• Journal of Environmental Science International
• /
• v.9 no.3
• /
• pp.201-208
• /
• 2000

PCBs and DDE were determined in the soil samples and the Korean striped field mice, Apodemus agrarius, collected at six localities in Changwon and one locality in Gaduck Island from August 1997 to May 1998. The residual level of PCBs in soils, in which the concentrations of high chlorinated compounds were much higher than those of low chlorinated ones, was highest in the industrial area(IA) in Changwon(60.7 ng/g in average), whereas those of DDE in soils was highest in Gaduck Island(331.9 ng/g in average). However, the levels of each compound detected from soils in the respective remaining places were relatively low. The similar tendency as in the soils was observed in the mice, indicating that the concentration of pollutants in the mice could denote the status of pollution in the terrestrial environment. The composition of PCB congeners in the mice, however, was different from that of soils, but similar to those of other mammals. Moreover, the residual levels of PCBs and DDE in pregnant females from which fetuses were removed were lower than those of males and non-pregnant females. It suggests that these compounds accumulated in pregnant females might have been transferred to the fetuses through placenta as in other mammals. Judging from the above facts, it is suggested that the striped field mouse can be an useful biological index to evaluate the contamination in mammals inhabiting terrestrial environment.

• Economic and Environmental Geology
• /
• v.29 no.4
• /
• pp.495-508
• /
• 1996

This study had three purposes: (1) to investigate dispersion and enrichment level of potentially toxic elements; (2) to identify uranium-bearing minerals in black shales; and (3) to assess the chemical speciation of heavy metals in soils and sediments. Rock, surface soil and stream sediment samples were collected in the Chungjoo area covered with black shales in Korea. These samples were analyzed for multi-elements using INAA and ICP-AES. The maximum abundance of U in black shales is 56 ppm and radioactivity counts up to 240CPM. Molybdenum, V, Ba, Cu, and Pb are enriched in black shales and most of soils show high concentrations of U, Mo, Ba, Cu, Pb and Zn. Concentrations of potentially toxic elements decrease in the order of mountain soil > farmland soil > paddy soil. Enrichment index of soils and sediments are calculated and higher than 1.0 in the black shale area with the highest value of 6.1. In order to identify U-bearing minerals, electron probe micro analysis was applied, and uraninite and brannerite in black shale were found. Uraninite grains are closely associated with monazite or pyrite with the size of $2{\mu}m$ to $10{\mu}m$ in diameter whereas brannerite occurs as $50{\mu}m$ euhedral grains. With the results of sequential extraction scheme, residual fractions of Cu, Pb and Zn in soils are mainly derived from weathering of black shale but Cu, Pb and Zn in sediments are present as non-residual fractions. Lead is predominantly present as oxidizable phase in soils whereas Zn is in exchageable/water-acid soluble phase in sediments.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2004.03b
• /
• pp.692-697
• /
• 2004

This study is on the increasement of strength about soft ground improvement material using waste residual(paper fly ash, coke ash, slag) by fire. Through this study the authors have analyzed the strength improvement of mixed soft silty sand with improvement materials. The strength of mixed soils with high mixture ratio and more curing days increased. But CA-30(cokes 60%) make more low strength improvement than others. Therefore the authors find out that paper fly ash+cokes, paper fly ash+slag or cokes+slag improvement material is more effect in improvement of soft silty sand than cokes+cenlent. And Ettringite reaction is free mixed soils with more than two materials.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2004.03b
• /
• pp.146-153
• /
• 2004

The goals of this study are to investigate the feasibility of the reference state approach in determining the generalized soil-water characteristic curve that is essential for characterization of unsaturated soil behavior. The soil-water characteristic curves are obtained from a number of specimens of fine-grained residual soils compacted with different void ratios. Based on the experimental test results, the feasibility of using the liquid limit state as the reference state for predicting the soil-water characteristic curve are verified. Finally, through the regression analysis of experimental data using the equation of Fredlund and Xing (1994), a reliable method is proposed to predict the generalized soil-water characteristic curve of fine-grained residual soils using the liquid limit state as the reference.

• Journal of the Korean Geotechnical Society
• /
• v.33 no.12
• /
• pp.7-20
• /
• 2017

In this study, effects of grain size distribution on the shear strength and rheological properties are investigated for coarse- and fine-grained soils by using direct shear apparatus. Shear strengths are estimated for fine-grained soils with the maximum particle size of 0.075 mm and coarse-grained soils with the maximum particle size of 0.425 mm and fine contents of 17% prepared at dry and liquid limit states. The direct shear tests are conducted under the relatively slow shear velocity, which corresponds to the reactivated landslide or debris flow after collapse according to the landslide classification. In addition, for the evaluation of rheological properties, residual shear strengths for both fine- and coarsegrained soils prepared under liquid limit states are obtained by multiple reversal shear tests under three shear velocities. From the relationship between residual shear strengths and shear rates, Bingham plastic viscosity and yield stress are estimated. The direct shear tests show that cohesions of fine-grained soil are greater than those of coarse-grained soil at both dry and liquid limit states. However, internal friction angles of fine-grained soil are smaller than those of coarse-grained soil. In case of rheological parameters, the plastic viscosity and yield stress of fine-grained soils are greater than those of coarse-grained soils. This study may be effectively used for the prediction of the reactivated landslide or debris flow after collapse.

