• 한국고분자학회:학술대회논문집
• /
• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
• /
• pp.184-184
• /
• 2006

We have succeeded in the preparation of high molecular weight polybenzimidazoles by solution polycondensation of 3,3'-diaminobenzidine tetrahydrochloride with isophthalic acid, terephthalic acid, or with their derivatives using polyphosphoric acid both as solvent and as condensing agent. Also, we modified phosphoric acid into fluoroalkyl-phosphonic acids[F-PA]. The main reasons are as follows, first of all F-PAs are stronger acids than PA and alkylphosphonic acids which should promote proton hopping and transport. In addition, F-PA has weaker adsorption onto Pt which help to prevent electrocatalyst poisoning and promote higher oxygen reduction activity. The ionic conductivity of 85%-H3PO4 doped membranes show $10^{-2}\;Scm^{-1}\;to\;3{\times}10^{-2}\;Scm^{-1}\;at\;150^{\circ}C$ MEA with 2 %-added electrolyte shows slightly higher cell voltage than the others.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
• /
• pp.21-24
• /
• 2008

Proton Exchange Membrane Fuel Cell (PEMFC) is an attractive candidate for residential power generator due to fast start-up and stop, high efficiency, low emission, and high power density. In this study, we employ short module stack to understand the performance of the unit cell of the stack in terms of operating temperatures. To simulate the practical fuel cell stack of residential power generator, the structure and active area of the short module stack is kept the same as that of the practical fuel cell. The results shows that the electric potential of short module stack is different from the number of cells times the potential of unit cell because of cell-to-cell variation.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2008년도 추계학술대회 논문집
• /
• pp.10-13
• /
• 2008

Fuel cell systems have witnessed remarkable development in recent years as they offer a clean and efficient alternative for power generation. Testing was conducted to determine the safety performance of a residential fuel cell system when subjected to abnormal operation condition, especially for voltage sag and fuel cut. In case of voltage sag to 198V, its arriving time at rated power had shown a slight lag but there wasn't any noticeable change when operating it between rated voltage(220V) and 10% voltage sag(198V). In case of fuel cut, it also showed stable shut-down characteristics. The test results are being used to develop a new safety evaluation for residential fuel cell system.

• 전기학회논문지
• /
• 제60권6호
• /
• pp.1280-1285
• /
• 2011

Recently, due to the use of fossil fuels for electric power production, carbon emissions increased excessively. Thereby, in order to replace fossil fuels, many studies about fossil fuels such as solar and fuel cell energy source are progressing. Fuel cell system has high energy conversion efficiency. Also, fuel cell system is environmentally friendly system because the carbon emission is almost not occur. Therefore, the fuel cell system is considered as the core technology of in the fields of the future energy and environmental. Fuel cell system has an effect on distribution power system because another power source of other than large power plants. So, fuel cell system can be degradation reason of power quality in the power system. In this paper, we constructed the system for an assessment on harmonics effect. The system is composed with power source, harmonics generation and linear load, fuel cell system. we also performed assessment on harmonics effect in customer and the distributed power system during grid connection of residential fuel cell system. An assessment cases are divided into three. A Case 1 is state that residential load and fuel system are connected to grid, Case 2 is state that residential load and harmonics load are connected to grid, and Case 3 is state that all loads are connected to grid. As a output of fuel cell system is increase, analysis results based on assessment system showed that power quality became more aggravation as effect of harmonics.

• 한국수소및신에너지학회논문집
• /
• 제20권2호
• /
• pp.104-115
• /
• 2009

In case of residential fuel cell system, it is significant to stably supply heat and power to a house with high efficiency and low cost for the successful commercialization. In this paper, the control strategy analysis has been performed to minimize the total cost including capital and operating cost of the residential fuel cell system. The proposed analysis methodology is based on the simulator including the efficiency models as well as the cost data for fuel cell components. The load control strategy is the key factor to decide the system efficiency and thus the cost analysis is performed when the fuel cell system is operated for several different load control logics. Additionally, annual efficiency of the system based on the seasonal load data is calculated since system efficiency is changeable according to the electric and heat demand change. As a result, the hybrid load control combined electricity oriented control and heat oriented control has the most economical operation.

