• Title/Summary/Keyword: Removal efficiency of fouling

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NOM fouling and Removal of Micro-pollutants in RO and NF Membrane processes (RO 및 NF막에서의 부식질에 의한 Fouling 및 미량오염물질의 제거)

  • Wang, Chang-Keun;Cha, Joon-Chul;Lee, Yong-Hyun;Kim, Su-Dong;Liu, Ju-Whan
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.1
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    • pp.73-80
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    • 2004
  • This study investigated the phenomena of membrane fouling by NOM and the effect of the fouling on removal of micro-pollutants. NOM has a great effect on decline of permeate flux. Permeate flow rate was reduced by 88% in RO and 34.8% in NF for 323hr operation period. Removal rate of $UV_{254}$, is 87.4% in RO and 78.5% in NF and removal rate of DOC is 42.7% in RO and 32.9% in NF for 2mg/l humic acid. Removal efficiency of the micro-pollutants by the RO and NF membranes fouled by humic acid was mostly lower than that by the new membrane. The concentration polarization which affects the flux and the rejection was thought to occur in the active layer of the membrane, as the membrane was getting fouled.

A Study on Membrane Fouling Contaminants and Control in Enhanced Sewage Treatment by Submerged Membrane Bioreactor (침지형 분리막을 이용한 오수고도처리 공정의 막오염 원인물질 및 제어에 관한 연구)

  • Park, Chul-Hwi;Yun, Jae-Gon
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.5
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    • pp.619-627
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    • 2004
  • Purposes of this study were to examine closely the extracellular polymeric substances (EPS) which was a membrane fouling contaminant, to control detected EPS by powdered activated carbon (PAC) dosage etc. and to evaluate the possibility of practical reuse facility. With high removal efficiency of general pollutants, when the PAC is added to MBR, improvement of removal efficiency of $COD_{cr}$, and color was expected and treated wastewater can be reused. It was judged that the correlation between EPS and membrane fouling was very high. Carbohydrate and DNA in the EPS were judged to be cause of membrane fouling. If EPS could be controled, not only membrane fouling would be decreased but also operation time would be extended. In experiment of powdered activated carbon (PAC), characteristics of the best PAC for membrane fouling control were the particle size of $7{\mu}m$, lodine Number of 1,050, surface area of peat of $1,150m^2/g$. In lab test, operation time of MBR by PAC dosage of 200mg/gVSS was longer than one of MBR by without PAC dosage. Because EPS, especially carbohydrate and DNA, was controled successfully by PAC, membrane fouling in MBR could be decreased.

Antifouling Effect of an Ultrasonic System Operating at Different Frequencies (주파수 변동에 따른 초음파방오장비의 파울링제거효과)

  • Bae, Jin-Woo;Park, Guan-Sik;Ru, Myung-Lok;Park, Goun-Ha
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.5
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    • pp.609-616
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    • 2019
  • When the fouling of a vessel occurs, its resistance at sea increases and there is a corresponding increase in fuel consumption. The maintenance cost of the vessel also increases because it is time-consuming to remove the fouling. To solve this problem and minimize environmental contamination of sea-water, there have been recent developments in anti-fouling paints as self-polishing copolymers that not include toxic elements such as tin. When these conventional techniques are applied to vessels, polishing is promoted during the operation whereby friction or vibration with seawater occurs. This leads to enhanced anti-fouling performance. However, when fouling is intensified such as during an anchorage, there is no flow of seawater and polishing is suppressed. This leads to a deterioration of the performance of anti-fouling. To solve these problems, we developed a system that induces vibration in a vessel during anchorage. As such, the deterioration of polishing due to insuf icient flow of seawater is inhibited. The reliability of the ultrasonic antifouling system was evaluated by calculating its repeatability. The removal efficiency of fouling of the proposed system was qualitatively evaluated using test specimens. The test revealed that the value of the coefficient of variation for the reproducibility of the frequency and amplitude was 0.2 % and 4.0 % on average. The degree of fouling of the specimens was the highest at 73.3 g in the No.5 sepcimen. Moreover, efficiency of fouling removal was 93.2 % on average compared to the specimens without the proposed system.

Effect of Ozonation in Microfiltration Membrane for Wastewater Reuse (정밀여과법 하수재이용 공정에서 오존의 전처리 효과에 관한 연구)

  • Moon, Seong-Yong;Ahn, Se-Hyuk;Lee, Sang-Hyup;Park, Jong-Hoon;Hong, Suk-Won;Choi, Yong-Su
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.4
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    • pp.535-543
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    • 2006
  • The Ozone oxidation process was applied to increase the efficiency of reuse process when treating the secondary effluent by the membrane system. This paper focus on decreasing efficiency of membrane fouling, because of membrane fouling reduction by ozone and evaluation of application of the ozone oxidation. The feed water was secondary effluent from BNR process. The result shows that the ozone pretreatment can reduce membrane fouling effectively. Also, the improvement of treated water quality was obvious. The reduction of the membrane fouling led decrease of following pollutant and increase of lnner adsorptive ability of hydrophilic organic matter and decrease of molecular weight. MF membrane process alone can meet the domestic reuse water standards. And ozone pretreatment process also can increase the removal rates of turbidity, COD, nitrogen, and color.

