• Title/Summary/Keyword: Residual Gas

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Effect of Air Additions on the Growth Characteristics of the Compound Layer during Oxynitriding in50%NH3+Air+N2 Atmosphere (50% NH3-Air-N2가스분위기에서 Oxynitriding시 Compound Layer의 성장 특성에 미치는 공기첨가효과)

  • Kim, Y.H.;Lee, Y.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.7 no.3
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    • pp.206-218
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    • 1994
  • In 50%$NH_3+Air+N_2$ atmospheres, the effect of air additions on the growth characteristics of the compound layer during oxynitriding at $570^{\circ}C$ for 2hr in carbon and alloy steels has been investigated. The ammount of apparent residual ammonia during oxynitriding has shown to be increased with air additions(9~36 Vol. %) and X-ray diffraction analysis of case oxynitreded has shown that the compound layer consist of ${\varepsilon}-Fe_{2-3}$(N, C) phase and ${\gamma}^{\prime}-Fe_4$(N,C) phase. In the case of carbon steels, the thickness of oxide layer, compound layer and porous layer and the amount of ${\varepsilon}-Fe_{2-3}$(N,C) phase in the compound layer were increased with additions of air in 50%$NH_3+N_2$ atmospheres. At the same gas composition, the thickenss of oxide layer, compound layer and porous layer in alloy steels showed slightly thin layer thickness compared to those of carbon steels and the ${\gamma}^{\prime}-Fe_4$(N,C) phase in the compound layer of alloy steels was found barely. Therefore, the most obvious effect of air addition in the gas nitriding atmosphere has been found to in crease further kinetics of nitriding reaction.

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Compositional Characterization of Petroleum Heavy Oils Generated from Vacuum Distillation and Catalytic Cracking by Positive-mode APPI FT-ICR Mass Spectrometry

  • Kim, Eun-Kyoung;No, Myoung-Han;Koh, Jae-Suk;Kim, Sung-Whan
    • Mass Spectrometry Letters
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    • v.2 no.2
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    • pp.41-44
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    • 2011
  • Molecular compositions of two types of heavy oil were studied using positive atmospheric pressure photoionization (APPI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). Vacuum gas oil (VGO) was generated from vacuum distillation of atmospheric residual oil (AR), and slurry oil (SLO) was generated from catalytic cracking of AR. These heavy oils have similar boiling point ranges in the range of 210-$650^{\circ}C$, but they showed different mass ranges and double-bond equivalent (DBE) distributions. Using DBE and carbon number distributions, aromatic ring distributions, and the extent of alkyl side chains were estimated. In addition to the main aromatic hydrocarbon compounds, those containing sulfur, nitrogen, and oxygen heteroatoms were identified using simple sample preparation and ultra-high mass resolution FT-ICR MS analysis. VGO is primarily composed of mono- and di-aromatic hydrocarbons as well as sulfur-containing hydrocarbons, whereas SLO contained mainly polyaromatic hydrocarbons and sulfur-containing hydrocarbons. Both heavy oils contain polyaromatic nitrogen components. SLO inludes shorter aromatic alkyl side chains than VGO. This study demonstrates that APPI FT-ICR MS is useful for molecular composition characterization of petroleum heavy oils obtained from different refining processes.

Recent galaxy mergers and star formation history of red sequence galaxies in rich Abell clusters at z ≤ 0.1

  • Sheen, Yun-Kyeong;Yi, Sukyoung K.;Ree, Chang H.;Jeffe, Yara;Demarco, Ricardo;Treister, Ezequiel
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.33.3-34
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    • 2016
  • We explored the GALEX UV properties of optical red sequence galaxies in 4 rich Abell clusters at z ~ 0.1. In particular, we tried to find a hint of merger-induced recent star formation (RSF) in red sequence galaxies. Based on the NUV - r' colors of the galaxies, about 36% of the post-merger galaxies were classified as RSF galaxies with a conservative criterion (NUV - $r^{\prime}{\leq}5$), and that number was doubled (~ 72%) when using a generous criterion (NUV - $r^{\prime}{\leq}5.4$). Post-merger galaxies with strong UV emission showed more violent, asymmetric features on the deep optical images. Also it turned out that all massive RSF galaxies (Mr' < -22 and NUV - $r^{\prime}{\leq}5$) exhibited post-merger signatures. Our results suggested that only 30% of RSF red sequence galaxies show morphological hints of recent galaxy mergers. This implies that internal processes (e.g., stellar mass-loss or hot gas cooling) for the supply of cold gas to early-type galaxies may play a significant role in the residual star formation of early-type galaxies at a recent epoch.

