• 제목/요약/키워드: Residual Gas

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The corrosion phenomena of AlCu films after reactive ion etching (반응성 이온 식각후 AlCu막의 부식현상)

  • 김창일;권광호;김상기;장의구
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.252-255
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    • 1996
  • Cl-based gas chemistry is generally used to etching for Al alloy metallization. After the etching of Al alloy with Cl-based gas plasma, residual chlorine on Al alloy reacts with $H_2O$ due to air exposure and results in Al corrosion. In this study, the corrosion Phenomena of Al were examined with XPS(X-ray photoelectron spectroscopy) and SEF(Scanning electron microscopy). It was confirmed that chlorine mainly existed at the grain boundary of Al alloy after plasma etching of Al alloy with Cl-based gas chemistry and Al corrosion was largely generated at the grain boundary of Al a1loy. And residual chlorine was passivated by sulfur and fluorine which were generated by SF$_{6}$ plasma. These effects of passivation reduced the Al corrosion due to air exposure.e.

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Development of High-Sensitivity Ion Sources for Residual Gas Analyzer

  • Park, Chang-Jun;Han, Cheol-Su;An, Sang-Jeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.104.2-104.2
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    • 2013
  • A residual gas analyzer (RGA) system has been developed in this laboratory. Characteristics of the RGA system parts such as ion source, quadrupole mass filter and sensitivity are introduced. Some efforts have been made to improve performance of the two types of ion sources, open ion source (OIS) and closed ion source (CIS). A metal mesh was placed onto the electron beam entrance of the CIS anode tube to block the filament field penetration. Sensitivity of the CIS ion sources with and without the mesh was compared by mass spectra of SF6 gas (97% He base) introduced into the CIS anode through a needle valve. About ten-times improvement in the RGA sensitivity was observed for the CIS with the mesh in the electron entrance. Computer simulation showed an axi-symmetric anode potential distribution and improved focusing of the electron beam inside the anode tube with the mesh.

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Using Two-Dimensional Chemiluminescence Images to Study Inhomogeneity in Mixture Gas in the Combustion Chamber for HCCI Combustion (이차원발광화상계측에 의한 예혼합압축자기착화연소의 연소실내 혼합기의 불균질성에 관한 연구)

  • Lim, Ock-Taeck;Iida, Norimasa
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.12
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    • pp.1043-1050
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    • 2010
  • Fuel stratification and thermal stratification occur in the HCCI combustion chamber on a microscopic scale. They affect the ignition and combustion processes. In this study, the effect of the inhomogeneity in the mixture gas on the HCCI combustion process was investigated. Two-dimensional chemiluminescence images were captured using a framing camera to evaluate the flame structure. DME was used as the test fuel. First, the effect of inhomogeneity in the fuel distribution in the premixture was investigated for the four-stroke optically accessible engine. Then, by comparing the combustion of the homogeneous mixture in the rapid compression machine, which does not contain any residual gas, with the combustion in the four-stroke engine, the effect of inhomogeneity in temperature due to the residual gas was analyzed. The results showed that a time lag appears spatially in combustion under inhomogeneous conditions in the four-stroke engine. The spatial variation in the combustion without the residual gas in the rapid compression machine is less than that in the combustion in the four-stroke engine.

Heat transfer and flow characteristics of a cooling thimble in a molten salt reactor residual heat removal system

  • Yang, Zonghao;Meng, Zhaoming;Yan, Changqi;Chen, Kailun
    • Nuclear Engineering and Technology
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    • v.49 no.8
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    • pp.1617-1628
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    • 2017
  • In the passive residual heat removal system of a molten salt reactor, one of the residual heat removal methods is to use the thimble-type heat transfer elements of the drain salt tank to remove the residual heat of fuel salts. An experimental loop is designed and built with a single heat transfer element to analyze the heat transfer and flow characteristics. In this research, the influence of the size of a three-layer thimble-type heat transfer element on the heat transfer rate is analyzed. Two methods are used to obtain the heat transfer rate, and a difference of results between methods is approximately 5%. The gas gap width between the thimble and the bayonet has a large effect on the heat transfer rate. As the gas gap width increases from 1.0 mm to 11.0 mm, the heat transfer rate decreases from 5.2 kW to 1.6 kW. In addition, a natural circulation startup process is described in this paper. Finally, flashing natural circulation instability has been observed in this thimble-type heat transfer element.