Identification of Fouling Phenomena and Establishment for Optimized Removal Process of Alginic Acid Sodium Salt Through Capacitive Deionization (CDI 공정에서 Alginic Acid Sodium Salt의 파울링 현상 확인 및 제거 조건 확립)

  • Lee, Jin Yeon;Rhim, Ji Won
    • Membrane Journal
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    • v.30 no.5
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    • pp.342-349
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    • 2020
  • In this study, we suggest conditions to reduce fouling in capacitive deionization (CDI) caused by alginic acid sodium salt, one of the most common fouling-causing substances in natural water and wastewater management. First, NaCl is used as feed material, which is selected as the control of the experiment. As expected, fouling phenomena is not observed from NaCl. On the other hand, when alginic acid sodium salt is added to the inlet, the fouling phenomena can be observed. In order to minimize the fouling phenomena, the feed concentration of alginic acid sodium salt, applied potential during desorption process, and duration of applied potential to our CDI cell are controlled. With 7 mg/L of feed stream concentration, CDI performed using 1.2 V for 1 min during adsorption followed by desorption with -2 V for 1 min exhibited the highest alginic acid salt removal efficiency reaching 50.07%.

Comparison of physical cleaning applied to chemical backwashing of wastewater reuse membrane system (하수재이용 막여과 공정에서 약품 역세에서의 물리세정 영향 비교 평가)

  • Lee, Chang-Ha;Kim, Young-Hoon;Jeon, Min-Jung;Lee, Yong-Soo;Jang, Am;Kim Hyung-Soo
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.6
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    • pp.981-987
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    • 2011
  • Biologically treated water contains a large quantity of organic matters and microorganisms which can cause various problems to membrane. The membrane fouling occurred by these reasons is hard to control by single physical cleaning. This study analyzes the efficiency of aeration with chemical backwashing and foulants removal during chemical backwashing. The cleaning efficiency improves when the chemical concentration is high and the contact time of chemical is long. Chemical backwashing with aeration shows exceptional cleaning efficiency which leads the physical cleaning is required during chemical backwashing since it forms flow inside the membrane submerged tank. From the foulants removal analysis, the particles such as turbidity and TOC removal rate increase when the aeration is applied. Dissolved matter of DOC and UV254 removal is dependent on higher chemical concentration. According to FTIR analysis, one of major foulants, the polysaccharide is controlled by the chemical backwashing with aeration condition.

The Evaluation of Fouling Mechanism on Cross Flow Precoagulation-UF Process (십자형 응집-UF 막분리 공정 적용시 전처리 응집조건에 따른 막오염 메카니즘 규명)

  • Jung, Chul-Woo;Son, Hee-Jong
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.639-645
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    • 2008
  • The objectives of this research are to (1) observe changes in particle size distribution due to formation of microflocs during coagulation process (2) identify the membrane fouling potential on cross flow system (3) investigate the mechanism of membrane fouling. The rate of flux decline for the hydrophobic membrane was significantly greater than for the hydrophilic membrane, regardless of pretreatment conditions. The pretreatment of the raw water significantly reduced the fouling of the UF membrane. Also, the rate of flux decline for the hydrophobic membrane was considerably greater than for the hydrophilic membrane. Applying coagulation process before membrane filtration showed not only reducing membrane fouling, but also improving the removal of dissolved organic materials that might otherwise not be removed by the membrane. That is, during the mixing period, substantial changes in particle size distribution occurred under rapid and slow mixing condition due to the simultaneous formation of microflocs and NOM precipitates. Therefore, combined pretreatment using coagulation not only improved dissolved organics removal efficiency but also flux recovery efficiency.

Treatment of Textile Wastewater by Membrane-Bioreactor Process (막-생물반응조 공정을 이용한 염색폐수의 처리)

  • 강민수;김성수;황규대;강종림
    • Membrane Journal
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    • v.7 no.4
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    • pp.175-182
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    • 1997
  • Membrane-bioreactor process which combines anaerobic-aerobic bioreactor and membrane process, was used to remove refractory organic susbstances and dye molecule in textile wastewater effectively. Direct feeding of raw feed water to membrane process caused serious fouling on membrane. On the other hand, pretreated feed by bioreactor before the membrane process remarkably reduced the fouling and prolonged the membrane life. Removal efficiency and fouling were more dependent on the material property of the membrane rather than the membrane pore size and structure. Operation mode of hollow fiber membrane module and linear velocity in the hollow fiber influenced the ramoval efficiency and the water flux of the membrane. The combined membrane- bioreactor process was more effective in treating the textile wastewater than each single process.

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Experimental investigation of organic fouling mitigation in membrane filtration and removal by magnetic iron oxide particles

  • Jung, Jaehyun;Sibag, Mark;Shind, Bora;Cho, Jinwoo
    • Membrane and Water Treatment
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    • v.11 no.3
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    • pp.223-229
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    • 2020
  • Here magnetic iron oxide particles (MIOPs) were synthesized under atmospheric air and which size was controlled by regulating the flow rate of alkali addition and used for efficient removal of bovine serum albumin (BSA) from water. The MIOPs were characterized using field-emission scanning electron microscopy (FE-SEM), Fourier transformation-Infrared spectroscopy (FT-IR) and vibrating sample magnetometer (VSM). The results revealed a successful preparation of the MIOPs. The removal efficiency for BSA using MIOPs was found to be about 100% at lower concentrations (≥ 10 mg/L). The maximum adsorption of 64.7 mg/g for BSA was achieved as per the Langmuir adsorption model. In addition, microfiltration membrane for removal of BSA as model protein organic foulant is also studied. The effect of various MIOPs adsorbent sizes of 210, 680 and 1130 nm on the absorption capacity of BSA was investigated. Water permeability of the BSA integrated with the smallest size MIOPs membrane was increased by approximately 22% compared by the neat BSA membrane during dead-end filtration. Furthermore, the presence of small size MIOPs were also effective in increasing the permeate flux.