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Molybdenum Recovery from Spent Acid Solution Neutralized by Ammonia Gas (암모니아 가스 중화에 의한 폐산내 Mo 회수에 관한 연구)

  • 차우열;태순재;유진태;박융호;박종진
    • Resources Recycling
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    • v.12 no.2
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    • pp.36-44
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    • 2003
  • The present work relates to the recovery of dissolved Mo from spent mandrel dissolving acid solution by injecting ammonia gas. In order to optimize the process parameters for high yield and high purity of recovered Mo products, a bench scale and a pilot scale experiments were carried out. As a result, more than 99.5% of Mo in spent acid was recovered in the form of ammonium molybdate(4MoO$_3$.$2NH_3$.$H_2$O). The purity of Mo products recovered was higher than 99.5%. In addition, the mother liquor, residual solution after precipitation and filtration of ammonium molybdate solid particles, could be utilized as fertilizers.

Numerical analyses for the structural assessment of steel buildings under explosions

  • Olmati, Pierluigi;Petrini, Francesco;Bontempi, Franco
    • Structural Engineering and Mechanics
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    • v.45 no.6
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    • pp.803-819
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    • 2013
  • This paper addresses two main issues relevant to the structural assessment of buildings subjected to explosions. The first issue regards the robustness evaluation of steel frame structures: a procedure is provided for computing "robustness curves" and it is applied to a 20-storey steel frame building, describing the residual strength of the (blast) damaged structure under different local damage levels. The second issue regards the precise evaluation of blast pressures acting on structural elements using Computational Fluid Dynamic (CFD) techniques. This last aspect is treated with particular reference to gas explosions, focusing on some critical parameters (room congestion, failure of non-structural walls and ignition point location) which influence the development of the explosion. From the analyses, it can be deduced that, at least for the examined cases, the obtained robustness curves provide a suitable tool that can be used for risk management and assessment purposes. Moreover, the variation of relevant CFD analysis outcomes (e.g., pressure) due to the variation of the analysis parameters is found to be significant.

A Study on the Formation of Trench Gate for High Power DMOSFET Applications (고 전력 DMOSFET 응용을 위한 트렌치 게이트 형성에 관한 연구)

  • 박훈수;구진근;이영기
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.7
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    • pp.713-717
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    • 2004
  • In this study, the etched trench properties including cross-sectional profile, surface roughness, and crystalline defects were investigated depending on the various silicon etching and additive gases, For the case of HBr$He-O_2SiF_4$ trench etching gas mixtures, the excellent trench profile and minimum defects in the silicon trench were achieved. Due to the residual oxide film grown by the additive oxygen gas, which acts as a protective layer during trench etching, the undercut and defects generation in the trench were suppressed. To improve the electrical characteristics of trench gate, the hydrogen annealing process after trench etching was also adopted. Through the hydrogen annealing, the trench corners might be rounded by the silicon atomic migration at the trench corners having high potential. The rounded trench corner can afford to reduce the gate electric field and grow a uniform gate oxide. As a result, dielectric strength and TDDB characteristics of the hydrogen annealed trench gate oxide were remarkably increased compared to the non-hydrogen annealed one.

Analysis on the Mass Loss in Self-blast type $SF_6$ Gas Circuit Breaker (Self-blast형 $SF_6$ 가스 차단기의 노즐용삭 분석)

  • Jeong, Young-Woo;Bae, C.Y.;Ahn, H.S.;Choi, J.W.;Oh, I.S.
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1422-1423
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    • 2006
  • In our study, the PTFE nozzle ablation in the high-voltage self-blast type $SF_6$ gas circuit breaker was investigated. The test circuit breaker has the structure that the pin electrode is moving and the pressure reservoir volume and the dimension is almost same as commercial 145kv 40kA circuit breaker for similar result in real circuit breaker. The variation of current and arcing time was the range of $36kA_{rms}$(symmetry) - $40kA_{rms}$(asymmetry) and 10-16 ms. From the measured data the tendecy of the mass loss of the nozzle to current load and arc energy was estimated. In this process, the distance from the arc to nozzle(PTFE) surface, area which was exposed to arc and stroke contour was considered. These results will be used to enhance the accuracy of the computational fluid dynamics analysis in circuit breaker and estimate the residual life time of a circuit breaker.