Bio-oil production using residual sewage sludge after lipid and carbohydrate extraction

  • Supaporn, Pansuwan;Ly, Hoang Vu;Kim, Seung-Soo;Yeom, Sung Ho
    • Environmental Engineering Research
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    • v.24 no.2
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    • pp.202-210
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    • 2019
  • In order to maximize the utilization of sewage sludge, a waste from wastewater treatment facility, the residual sewage sludge generated after lipid and carbohydrate extraction for biodiesel and bioethanol production was used to produce bio-oil by pyrolysis. Thermogravimetric analysis showed that sludge pyrolysis mainly occurred between 200 and $550^{\circ}C$ (with peaks formed around 337.0 and $379.3^{\circ}C$) with the decomposition of the main components (carbohydrate, lipid, and protein). Bio-oil was produced using a micro-tubing reactor, and its yield (wt%, g-bio-oil/g-residual sewage sludge) increased with an increase in the reaction temperature and time. The maximum bio-oil yield of 33.3% was obtained after pyrolysis at $390^{\circ}C$ for 5 min, where the largest amount of energy was introduced into the reactor to break the bonds of organic compounds in the sludge. The main components of bio-oil were found to be trans-2-pentenoic acid and 2-methyl-2-pentenoic acid with the highest selectivity of 28.4% and 12.3%, respectively. The kinetic rate constants indicated that the predominant reaction pathway was sewage sludge to bio-oil ($0.1054min^{-1}$), and subsequently to gas ($0.0541min^{-1}$), rather than the direct conversion of sewage sludge to gas ($0.0318min^{-1}$).

A Study on the Mechanical Properties of Gas Pressure Welded Splices of Deformed Reinforcing Bar (가스압접 이형철근의 기계적 강도 특성 연구)

  • Jeon, Juntai
    • Journal of the Society of Disaster Information
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    • v.11 no.4
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    • pp.520-526
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    • 2015
  • Reinforcing bar splices are inevitable in reinforced concrete structure. In these days, there are three main types of splices used in reinforced concrete construction site - lapped splice, mechanical splice and welded splice. Low cost, practicality in construction site, less time consuming and high performance make gas pressure welding become a favorable splice method. However, reinforcing bar splice experiences thermal loading history during the welding procedure. This may lead to the presence of residual stress in the vicinity of the splice which affects the fatigue life of the reinforcing bar. Therefore, residual stress analysis and tensile test of the gas pressure welded splice are carried out in order to verify the load bearing capacity of the gas pressure welded splice. The reinforcing bar used in this work is SD400, which is manufactured in accordance with KS D 3504. The results show that the residual stresses in welded splice is relatively small, thus not affecting the performance of the reinforcing bar. Moreover, the strength of the gas pressure welded splice is high enough for the development of yielding in the bar. As such, the reinforcing bar with gas pressure welded splice has enough capacity to behave as continuous bar.

Effects of Residual Magnetization on MEL Non-destructive Inspection of Gas Pipeline (가스관의 자속누설탐사에서 잔류자화의 영향에 관한 연구)

  • Jang, Pyung-Woo
    • Journal of the Korean Magnetics Society
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    • v.14 no.4
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    • pp.143-148
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    • 2004
  • Effects of residual flux density M$_{res}$ and number of inspection on the detection voltage and flux density B of the gas pipeline were investigated in MFL inspection, which is widely used for the non-destructive inspection in a gas pipeline. A simulation equipment composed of the magnetizer and iron ring attached on an aluminum disc was constructed instead of a huge gas pipeline facility. With this system. the iron ring could be perfectly demagnetized and signals from the bolt screw stuck on the disc could be clearly detected so that the effects of M$_{res}$S and the inspection number on the detection voltage and B of iron ring were effectively investigated. With increasing the number of inspection, M$_{res}$, B of the iron ring and the detection voltage decreased and then kept at constant values while final M$_{res}$ increased with increasing initial M$_{res}$. If inspection condition were kept unchanged, the detection voltage was proportional to the last M$_{res}$ of the iron ring instead of B. This was probably due to magnetic hysteresis of the iron ring inherited from magnetic domain so that consideration on the magnetic hysteresis was inevitable in the analysis of MFL signal from defects of a gas pipeline. A new inspection scheme using the magnetizer with reversed magnetization in the subsequent inspection was proposed from the result that a high detection voltage could be obtained in the first inspection of gas pipeline with positive M$_{res}$.