• Korean Journal of Agricultural Science
• /
• v.43 no.4
• /
• pp.634-640
• /
• 2016

The objective of this study was to evaluate the effectiveness of using HR-GC/MS for the rapid screening of dieldrin residues in soils. Persistent organic pollutants (POPs) of organochlorine pesticides such as dieldrin, were analyzed in sedimentary rock and granite rock collected from greenhouses, Niigata, Japan. Dieldrin remains in Japanese farming soils, more than 40 years after their use as insecticides was prohibited. The averages in soil moisture ranged from 2.79% to 7.20% in soils derived from sedimentary rock and from 25.59% to 31.40% in soils derived from granite rock. Mean concentrations of dieldrin residues in sedimentary rock and granite rock were $39.7ng\;g^{-1}$ and $40.51ng\;g^{-1}$, respectively. Dieldrin residue was detected at a slightly higher concentration in granite rock than sedimentary rock samples. There was no consistency between the two soils or between surface and subsurface soils. The coefficients of variation of the two soils were 10.6% and 8.7%, respectively. These results suggest that our high-resolution mass spectrometry detector (HR-GC/MS) is effective at analyzing residual organochlorine pesticides in soil. In order to increase the precision and sensitivity for chemical analysis of POPs, high-resolution gas chromatography coupled with a HR-GC/MS is highly recommended.

• Proceedings of the Korean Geotechical Society Conference
• /
• 1998.10a
• /
• pp.65-72
• /
• 1998

• Journal of the Korean GEO-environmental Society
• /
• v.11 no.9
• /
• pp.5-14
• /
• 2010

This study was aimed to suggest reliable information of shear strength characteristics due to change of saturation in the landfills or slopes during rainfall infiltration. According to the Mohr-Coulomb failure criteria, the characteristics of shear strength due to change of saturation were analyzed for the weathered residual soils which were sampled in the road construction site of Daejeon city. From the direct shear strength tests, the cohesions and the shear resistance angles were showed maximum values in the condition of optimum moisture content, and then decreased in the condition of wet side compaction. In this study, the cohesions were decreased more than 50% according to increasing saturation by infiltration for the compaction soils. But the reductions of the shear resistance angles were about $1{\sim}2^{\circ}$ which was small value, and thus the changes of the saturation were not nearly influenced the shear resistance angle. The influences of the saturation were seemed to very small for the residual strength parameters according to Mohr-Coulomb failure criteria.

• Journal of the Korean Geotechnical Society
• /
• v.21 no.8
• /
• pp.85-93
• /
• 2005

Earth pressures acting on unmovable rigid walls vary according to loading-unloading conditions due to compaction experienced by backfill soil. Appropriate coefficients of earth pressure at rest with considering this influence need to be determined to estimate earth pressures more reasonably.0 this study, a single cycle hysteretic model simulating soil's loading-unloading-reloading behavior under $K_o-condition$ was reproduced by conducting a series of $K_o-triaxial$ test for compacted residual soils. Based on the results, coefficients of earth pressure at rest at each stage of stress paths such as, virgin loading, unloading and reloading were determined. Also, applicabilities of empirical equations to the estimation of the coefficients were evaluated by comparing the experimental results with those estimated by the equations. As a result, it was concluded that the empirical equations could be applied reasonably to the estimation of the coefficients for compacted residual soils in cases where some amount of error might be acceptable for the reloading stage of the hysteretic model.

• Journal of Korean Society of Environmental Engineers
• /
• v.27 no.1
• /
• pp.25-35
• /
• 2005

This study analyzed total concentrations and existing forms of heavy metals in soils of Ulsan using a sequential extraction method. Soil samples were collected from 6 categorized areas including green, residential, heavy traffic, petrochemical industrial complex(IC), mechanical and shipbuilding IC, and non-ferrous metal IC areas. which represent different emission characteristics. The highest total concentrations of heavy metals by a sequential extraction analysis were observed in the soils collected from the non-ferrous metal IC area, followed by the mechanical and shipbuilding IC and heavy traffic areas. Dominant(> 50%) existing forms of Cd, Cr and Ni were residual forms followed by Fe and Mn oxides in almost areas. Residual fractions in the non-ferrous metal IC areas were relatively lower than those in other areas. However, the fractions of organic and sulphides in the IC areas were higher. The dominant farms of Cu were much different with the investigated areas. In most areas, the dominant forms of Pb and Zn were Fe and Mn oxides, followed by residual fraction for Pb. The exchangeable and carbonate fractions represent mobility of metallic elements in soils. They are also significantly affected by the environmental renditions, such as pHs of soil and rainfall. In this study the exchangeable and carbonate fractions were lower than other fractions. Because the total concentrations of heavy metals in the soils of the non-ferrous metal IC area were extremely high, however, the mobile fractions of heavy metals in the IC area would be significant. Thus a large amount of heavy metals can be released into plants, water bodies, and soils. Therefore, urgent measures, such as source control for soil remediation of heavy metals, in the non-ferrous metal IC areas are essentially required. Analysis results obtained from the sequential extraction and the aqua regia extraction showed a high correlation, whose determination coefficients(R2) of heavy metals except Cd approximately ranged from 0.7 to 0.9.