• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 1999년도 Pre-symposium of the 10th ISWPC Recent Advances in Paper Science and Technology
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• pp.254-258
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• 1999

The distribution of anionic groups in the fibers, the fines, the colloidal fraction and the dissolved fraction, respectively, of thermomechanical pulp (TMP) suspensions was determined and peroxide bleaching of spruce TMP were also studied. Spruce TMP was extracted with hexane, treated with alkali, or bleached with peroxide. Suspensions made at pH 5.5 were fractionated into long fibres, large fines, small fines, a colloidal fraction and a dissolved fraction. The charge of the fractions was determined using polyelectrolyte titration. To determined the origin of the charges, the contents of fatty acids, resin acids and acidic units in hemicelluloses in the different fractions were determined by has chromatography. Extraction of TMP with hexane prior to fractionation increased the measured charge of the fibres. The removal of the wood resin probably uncovered some carboxyl groups on the fibre surfaces, or improved th e penetration of polybrene into the pores of the fibres. The charge of the fines and the colloidal fraction was lower when the wood resin had been removed. Alkaline treatment of the TMP increased the charge of the fibres and fines, mainly because of demethylation of pectins. Alkaline treatment increased the charge also of the dissolved fraction, because of the release the charge also of the dissolved fraction, because of the release of pectic acids into the water phase. Alkaline peroxide bleaching further increased the charge of fibres and the dissolved fraction, most likely because of lignin oxidation. The charge of the colloidal fraction, consisting mainly of wood resin, was only slightly affected by alkaline treatment and peroxide bleaching. The anionic groups in TMP suspensions were mainly free uronic acids in the hemicelluloses. The contribution from the fatty and resin acids was substantial only for the colloidal fraction.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.561-564
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• 2006

The tensile characteristics of four types GFRP (glass fiber reinforced polymer) reinforcing bars with different resin mix proportions and fiber volume fraction were analyzed experimentally. Four types of GFRP reinforcing bars containing approximately 66 or 70% fiber volume fraction with A or B rein mix proportions were considered in this test. All testing procedures including specimens preparation, set-up of test equipments and measuring devices were made according to the recommendations of CSA Standard S806-02. From the test results, it was found that GFRP reinforcing bars containing approximately 70% fiber volume fraction with A rein mix proportion showed the higher tensile strength than that of the others due to the higher fiber volume fraction and proper resin mix proportion.

• Composites Research
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• 제31권4호
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• pp.161-170
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• 2018

원통형 복합재 격자 구조체는 필라멘트 와인딩 기법으로 제작되며 제작 공정에서 발생할 수 있는 섬유체적비 불균일과 수지응집층은 구조체의 강성도 및 강도에 영향을 줄 수 있다. 구조체의 주요 요소인 후프 및 헬리컬 리브의 단면 분석을 통해 섬유체적비 불균일 및 수지응집층의 존재 여부를 확인하였으며, 단면 분석 결과를 바탕으로 후프 및 헬리컬 리브에 대한 실험 및 이론적 접근을 통해 섬유체적비 불균일 및 수지응집층이 리브 요소의 강성도에 미치는 영향을 분석하였다. 섬유체적비 불균일이 후프 리브의 굽힘 거동에 영향을 미치는 것을 확인하였으며 헬리컬 리브의 경우 섬유체적비 불균일 및 수지응집층에 의해 강성도에 변화가 있음을 확인하였다.

• 한국세라믹학회지
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• 제44권5호
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• pp.179-183
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• 2007

BCB $Resin-BaNd_2Ti_4O_{12}$(BNT) composites with BNT contents were prepared by tape casting method and epoxy resin-BNT composites were prepared by using heating press. Their dielectric properties and microstructures were investigated. The dielectric properties such as dielectric constant and dielectric loss at 1 MHz for epoxy resin-BNT composites and BCB resin-BNT composites are improved with an increase of BNT volume fraction. The dielectric constant of the Epoxy-BNT composite increased from 5.9 to 7.8 as the volume fraction of BNT increased from 15 to 25. The dielectric constant of the BCB-BNT composite increased from 9.1 to 15.5 as the volume fraction of BNT increased from 30 to 50. The dielectric behavior of BCB-BNT system can be explained by Lichtenecker's equation. The dielectric constant of epoxy resin-BNT composite is smaller than that of BCB resin-BNT composite. These results are considered to be related with the dispersion of BNT filler in polymer matrix from the result of SEM photograph.

• 한국수소및신에너지학회논문집
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• 제30권6호
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• pp.629-634
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• 2019

Dicyclopentadiene is a low viscosity resin which forms a poly-dicyclopentadiene rapidly through ring opening metathesis polymerization (ROMP). This poly-dicyclopentadiene has outstanding properties of low-temperature, water and impact resistances. Due to these advantages, military and offshore structures try to apply the DCPD composites by using liquid composite molding process. In this study, 14%, 38% volume fraction fiber glass strand mat reinforced p-DCPD composites processed by structural reaction injection molding (S-RIM) which has resin-catalsyt mixing head and glass fiber preform in the mold. Additionally, S-RIM numerical analysis was conducted to predict the process time depending on fiber volume fraction and mold temperature. The process time is shorter when it has the lower fiber volume fraction or the higher mold temperature. At higher mold temperature, it is necessary to set the maximum mold temperature considering the resin curing time.