Study about material properties of Al particles and deformation of Al alloy substrate by cold gas dynamic spray (초음속 저온분사법에 의한 알루미늄 합금 모재의 변형과 적층된 알루미늄 층의 물성에 대한 연구)

  • Lee, J.C.;Ahn, S.H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.145-148
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    • 2006
  • Cold gas dynamic spray is a relatively new coating process by which coatings can be produced without significant heating during the process. Cold gas dynamic spray is conducted by powder sprayed by supersonic gas jet, and generally called the kinetic spray or cold-spray. Cold-spray was developed in Russia in the early 1980s to overcome the defect of thermal spray method. Its low process temperature can minimize thermal stress and also reduce the deformation of the substrate. Most researches on cold-spray have focused on micro scale coating, but our research team tried to apply this method to macro scale deposition. The macro scale deposition causes deformation of a thin substrate which is usually convex to the deposited side. In this research, the main cause of the deformation was investigated using 6061-T6 aluminum alloy and properties of deposited aluminum layer such as coefficient of thermal expansion, Elastic modulus, hardness, electric conductivity were measured. From the result of the analysis, it was concluded that compressive residual stress was the main reason of substrate deformation while CTE had little effect.

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Study on the Development of Simultaneous Analytical Method for the Residual Organic Chloride Pesticides by Gas Chromatography (기체 크로마토그래피를 이용한 유기 염소계 잔류 농약 동시 분석 방법 개발에 관한 연구)

  • Kim, Woo-Seong;Lee, Bong-Hun;Park, Heung-Jai
    • Journal of Environmental Science International
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    • v.5 no.5
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    • pp.561-567
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    • 1996
  • A method for the simultaneous analysis of 31 residual organic chloride pesticides was studied using gas chromatography. Prepared analytical samples were injected to gas chromatography (HP 5890 Series II plus) on the Ultra-2 column with ECD. The packing materials for column were changed as the following reagents ; florisil and alumina N, The residual solution was loaded to column and was elected pith erection solvents ; ether : benzene (2 : 8) solution, hexane : benzene (1 : 1) solution, dichloromethane, acetone, and methanol. The analytical results showed that 6 kinds of organic chlorides were not detected when florisil (first condition) was used as the column packing material. The nondetected 6 kinds of organic chlorides in the first analytical condition were detected and the recoveries of thrin-pesticides were increased, in particular, captan and captafol, but the recoveries of benzene hexachloride compounds were decreased when dichloromethane and methanol were added as elution solvents (pac'king material was florisil as in the first condition). The recoveries of dichlornuanid, chlorofenvinfos, folpet, and dicofol were increased and that of aldrin was increased, but those of captan and captafol were not good when alumina N was used as the packing material. To detect simultaneously thrin-pesticides, captan, and captafol, florisil and alumina N were used as the packing materials. The elution result showed that captan and captafol were not detected. This was because the column was activated insufficiently. The analytical method was the best (31 kinds of organic chlorides in the residual pesticides were detected sharply and showed high sensitivity) when the column (packing materials were florisil and alumina N: together) was fuliy activated and the impurities were removed using various elution solvents.

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Effect of Melting Pool on the Residual Stress of Welded Structures in Finite Element Analysis

  • Lee, Jang-Hyun;Hwang, Se-Yun;Yang, Yong-Sik
    • Journal of Ship and Ocean Technology
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    • v.11 no.3
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    • pp.14-23
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    • 2007
  • Welding processes cause undesirable problems, such as residual stresses and deformations due to the thermal loads imposed by local heating, melting, and cooling processes. This paper presents a computational modeling technique to simulate the Gas Metal Arc Welding (GMAW) process, emphasizing the effect of the melting bead on the residual stress distribution. Both a three-bar analogy and a three-dimensional thermo-mechanical finite element analysis are carried out in order to explain the effect. Element (de)activation, enthalpy, and adjustment of the reference temperature of thermal strain are considered with respect to the effect of the weld filler metal added to the base metal during a thermo-elastic-plastic analysis. Stress distributions obtained by the present study are compared with measured values and available data from other studies. The effect of the melting bead on the residual stress distribution is discussed and demonstrated.