능개선이 염소이온투과저항성에 미치는 영향에 관한 실험적 연구)

  • Kim, Jae-Sung;Kang, Suk-Pyo;Hong, Sung-Yoon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.782-785
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    • 2004
  • Salt attack is one of the serious deterioration factor with respect to the durability of concrete structure. Especially, in case of exposed rebar concrete structure in marine environment, corrosion of rebar is accelerated by penetration of $Cl^-$ from exterior. Through this path, volume of corroded rebar is increased about two and half times due to increased inner pressure originated from rust. As a consequence, the overall deterioration of concrete structure, namely, cracks, reduction of adhesive strength and pop-out is followed. In this paper, the effect of structure treatment of concrete on chloride resistance has been investigated. At the same time, the relationship among several characteristics, such as resistance to chloride, water absorption coefficient and surface hardness of concrete has been investigated. It is believed that surface performance improvement by the application of penetrative hardening agent influences on positively water absorption coefficient, surface hardness of concrete and resistance to chloride ion penetration.

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Fundamental Study on High Strength and High Durability Cement Concrete Pavement: Part II Strength and Durability Evaluations (시멘트콘크리트 포장의 고강도 고내구성을 위한 기초 연구 : Part II 최적배합콘크리트의 강도 및 내구특성 분석)

  • Yun, Kyong-Ku;Park, Cheol-Woo;Hong, Seung-Ho
    • International Journal of Highway Engineering
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    • v.11 no.3
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    • pp.51-60
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    • 2009
  • This study investigates the fresh state characteristics, strength, chloride ion penetration resistance and freeze-thaw resistance of the suggested high strength-high durability cement concrete pavement. The required workability and air content could be achieved by using an appropriate admixtures. However its dosage should be carefully determined through field trial batches. Compressive strength increased with the increased cement content and, in particular, high cement volume concrete continuously developed strength up to 90 days. No clear relationship, however, existed between flexural strength and cement content. Chloride penetration resistance seemed as a function of curing age rather than the cement content. Freeze-thaw resistance test was conducted using two different coolants, tap water and 4% NaCl solution. When the tap water was used no severe damage was observed up to 300 cycles regardless the air content. Under 4% NaCl solution, specimens of 326kg/$m^3$ cement content showed severe damage with surface scaling. Based on the experimental investigations herein, it is highly recommended that the cement content be greater than 400kg/$m^3$ for strength-high durability cement concrete pavement structures.

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Carbonation and Cl Penetration Resistance of Alkali Silicate Impregnant of Concrete (Silicate계 콘크리트 침투성 함침제의 탄산화 및 염해 저항성)

  • Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Journal of the Korean Ceramic Society
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    • v.45 no.11
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    • pp.719-724
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    • 2008
  • Every concrete structure should continue to perform its intended functions such as to maintain the required strength and durability during its lifetime. Deterioration of the concrete structure, however, occurs more progressively from the outside of the concrete exposed to severe conditions. Main deteriorations in concrete structures result from carbonation, chloride ion attack and frost attack. Concrete can therefore be more durable by applying surface protection to increase its durability using impregnants, which are normally classified into two large groups in polymeric and silicate materials. Concrete impregnants are composed of silanes and alkali silicates (sodium, potassium and lithium silicate). Thus, this study is concerned with elevating the carbonation and Cl- penetration resistance of concrete structures by applying alkali silicate hydrophilic impregnants including lithium and potassium silicates. From the experimental test results, lithium and potassium silicates produced a good improvement in carbonation resistance and are expected to be used as hydrophilic impregnants of concrete structures.

Deicing Performance with Deicer Types (제설제 종류에 따른 제설성능 평가)

  • Lee, Byung-Duck;Lee, Chan-Young;Yun, Byung-Sung;Lee, Joo-Kwang;Chung, Young-Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.371-374
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    • 2005
  • In this study, calcium chloride($CaCl_2$), sodium chloride (NaCl), organic acids-containing deicer(NS 40, NS 100), mixed deicier($NaCl\;70\%\;+\;CaCl_{2}\;30\%,\;NS\;40\;70\%\;+\;CaCl_{2}\;30\%,\;NaCl\;70\%\;+\;NS\;40\;30\%,\;NS\;40\;70\%\;+\;NaCl\;30\%$) is investigated based on the laboratory test for deicing performance. Test items for deicing performance were ice melting and ice penetration, freezing point depressions and eutectic points, pH, thermal properties for selected deicing chemicals. As a test results, in case of the use chloride-containing deicier in area that concrete structures has subjected to freez-thaw reaction in winter season, it showed desirable method that use deicing chemicals mixed with optimum ratio rather than use one deicing chemicals when is consider to deicing performance and effects, corrosion of steel materials, freez-thaw resistance of concrete. When use various deicing chemicals mixed, NS40($70\%$)+Calcium chloride($30\%$) showed the best effective method.

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The effects of stacking sequence on the penetration-resistant behaviors of T800 carbon fiber composite plates under low-velocity impact loading

  • Ahmad, Furqan;Hong, Jung-Wuk;Choi, Heung Soap;Park, Soo-Jin;Park, Myung Kyun
    • Carbon letters
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    • v.16 no.2
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    • pp.107-115
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    • 2015
  • Impact damages induced by a low-velocity impact load on carbon fiber reinforced polymer (CFRP) composite plates fabricated with various stacking sequences were studied experimentally. The impact responses of the CFRP composite plates were significantly affected by the laminate stacking sequences. Three types of specimens, specifically quasi-isotropic, unidirectional, and cross-ply, were tested by a constant impact carrying the same impact energy level. An impact load of 3.44 kg, corresponding to 23.62 J, was applied to the center of each plate supported at the boundaries. The unidirectional composite plate showed the worst impact resistance and broke completely into two parts; this was followed by the quasi-isotropic lay-up plate that was perforated by the impact. The cross-ply composite plate exhibited the best resistance to the low-velocity impact load; in this case, the impactor bounced back. Impact parameters such as the peak impact force and absorbed energy were evaluated and compared for the impact resistant characterization of the composites made by different stacking sequences.