• Composites Research
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• 제34권2호
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• pp.88-95
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• 2021

VARTM(Vacuum-assisted resin transfer molding) 공정은 OoA(Out of Autoclave)에 속하는 저가형 공정기술로 다양한 분야에 널리 사용되어 왔다. 그러나 오토클레이브 공정보다 품질이 낮아 고신뢰성이 요구되는 항공산업에는 적용하기 어려웠다. VARTM 공정의 주요 문제는 오토클레이브 대비 낮은 섬유부피분율과 높은 Void 함량에 의한 기계적 물성의 손실이었다. 따라서 많은 연구자들이 Void를 줄이고 섬유부피분율을 높일 수 있는 연구를 수행해 왔다. 이러한 연구의 흐름에 따라 본 연구에서는 수지 주입 과정 중 대기압을 제어하는 방법이 섬유부피분율을 높이고 Void를 감소시킬 수 있는지 검토하였다. 신뢰성 평가는 Void와 연관성이 있는 압축강도시험, 섬유부피분율 분석, 광학현미경 촬영을 통해 확인하였다. 결과적으로 VARTM 공정에서 수지 주입과정 중 대기압을 단계별로 높이는 방법이 섬유부피분율 증가와 Void 감소에 직접적인 효과가 있음을 확인하였다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2003년도 추계학술발표대회 논문집
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• pp.79-82
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• 2003

In case of performing resin transfer molding (RTM), race track effects and non-uniform fiber volume fraction may cause undesirable resin flow pattern and thus result in dry spots, which affect the mechanical properties of the finished parts. In this study, a real time RTM control strategy to reduce these unfavorable effects is proposed. Through numerical simulations and experiments, the validity of the proposed scheme is demonstrated.

• Structural Engineering and Mechanics
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• 제62권3호
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• pp.273-279
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• 2017

A meso-scale model is proposed to study filament-wound composites with fiber undulations and crossovers. First, the crossover and undulation region is classified as the circumferential undulation and the helical undulation. Next, the two undulations are separately regarded as a series of sub-models to describe the meso-structure of undulations by using meso-parameters such as fiber orientation, fiber inclination angle, resin rich area, fiber volume fraction and bundle cross section. With the meso-structure model and the classic laminate theory, a method for calculating the stiffness of filament wound composites is eventually established. The effects of the fiber inclination angle, the fiber and resin volume fraction and the resin rich area on the stiffness are studied. The numerical results show that the elastic moduli for the circumferential undulation region decrease to a great extent as compared with that of the helical undulation region. Moreover, significant decrease in the elastic and shear moduli and increase in the Poisson's ratio are also found for the resin rich area. In addition, thickness and bundle section have evident effect on the equivalent stiffness of the fiber crossover and the undulation region.

• 한국자원식물학회지
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• 제27권6호
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• pp.635-641
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• 2014

Scutellaria baicalensis $G_{EORGI}$ (Scutellariae Radix) has been used to clear heat and to dry dampness in the stomach or intestines, which manifests as diarrhea or dysenteric disorder. In this study, we investigated the effective preparation of active components in Scutellariae Radix using the methods of solvent extraction and absorption fractionation for the development of new functional food or pharmaceuticals. The marker substances, baicalin, baicalein, wogonoside, and wogonin were directly isolated from the Scutellariae Radix. There chemical structures were elucidated by spectroscopic analysis. The Scutellariae Radix was extracted with hot water. To enhance yield of flavonoids in Scutellariae Radix, the hot water extract was dissolved in ethanol with concentration dependent manner. The precipitates were separated using centrifugal techniques at 10,000 rpm. Supernatant liquid was applied to the HPLC for quantification of major compounds. Separately, the hot water extract was absorbed on Diaion HP-20 resin. And then, the absorbed fraction was eluted with methanol for HPLC. The contents of baicalin, baicalein, wogonoside and wogonin in different treatment methods were analyzed by HPLC. Total amount of four major components were 16.9% in 50% ethanol extract, 21.7% in 70% ethanol extract, 20.5% in 90% ethanol extract, and 39.3% in absorbed fraction of Diaion HP-20 resin. In these results, we found that resin absorption method is suitable for the extraction of enriched flavonoids from Scutellariae Radix.

• Composites Research
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• 제28권6호
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• pp.340-347
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• 2015

VARTM 공정에서 고분자 수지가 함침 될 때 시간에 따라 섬유보강재가 팽창하여 섬유체적율이 감소하는 현상이 발생한다. 풍력 블레이드와 같은 대형 복합재료 구조물의 경우 섬유체적율의 변동 폭이 커져 제품의 치수가 변하고 기계적 물성이 저하될 뿐 아니라 예측하지 못한 고분자 수지의 사용량이 증가하는 등의 문제점과 경제적인 손실이 발생할 여지가 증가할 수 있다. 본 연구에서는 VARTM 공정에서 수지 함침에 따른 섬유 보강재의 팽창 현상에 관한 분석을 통하여 복합재료 액상 성형 공정에서의 섬유 체적율을 조절하는 방안을 모색하였다. 그 결과 유동 선단의 진행에 따라 섬유의 팽창 현상이 크게 두 단계로 구분되어 나타나는 것을 확인하였고 각각의 단계에서 작용하는 힘을 분석함으로써 섬유의 체적율 변화에 관한 현상학적 모델을 제시하였고 1차원 편미분 수치 해석과 연계하여 VARTM공정에서 수지 함침에 따른 섬유 체적율의 변화를 예측하였다.