• Title/Summary/Keyword: Replacement method

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Nanostructure Control of PtNiN/C Catalysts for Oxygen Reduction Reaction by Regulating Displacement Rate of Precursor (전구체 치환 속도 조절을 통한 산소환원반응용 PtNiN/C 촉매의 나노구조 제어)

  • Dong-gun Kim;Seongseop Kim;Sung Jong Yoo;Pil Kim
    • Clean Technology
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    • v.30 no.1
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    • pp.55-61
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    • 2024
  • Efforts are actively underway to address the issues related to the high cost of Pt-based catalysts for oxygen reduction reactions by designing high-performance Pt-based alloys through the control of their nanostructures. In this study, a method was proposed to control the nanostructure of Pt-based alloys, either hollow or core-shell, by adjusting the pH of the solution during the galvanic replacement reaction between the carbon-supported nickel-nickel nitride composite and the Pt ions. The physical characteristics, including the state, quantity, and morphology of the metal particles under different preparation conditions, were evaluated through X-ray diffraction, transmission electron microscopy, and inductively coupled plasma. When the prepared catalysts were employed for the oxygen reduction reaction, they exhibited an improvement in area specific-activity compared to a commercial Pt/C, with a 1.7 and 1.9-fold enhancement for the hollow and core-shell structured catalysts, respectively.

Determination of High-pass Filter Frequency with Deep Learning for Ground Motion (딥러닝 기반 지반운동을 위한 하이패스 필터 주파수 결정 기법)

  • Lee, Jin Koo;Seo, JeongBeom;Jeon, SeungJin
    • Journal of the Earthquake Engineering Society of Korea
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    • v.28 no.4
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    • pp.183-191
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    • 2024
  • Accurate seismic vulnerability assessment requires high quality and large amounts of ground motion data. Ground motion data generated from time series contains not only the seismic waves but also the background noise. Therefore, it is crucial to determine the high-pass cut-off frequency to reduce the background noise. Traditional methods for determining the high-pass filter frequency are based on human inspection, such as comparing the noise and the signal Fourier Amplitude Spectrum (FAS), f2 trend line fitting, and inspection of the displacement curve after filtering. However, these methods are subject to human error and unsuitable for automating the process. This study used a deep learning approach to determine the high-pass filter frequency. We used the Mel-spectrogram for feature extraction and mixup technique to overcome the lack of data. We selected convolutional neural network (CNN) models such as ResNet, DenseNet, and EfficientNet for transfer learning. Additionally, we chose ViT and DeiT for transformer-based models. The results showed that ResNet had the highest performance with R2 (the coefficient of determination) at 0.977 and the lowest mean absolute error (MAE) and RMSE (root mean square error) at 0.006 and 0.074, respectively. When applied to a seismic event and compared to the traditional methods, the determination of the high-pass filter frequency through the deep learning method showed a difference of 0.1 Hz, which demonstrates that it can be used as a replacement for traditional methods. We anticipate that this study will pave the way for automating ground motion processing, which could be applied to the system to handle large amounts of data efficiently.

Estimating the Damage Cost of Deforestation due to Limestone Mining: Focusing on Donghae, Samcheok and Yeongwol City (석회석 광산에 의한 산림 피해의 비용 추정: 동해시, 삼척시, 영월군을 중심으로)

  • Shin, YoungChul
    • Environmental and Resource Economics Review
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    • v.18 no.3
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    • pp.431-455
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    • 2009
  • This study estimates the WTP for the plan of solving deforestation due to limestone mining and calculates that damage cost using contingent valuation method. As the results of analysing a dichotomous choice CV data, the yearly mean WTP per household for the plan is 5,045 won(95% confidence interval : 3,729~6,360 won) in single bounded CV model and is 4,361 won(95% confidence interval : 3,710~5,012 won) in double bounded CV model. The damage cost of deforestation due to limestone mining can be estimated as 55.3% of WTP for the plan which is assigned to restoring the deforestation area to the original or similar alternative state. The average yearly deforestation cost of 1 ha due to limestone mining is reached 20.90 million won(95% confidence interval : 16.53~25.27 million won). And the asset value of that 1 ha damage is 160.02 million won(95% confidence interval : 126.56~193.49 million won). The fact is found that the damage cost of deforestation using replacement cost method is likely to be underestimated. The total damage cost of deforestation because of limestone mining in 3 cities (Donghae, Samcheok, Yeongwol) is 204.0 billion won(95% confidence interval : 161.4~246.7 billion won) which is composed of 26.5% for Donghae, 28.9% for Samcheok, and 44.6% for Yeongwol according to the damage size of deforestation due to limestone mining in 3 cities.