Effects of Corrosion Inhibitor on Corrosion of Al-based Alloys in Ethylene Glycol-Water Coolant Environment

  • Gwang-Soo Choi;Young-Man Kim;Chan-Jin Park
    • Corrosion Science and Technology
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    • v.22 no.5
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    • pp.305-313
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    • 2023
  • The objective of this study was to investigate the effectiveness of sodium dodecyl benzene sulfonate (SDBS) as a corrosion inhibitor on the pitting corrosion behavior of aluminum alloys used in electric vehicle battery cooling systems within a mixture of ethylene glycol and water (EG-W) coolant. Potentiodynamic polarization testing revealed unstable passive film formation on the aluminum alloys in the absence of SDBS. However, the addition of SDBS resulted in a robust passive film, enhancing the pitting corrosion resistance across all examined alloys. Pitting corrosion was predominantly observed near intermetallic compounds in the presence of Cl? ions, which was attributed to galvanic interactions. Among tested alloys, A1040 demonstrated superior resistance due to its lower areal fraction of precipitates and donor density. The incorporation of SDBS inhibitors mitigated the overall pitting corrosion process by hindering Cl? ion penetration. These findings suggest that SDBS can significantly improve pitting corrosion resistance in aluminum alloys employed in battery coolant environments.

Evaluation of the Deicing Performance and Concrete Structure Effect with Various Deicing Chemicals (제설제 종류에 따른 융빙성능 및 콘크리트에 미치는 영향 평가에 관한 연구)

  • Lee, Byung-Duck;Yun, Byung-Sung;Lee, Joo-Kwang;Chung, Young-Hwan
    • International Journal of Highway Engineering
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    • v.7 no.4 s.26
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    • pp.113-123
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    • 2005
  • In this study, calcium chloride$(CaCl_2)$, sodium chloride (NaCl), organic acids-containing deicer(NS 40, NS 100), mixed deicier$(NaCl\;70%+CaCl_2\;30%,\;NS\;40\;70%+CaCl_2\;30%,\;NaCl\;70%+NS\;40\;30%,\;NS\;40\;70%+NaCl\;30%)$ is investigated based on the laboratory test for deicing performance, freez-thaw resistance of concrete, and corrosion rate of metal. Test items for deicing performance were ice melting and ice penetration, freezing point depressions and eutectic point, pH, thermal properties for selected deicing chemicals as well as their compatibility with concrete and metal were experimentally investigated. As a test results, in case of the use chloride-containing deicier in area that concrete structures has subjected to freez-thaw reaction in winter season, it showed that mixed deicing chemicals with optimum ratio has desirable method than use one deicing chemicals when is consider to deicing performance and effects, corrosion of steel materials, and freez-thaw resistance of concrete. When use various deicing chemicals mixed, NS40(70%)+calcium chloride(30%) showed the best effective method.

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Effect of Oxide Particles Addition to Powder Coating on Corrosion Resistance of Steel Used as Marine Equipments (조선·해양 기자재용 강재의 내식성에 미치는 분체도장 중 산화물 첨가의 영향)

  • Park, Jin-seong;Ryu, Seung Min;Jeong, Yeong Jae;Kim, Sung Jin
    • Corrosion Science and Technology
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    • v.19 no.2
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    • pp.100-107
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    • 2020
  • The demand for powder-coated steel used in the marine industry is increasing owing to their superior corrosion resistance. However, the powder coatings used in commercial products can deteriorate easily by the penetration of brine. In an attempt to suppress brine penetration into the powder coating and significantly increase the corrosion resistance, three types of oxide particles were added to the coating. Electrochemical impedance spectroscopy tests in 3.5% NaCl solution were performed to evaluate the corrosion behaviors of the powder coating with oxide particles. The results showed that the addition of SiO2 particles to a powder coating severely decreased the corrosion resistance due to the easy detachment of agglomerated SiO2 particles with a coarse size from the coating layer. In contrast, the TiO2 and SnO2-added coatings showed better corrosion resistance, and the TiO2-added coating performed best in the test conducted at room temperature. However, conflicting results were obtained from tests conducted at a higher temperature, which may be attributed to the effective suppression of brine penetration by the fine SnO2 particles uniformly distributed in the coating.

A Method on the Rapid Assessment of Resistance to Chloride Ion Penetration for Mortar and Concrete with Mineral Admixtures (혼화재를 사용한 모르타르 및 콘크리트의 염소이온 침투 저항성 평가)

  • Park Jung-Jun;Kim Sung-Wook;Koh Kyung-Taek;Lee Jong-Suk;Lee Jang-Hwa
    • Journal of the Korea Concrete Institute
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    • v.16 no.4 s.82
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    • pp.485-492
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    • 2004
  • In this study, ASTM C 1202 which is most commonly used for evaluating the penetration resistance into the concrete is reviewed. The test results by ASTM C 1202 showed that the passed charge could be underestimated as the $OH^-$ ion concentration in the concrete is lowered when the concrete is mixed with the admixtures. Therefore, the modified method using the distilled water was proposed in the paper. According to the test results, the modified method is not susceptible to $OH^-$ ion and temperature rise. In addition, the long term emersion test for the concrete mixed with the admixtures in the NaCl solution showed that the chloride diffusion coefficient tested by the modified method have higher correlation compared to the conventional ASTM method.