• 한국수소및신에너지학회논문집
• /
• 제14권1호
• /
• pp.35-45
• /
• 2003

Polymer electrolyte fuel cells(PEFC) have been considered to be a suitable candidate for residential, portable and mobile applications, due to their high efficiency and power density, even at low operating temperature. KIER developed a 5kW class PEFC system for residential application and operated the system for over 1,000 hours. To develop a 5kW PEFC system, performance of a cell was improved through successive tests of single cell of small and large area. Fabrication of three 2,5 kW class stacks, design and fabrication of natural gas reformer, design of auxiliary equipments such as DC/DC converter, DC/AC inverter and humidifying units were carried out along with integration of components, operation and evaluation of total system. During the development period from 1999 to 2001, MEA(membrane electrode assembly) fabrication technologies, design and fabrication technologies for separators, stacking technologies and so on were developed, thereby providing basis for developing stacks of higher efficiency and power density in the future. Experience of development of natural gas reformer opened possibilities to use various kinds of fuels. Main results obtained from the development of a 5kW class PEFC system for residential application are summarized.

• 한국수소및신에너지학회논문집
• /
• 제16권4호
• /
• pp.364-371
• /
• 2005

Fuel cell systems(FCS) have a financial and environmental advantage by providing electricity at a high efficiency and useful heat. For use in a residence, a polymer electrolyte fuel cell system(PEFCS) with a battery pack and a hot water storage tank has been modelled and simulated. The system is operated without connection to grid line. Its electric conversion efficiency and heat recovery performance are highly dependent on operation strategies and also on the seasonal thermal and electric load pattern. The output of the fuel cell is controlled stepwise as a function of the state of the battery and/or the storage water tank. In this study various operation strategies for cogeneration fuel cell systems are investigated. Average fuel saving rates at different seasons are calculated to find proper load management strategy. The scheme can be used to determine the optimal operating strategies of PEFCS for residential and building applications.

• Journal of Electrical Engineering and Technology
• /
• 제5권2호
• /
• pp.307-318
• /
• 2010

In this work, an accurate analysis of low frequency current ripple in residential fuel cell power generation systems is performed based on the proposed residential load model and its unique operation algorithm. Rather than using a constant dc voltage source, a proton exchange membrane fuel cell (PEMFC) model is implemented in this research so that a system-level analysis considering the fuel cell stack, power conditioning system (PCS), and the actual load is possible. Using the attained results, a comparative study regarding the discrepancies of low frequency current ripple between a simple resistor load and a realistic residential load is performed. The data indicate that the low frequency current ripple of the proposed residential load model is increased by more than a factor of two when compared to the low frequency current ripple of a simple resistor load under identical conditions. Theoretical analysis, simulation data, and experimental results are provided, along with a model of the load usage pattern of low frequency current ripples.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
• /
• pp.78-81
• /
• 2008

Residential fuel cell cogeneration systems have gained much interest due to its high efficiency. In the present study, we have performed numerical simulation of residential fuel cell cogeneration system which includes a fuel cell/battery hybrid system. The cogeneration system consists of 1kW PEFC, two 60Ah batteries, inverter/converter and reformer. Several empirical models have been employed for respective components to improve the accuracy of the simulations. The load varies seasonally. The present simulations can successfully predict the characteristics of the hybrid cogeneration system and thus it can be utilized for establishing an optimal operating strategy of the system.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2008년도 추계학술대회 논문집
• /
• pp.55-58
• /
• 2008

Residential fuel cell cogeneration systems have gained much interest due to its high efficiency. In this study, we have performed numerical simulation of residential fuel cell cogeneration system which includes a fuel cell/grid hybrid system. The cogeneration system consists of 1kW PEFC, cooling system, inverter/converter and reformer. Several empirical models have been employed for respective components to improve the accuracy of the simulations. The load varies seasonally. The present simulations can successfully predict the characteristics of the hybrid cogeneration system and thus it can be utilized for establishing an optimal operating strategy of the system.