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A Study on the pH Reduction of Controlled Low Strength Material with Coal Ash (석탄회를 활용한 CLSM의 pH 저감에 관한 연구)

  • Kim, Youngil;Jee, Sunghyun;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.9
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    • pp.39-45
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    • 2010
  • Controlled low strength material(CLSM) is produced by mixing portland cement, fine aggregates, water and chemical admixtures. Sand is the most commonly used as the fine aggregates in the conventional CLSM. It is getting more and more difficult to obtain sand in Korea so it is required that the alternative materials be developed as the replacement of sand. Since the engineering characteristics of coal ash are similar to the sand, it becomes necessary to examine the application of the coal ash as the alternative material for CLSM and as the environment-friendly material. When the results meet the optimum pH level that plants can live, it can be expanded the scale of application of the study on the plant as the important field. This study was subjected to present the method to reduce the pH range of CLSM to a suitable condition that plants can survive. To verify this method, the care of neutralization was conducted by immersing the specimen to Ammonium monohydrogen phosphate. Before curing and neutralization, the maximum pH of developmental CLSM is approximately 11. However, the pH value of developmental CLSM has under 9.5 after peaceful curing and neutralization management.

Analysis of the Physical Properties of Ground before and after Low Flowing Grouting (저유동성 그라우팅 시공전후 지반의 물성변화 분석)

  • Seo, Seok-Hyun;Lee, Jung-Sang;Kang, Won-Dong;Jung, Euiyoup
    • Journal of the Korean Geosynthetics Society
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    • v.18 no.4
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    • pp.115-127
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    • 2019
  • The low-flow grouting injection technique, the target construction method for this study, is a method of pouring mortar into the ground by non-emission replacement principle, which can be expected to increase the density of the ground, and, in some cases, be used as a base file using the strength of the high injection solids, along with low noise, low pollution, and high durability. To verify that the dynamic characteristics of the ground are improved by the low-flow injection technique, the test work was conducted on the site and physical tests were performed, and the quality of the improvement formed in the ground was verified through the indoor test on the core and core recovery rate was analyzed. The density logs test layer calculated the volume density of the ground layer by using the Compton scattering of gamma-rays, and the sonic logs was tested on the ground around the drill hole using a detector consisting of sonar and receiver devices inside the drill hole. As a result of the measurement of the change in physical properties (density and sonic logs) before and after grouting, both properties were basically increased after infusion of grout agent. However, the variation in density increase was greater than the increase in speed after grouting, and the ground density measurement method was thought to be effective in measuring the fill effect of the filler. Strength and core recovery rates were measured from specimens taken after the age of 28 days, and the results of the test results of the diffusion and strength test of the improved products were verified to satisfy the design criteria, thereby satisfying the seismic performance reinforcement.

Suggestion of the Settlement Estimation Method for Granular Compaction files Considering Lateral Deformations (횡방향 변형을 고려한 조립토 다짐말뚝의 침하량 평가기법 제안)

  • Hwang Jung-Soon;Kim Hong-Taek;Kim Seung-Wook;Koh Yong-Il
    • Journal of the Korean Geotechnical Society
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    • v.21 no.3
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    • pp.149-157
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    • 2005
  • In cases of the loosely accumulated ground and soft clayey soils, the settlement criterion usually governs in evaluating the stability of structures. The settlement is also a dominant factor to control the design of granular compaction piles mainly applied to the reinforcement of foundation structures in soft ground. In the previous studies, settlement behaviors of granular compaction piles have generally been analyzed with an evaluation of the settlement reduction factor based on the load-sharing ratio and the replacement ratio. In this approach, however, since the reinforced ground with granular compaction piles is simplified as the composite ground, only the difference of a relative vertical strength between piles and soils is taken into account without reflecting lateral behaviors of granular compaction piles. In the present study, the method of estimating the settlement of granular compaction piles is proposed by synthetically considering a vertical strength of the ground, lateral behaviors of granular compaction piles, the strength of pile materials, a pile diameter, and an installation distance of the pile. Further, far the verification of a validity of the proposed method, predicted settlements are compared with results from previous studies. In addition, parametric studies are performed together with detailed analyses of relevant design parameters.

Ultrasonic Pulses Characteristics in Lightweight Fine Aggregate Concrete under Various Load Histories (하중 이력에 따른 경량 잔골재 콘크리트의 초음파 특성)

  • Yoo, Kyung-Suk;Kim, Jee-Sang;Kim, Ik-Beam
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.3
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    • pp.209-216
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    • 2014
  • One of the widely used NDT(Non-destructive techniques) is the ultrasonic pulse velocity (USPV) method, which determines the travel time of the ultrasonic pulse through the tested materials and most studies were focused on the results expressed in time domain. However, the signal of ultrasonic pulse in time domain can be transformed into frequency domain, through Fast fourier transform(FFT) to give more useful informations. This paper shows a comparison of changes in the pulse velocity and frequency domain signals of concrete for various load histories using lightweight fine aggregates. The strength prediction equation for normal concrete using USPV cannot be used to estimate lightweight fine aggregate concrete strength. The signals in frequency domain of ultrasonic pulse of lightweight fine aggregate concrete does not show any significant difference comparing with those of normal concrete. The increases in stress levels of concrete change the pulse velocities and maximum frequencies, however the apparent relationship between themselves can not be found in this experiment.