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A Study on the CAI Combustion Characteristics and Stratified Combustion to Extend the Operating Region Using Direct Injection Gasoline Engine (직접분사식 가솔린 엔진을 이용한 CAI 연소특성 및 운전영역 확대를 위한 성층 연소 특성에 관한 연구)

  • Lee, Chang-Hee;Choi, Young-Jong;Lim, Kyoung-Bin;Lee, Ki-Hyung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.5
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    • pp.25-31
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    • 2006
  • Controlled Auto Ignition(CAI) combustion has great potential in achieving significant increase in engine efficiency, while simultaneously reducing exhaust emissions. The process itself involves the auto ignition and subsequent simultaneous combustion of a premixed charge. In this study, NVO(Negative Valve Overlap) system was applied to a CAI engine in order to use residual gas. The fuel was injected directly to the cylinder under the high temperature condition resulting from heating the intake port to initiate CAI combustion. This paper introduced the valve timing strategy and experimental set-up. From this study, the effect of engine speed and valve timing on CAI combustion and exhaust emissions was clarified. In addition, stratified charge method was used to extend CAI operating region.

A Study on Plasma Sprayed Porous Super Austenitic Stainless Steel Coating for Improvement of Bone Ingrowth (Bone ingrowth 향상을 위해 플라즈마 용사된 초내식성 오스테나이트 스테인리스강의 다공성 코팅층에 대한 연구)

  • 오근택;박용수
    • Journal of the Korean institute of surface engineering
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    • v.29 no.2
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    • pp.81-92
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    • 1996
  • The cementless fixation of bone ingrowth by porous coatings on artificial hip joint prostheses are replacing polymethylmethacrylate(PMMA) bone cement fixations. However, the major interests in the field of porous metal coating are environmental corrosivity accelerated by metal ion release, deterioration in the mechanical property of the coating, and the mechanical failure of the coatings as well as the substrate. Therefore, the selection of right materials for coatings and the development of porous coating techniques must be accomplished. Because of the existing problems in Ti and Ti alloys which are used extensively, this study is focused on the plasma spraying technique for coating on super stainless steel substrate. In order to determine the optimum conditions which satisfy the requirement for the porous coatings, under the plasma spraying, we selected the experimental parameters which extensively influenced on the characteristics of the coating through the pre-examination. Spray distance has been selected among 120, 160, and 200mm and primary gas flow rate among 70, 100, and 130 SCFH. Current and secondary gas($H_2$) flow rate was fixed at 400A, and 15 SCFH respectively. To understand the characteristics of the coatings, surface morphology, cross-sectional micro-structure, surface roughness, residual stress, and corrosion resistance were elucidated and the best conditions for the bone ingrowth improvement on artificial hip joint prostheses were found.

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Hydrogen Production by the Photocatalystic Effects in the Microwave Water Plasma

  • Jang, Soo-Ouk;Kim, Dae-Woon;Koo, Min;Yoo, Hyun-Jong;Lee, Bong-Ju;Kwon, Seung-Ku;Jung, Yong-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.284-284
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    • 2010
  • Currently, hydrogen has been produced by Steam Reforming or partial oxidation reforming processes mainly from oil, coal, and natural gas and results in the production of $CO_2$. However, these are influenced greatly on the green house effect of the earth. so it is important to find the new way to produce hydrogen utilizing water without producing any environmentally harmful by-products. In our research, we use microwave water plasma and photocatalyst to improve dissociation rate of water. At low pressure plasma, electron have high energy but density is low, so temperature of reactor is low. This may cause of recombination in the generated hydrogen and oxygen from splitting water. If it want to high dissociation rate of water, it is necessary to control of recombination of the hydrogen and oxygen using photocatalyst. We utilize the photocatalytic material($TiO_2$, ZnO) coated plasma reactor to use UV in the plasma. The quantity of hydrogen generated was measured by a Residual Gas Analyzer.

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