• Proceedings of the KSME Conference
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• 2004.11a
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• pp.1172-1177
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• 2004

The evolution of incipient soot particles has been examined by high resolution electron microscopy (HRTEM) and elemental analyzer in ethylene-air inverse diffusion flames. Laser Induced Incandescence(LII) and laser scattering methods were introduced for examining the change of soot volume fraction and morphological properties in combustion generated soot qualitatively. Soot particles, collected by thermophoretic sampling were analyzed by using HRTEM to examine the nano structure of precursor particles. HRTEM micrographs apparently reveal a transformation of condensed phase of semitransparent tar-like material into precursor particles with relatively distinct boundary and crystalline which looks like regular layer structures. During this evolution histories C/H analysis was also performed to estimate the chemical evolution of precursor particles. The changes of C/H ratio of soot particles with respect to residence time can be divided into two parts: one is a very slowly increasing regime where tar-like materials are transformed into precursor particles (inception process) the other is an increasing region with constant rate where surface growth affects the increase of C/H ratio dominantly (surface growth region). These results provide a clear picture of a transition to mature soot from precursor materials.

• Journal of Korean Society for Atmospheric Environment
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• v.12 no.2
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• pp.189-198
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• 1996

Mercury (Hg) is ubiquitous throughout the earth's atmosphere. The uniqueness of its atmospheric geochemistry is well-known with the high environmental mobility and relatively long atmospheric residence time (c.a., 1 year) associated with its high chemical stability. Despite a growing recognition of the environmental significance of its global cycling, the prexisting Korean database for atmospheric Hg is extremely rare and confined to a number of concentration measurements conducted under relatively polluted urban atmospheric environments. To help activate the research on this suvject, an in-depth analysis on the current development in the measurements of atmospheric mercury and the associated fluxes has been made using the most using the most updated data ests reported worldwide. As a first step toward this purpose, the most reliable techniques commonly employed in the measurements of its concentration in the background atmosphere are introduced in combination with the flux measurement techniques over soil surface such as: dynamic enclosure (or field flux chamber) method and field micrometeorological method. Then the results derived using these measurement techniques are discussed and interpreted with an emphasis on its mobilization across the terrestrial biosphere and atmosphere interface. A unmber of factors including air/soil temperature, soil chemical composition, soil water content, and barometric pressure are found out to be influential to the rate and amount of such exchange processes. Although absolute magnitude of such exchange processes is insignificant relative to that of the major component like the oceanic environment, this exchange process is thought to be the the predominant natural pathway for both the mobilization and redistribution of atmospheric Hg on a local or regional scale.

• Journal of the Korean Society of Combustion
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• v.18 no.4
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• pp.53-58
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• 2013

Lots of Coal power plants (about 30) using bituminous coals are being run in Korea. The use of high volatile low grade sub-bituminous coal is increasingly extended because of imbalance between the worldwide coal supply and demand. Mill-fire has been an important issue since the use of such sub-bituminous coal. In existing coal plants of Korea, shutdown of coal and air supplies could be only a way, and an alternative has not been found in suppressing the mill fire. The inside fowfield in the mills has a highly fuel-rich, low temperature, and high velocity and non-reactive such that it could be a nonreactive system essentially. Nevertheless, occasional fire-occurrence could be attributed to the existence of an ignition source. However it has not been so far investigated in detail. The current work has a focus on suppressing the mile fire via some parametric experimental study such as effects of temperature, residence time, ignition source, and inert gas mixing. The results show that an small amount of $CO_2$- or $N_2$-mixing with air is very effective in suppressing fire formation even at high temperatures or flying sparks. The results suggest that exhaust gas recirculation into the mill should be an alternative to suppress mill fire.

• Journal of the Korean Wood Science and Technology
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• v.37 no.3
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• pp.231-238
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• 2009

Red pine (Pinus densiflora) has been used for structural wood members of Korean traditional residence (HANOK) and historic wooden structures. For these constructions, generally, natural drying has conducted for long time; however, unless drying is conducted sufficiently, it could cause several drying defects such as check or warping. Shrinkage changes of red pine species for small clear specimens and big-size specimens according to the conditions of moisture contents, were examined. For the estimation of volumetric shrinkage at a special moisture content, it was more precise to divide the range of moisture contents into two groups, green to air-dry and air-dry to oven-dry. The volumetric shrinkage had no difference with specimen sizes in sapwood, but decreased as specimen size increased in heartwood.

• Journal of the Korean Society of Combustion
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• v.9 no.2
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• pp.38-44
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• 2004

The evolution of incipient soot particles has been examined by high resolution electron microscopy (HRTEM) and elemental analyzer in ethylene-air inverse diffusion flames. Laser Induced Incandescence(LII) and laser scattering methods were introduced for examining the soot volume fraction and morphological properties in combustion generated soot qualitatively. Soot particles, collected by thermophoretic sampling, were analyzed by using HRTEM to examine the nano structure of precursor particles. HRTEM micrographs apparently reveal a transformation of condensed phase of semitransparent tar-like material into precursor particles with relatively distinct boundary and crystalline which looks like regular layer structures. During this evolution histories, C/H analysis was also performed to estimate the chemical evolution of precursor particles. The changes of C/H ratio of soot particles with respect to residence time can be divided into two parts: one is a very slowly increasing regime where tar-like materials are transformed into precursor particles (inception process) the other is an increasing region with constant rate where surface growth affects the increase of C/H ratio dominantly (surface growth process). These results provide a clear picture of a transition to mature soot from precursor materials.