Determination of Adequate Method for Protein Extraction from Rice Bran and the Substitution of Dried Skim Milk with Protein Concentrate from Rice Bran in Early Weaned Pigs

  • Phipek, W.;Nagasinha, C.;Vallisuth, S.;Nongyao, C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.24 no.9
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    • pp.1268-1273
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    • 2011
  • The present study was conducted to determine a feasible method of protein concentrate extraction from rice bran (RBPC) and its effect as a substitution for skim milk in early weaning pig diets. An investigation to extract protein concentrate from full fat rice bran was undertaken to determine the best ratio of water and rice bran, the amount of NaOH and a HCl solvent to use in a simple paddle-type mixer with modified spinning to produce RBPC. The results stated that the best ratio for water mixing in the RBPC extraction process was 1:5 with 20 g NaOH and 30 min in a paddle-type mixer at 300 rpm. A mix of 250 ml 0.2 N HCl was optimum for neutralization and protein precipitation. After the fluid was spun out with a washing machine, the sediment was left for 12-14 hours to complete the filtration. One kilogram of rice bran could produce an average of 324.5 gram RBPC and it contained 3.40% ash, 496.48 kcal of GE/100 gram, 1.94% crude fiber, 28.20% ether extract, 7.64% moisture and 16.66% crude protein, respectively. A total of 45 crossbred piglets, weaned at 3 weeks of age were allotted into control diet (A) and dietary treatments formulated with a four different rates of RBPC substitution for skim milk at a percentage of 25 (B), 50 (C), 77 (D) and 100 (E) respectively, in a randomized complete block (RCB) design. All piglets had free access to feed and water until 8 week of age when the experiment ended. Feed intake, average daily gain, growth rate and feed efficiency were not affected by dietary treatments. Blood test parameters after completion of the growth trial indicated normal health. Even though the mean of cell hemoglobin concentration was significantly different between treatments (p<0.05) it was still within the normal range. The cost difference for BW gain of 100% RBPC substituted for skim milk in the weaning diet was approximately 35% lower than that of the control and the relative cost of production was 96.67, 92.85, 70.75 and 64.48% lower for the replacement of 25, 50, 75 and 100% of skim milk respectively. These results implied that this technology is feasible for use by small scale farmers to improve their self-reliance.

Evaluation of Application of High Quality Recycled Fine Aggregate Manufacturing System by the Drying Specific Gravity Separation Method (건식비중분리법에 의한 고품질 재생잔골재 제조생산 시스템의 적용성 평가)

  • Kim Moo-Han;Kim Jae-Hwan;Kim Yong-Ro;Na Chul-Sung
    • Journal of the Korea Concrete Institute
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    • v.17 no.1 s.85
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    • pp.69-76
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    • 2005
  • In this study, the high qualify recycled fine aggregate manufacturing system by the drying specific gravity separation method was evaluated. For the evaluation of the performance of the recycled aggregate, the engineering properties and durability of recycled aggregate has been tested. From the test results, the quality of recycled fing aggregates was improved by high quality recycled fine aggregate manufacturing system and satisfied with the quality standards of KS and JASS 5. Also, compressive and tensile strengths of recycled concrete show no critical difference caused by recycled fine aggregate replacement ratio. However, durability such as carbonation depth chloride ion penetration depth and drying shrinkage shows more deterioration than the concrete without recycled fine aggregate

Computer-Aided Diagnosis for Liver Cirrhosis using Texture features Information Analysis in Computed Tomography (컴퓨터단층영상에서 TIA를 이용한 간경화의 컴퓨터보조진단)

  • Kim, Chang-Soo;Ko, Seong-Jin;Kang, Se-Sik;Kim, Jung-Hoon;Kim, Dong-Hyun;Choi, Seok-Yoon
    • The Journal of the Korea Contents Association
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    • v.12 no.4
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    • pp.358-366
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    • 2012
  • Cirrhosis is a consequence of chronic liver disease characterized by replacement of liver tissue by fibrosis, scar tissue and regenerative nodules leading to loss of liver function. Liver Cirrhosis is most commonly caused by alcoholism, hepatitis B and C, and fatty liver disease, but has many other possible causes. Some cases are idiopathic disease from unknown cause. Abdomen of liver Computed tomography(CT) is one of the primary imaging procedures for evaluating liver disease such as liver cirrhosis, Alcoholic liver disease(ALD), cancer, and interval changes because it is economical and easy to use. The purpose of this study is to detect technique for computer-aided diagnosis(CAD) to identify liver cirrhosis in abdomen CT. We experimented on the principal components analysis(PCA) algorithm in the other method and suggested texture information analysis(TIA). Forty clinical cases involving a total of 634 CT sectional images were used in this study. Liver cirrhosis was detected by PCA method(detection rate of 35%), and by TIA methods(detection rate of 100%-AGI, TM, MU, EN). Our present results show that our method can be regarded as a technique for CAD systems to detect liver cirrhosis in CT liver images.