• Ocean and Polar Research
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• v.25 no.3
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• pp.269-275
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• 2003

Effects of different operating factors including superficial air velocity (SAV), hydraulic residence time (HRT), protein concentration, and foam overflow height on protein removal by a foam fractionator in simulated seawater aquaculture system were investigated. This experiment was conducted on batch and consecutive modes at different combinations of the affecting factors. The foam fractionator had a diameter of 20cm and a height of 120cm and the experiment was conducted with synthetic wastewater. In 5 consecutive trials, protein concentrations in culture tank water decreased faster when the foam fractionator was operated at higher SAVs and lower HRTs. In batch trials, protein removal rates increased with an increase in SAV but decreased with an increase in URT. Higher protein concentrations in the bulk solution resulted in higher protein removal rates. Protein concentrations in the collected foam condensates increased but the foam overflow rates decreased with the increase of foam overflow heights. The results of this experiment indicate that foam fractionation would be an effective way for protein removal in seawater aquaculture systems and the performance of the foam fractionator depends largely on the operating parameters, especially SAV.

• 한국연소학회:학술대회논문집
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• 2004.11a
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• pp.169-174
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• 2004

The NOx emission characteristics with oxygen enrichment in nonpremixed counterflow and coflow jet flame of $CH_4$ fuel have been investigated numerically. A small amount of nitrogen is included in oxygen-enriched combustion, in order to consider the inevitable $N_2$ contamination by air infiltration. The results show that the initial increase of NO with increasing oxygen enrichment is due to increasing temperature and residence time, while its subsequent decrease above 75% oxygen is due to decreasing the consumption rate of nitrogen. When oxygen addition exceeds 30%, Thermal NO gradually becomes the dominant production pathway and Prompt NO becomes negative pathway for net NO production rate. It is also seen that Thermal NO plays an important role in NO reduction when strain rate increase in oxygen-enriched combustion. Finally, the results of EINOx with oxygen enrichment in coflow jet flame show the similar profile with those of conterflow flame. It is confirmed that, with leakage of 1% nitrogen in the oxidizer stream, the corresponding EINOx is eight times of that emitted from regular $CH_4$/Air flame.

• Solar Energy
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• v.2 no.2
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• pp.11-20
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• 1982

This paper presents the experimental investigations of a system as a second treatment means to increase boiler efficiency and heat transfer from combustion gas to heating surfaces in the case of spray combustion. In order to reburn residual combustible components accelerate the burning rate of sprayed fuel droplets, improve the diffusion flame and delay the residence time of the flame, advice with slit type nozzles for spouting preheated supplementary air is used in this study. In the experiment, boiler efficiency and smoke concentration in the exhaust gas at given conditions are measured in both case of installing and not-installing device in the model of combustion chamber which was designed to be equipped with five surfaces. The results obtained in this experiment are as follows ; 1. The optimum values of air rate ${\lambda}$ are about 1.3 in both case. 2. The exhaust gas temperature in the case with device increases about $30{\sim}70^{\circ}C$ above that of the case without the device. 3. Boiler efficiency and reduction effect of smoke emissions are improved considerably.

• Journal of Environmental Health Sciences
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• v.34 no.4
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• pp.333-341
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• 2008

In this study, the possibility and the optimal conditions for treating slurry type piggery wastewater using supercritical water oxidation were tested in the laboratory. The results could be summarized as follows; The slurry type piggery wastewater, which was diluted 50 times, was treated most effectively at the pressure of 300 bar, the temperature of $550^{\circ}C$ and the residence time of 10 minutes. The air saturated water was injected, as an oxidizing agent, and the removal efficiencies of $COD_{Cr}$, T-N, $NH_4^+$-N and T-Pattheoptimal conditions were 92, 40, 59 and 100%, respectively. Therefore, analte rnativemea suremu stbetaken to improve theremo valefficiency of the nitrogen compounds.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.231-239
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• 2003

In this study, the waste of landfill was treated using advanced enriched oxygen combustion system. The oxygen concentration of this study was 21%, 25%, 30% and 40% and the operating capacity was 200 g/min and the residence time was 10 minutes. As increased the oxygen concentration of combustion air. temperature of the incinerator was increased and the temperature was increased rapidly when the oxygen concentration was 30%. As increased the oxygen concentration, the NOx (ppm) of flue gas increase d for thermal NOx, however the CO (ppm) of flue gas decreased according to the increase of combustion efficiency . The optimum operation condition of incineration was obtained when the oxygen concentration is 30%${\sim}$40%. The unburned carbon of ash decreased from 10% to 4% when the oxygen concentration was increased from 21% to 30%, therefore the high combustion efficiency can be obtained if used the oxygen enriched combustion system.