• Bulletin of the Korean Chemical Society
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• v.34 no.5
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• pp.1513-1520
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• 2013

Novel chitosan (CS) based membrane networks were developed by solution casting and followed by crosslinking with different crosslinkers such as glutaraldehyde, urea-formaldehyde, and thiourea-formaldehyde. The developed membrane networks were designated as CS-GA, CS-UF and CS-TF. Crosslinking reaction of CS membranes was confirmed by Fourier transform infrared spectroscopy. Membrane rigidity and compactness were studied by the differential scanning calorimetry. The surface morphology of CS membranes was characterized by scanning electron microscopy. The sorption behaviour with respect to contact time, initial pH and initial metal ion concentration were investigated. The maximum adsorption capacity of CS-GA, CS-UF and CS-TF sorbents was found to be 1.03, 1.2 and 1.18 mM/g for $Cu^{2+}$ and 1.48, 1.55 and 2.18 mM/g for $Ni^{2+}$ respectively. Swelling experiments have been performed on the membrane networks at $30^{\circ}C$. Desorption studies were performed in acid media and EDTA and it was found that the membranes are reusable for the metal ion removal for three cycles. The developed membranes could be successfully used for the separation of $Cu^{2+}$ and $Ni^{2+}$ metal ions from aqueous solutions.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.27 no.1
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• pp.27-35
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• 2014

In this study, an improved energy-based nonlinear static analysis method are proposed to be used for more accurate evaluation of progressive collapse potential of steel moment frames by reflecting the contribution of a double-span floor slab. To this end, the behavior of the double-span floor slab was first investigated by performing material and geometric nonlinear finite element analysis. A simplified energy-absorbed analytical model by idealizing the deformed shape of the double-span floor slab was developed. It is shown that the proposed model can easily be utilized for modeling the axial tensile force and strain energy response of the double-span floor slab under the column-removal scenario.

• Journal of Applied Reliability
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• v.12 no.1
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• pp.35-46
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• 2012

Wood pellet is one of biomass energy fuels, which is produced by compressing woody biomass such as sawdust, planer shavings, and whole-tree removal or tree tops and branches leftover after logging into cylindrical form. Latterly much attention has been paid to wood pellet boiler which is suitable for use at various scales in domestic and industrial furnaces for heat production to replace conventional fossil fuel energy sources since the use of wood pellet that is carbon neutral can alleviate global warming. This study presents the result of developing a high efficiency wood pellet boiler with 55MJ/h capacity. Efficiency has been improved by using a rotating disk burner with a shorter screw feeder. Special attention has been paid to the improvement of the safety of the wood pellet boiler from backfire by adopting a double protecting system composed of a shutter and an air curtain. The result shows that the efficiencies of the wood pellet boiler are 97.2% and 89.2% based on lower and higher heating values, respectively, at 15.1kW of heating output.

• Carbon letters
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• v.9 no.3
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• pp.181-187
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• 2008

Batch sorption experiments were carried out for the removal of metylene blue from its aqueous solution using $H_3PO_4$ activated Acacia arabica carbon (AAC). The prepared activated carbon was characterized and was found as an effective adsorbent material. The operating variables studied were initial metylene blue concentration, AAC concentration and solution pH. AAC activated carbon posses a maximum sorption capacity for the range of initial dye concentrations studied (60~100 mg $L^{-1}$). The sorption kinetics were analyzed using reversible first order kinetics, second order, reversible first order, pseudo-first order, and pseudo-second order model. The sorption data tend to fit very well in pseudo-second order model for the entire sorption time. The average pseudo-second order rate constant, $K_{II}$ and regression coefficient value were determined to be 0.0174 mg $g^{-1}$ $min^{-1}$ and 0.9977. The biosorption process also fit well to reversible I order kinetics with a regression coefficient of 0.9878.

• Carbon letters
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• v.9 no.1
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• pp.23-27
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• 2008

The adsorption and reduction of Cr (VI) to Cr (III) by surface modified activated carbon (AC) in an aqueous solution was studied. The effects of surface modifications on the properties of the carbons were investigated by the analysis of specific surface area, carbon surface pH, acid/base surface values and functional groups. In order to understand the Cr(VI) adsorption and reduction ratio from Cr(VI) to Cr(III), the Cr adsorption capacity of AC was also measured and discussed by using inductively coupled plasma and UV spectrophotometer. The modifications bring about substantial variation in the chemical properties whereas the physical properties such as specific surface area, pore volume and pore size distribution nearly were not changed. Total Cr adsorption efficiency of as-received activated carbon (R-AC) and nitric acid treated activated carbon (N1-AC and N2-AC) were recorded on 98.2, 99.7 and 100%. Cr(III) reduction efficiency of R-AC increased largely from 0.4% to 28.3% compared to N1-AC and N2-AC.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.60 no.2
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• pp.239-244
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• 2011

Due to large demand, the increase of fault current has caused the capacity of power machines in power grid to increase. Among several countermeasures, the superconducting fault current limiter (SFCL) has been noticed as one of the promising countermeasures to solve these problems. However, in spite of excellent current limiting performances of the SFCL, the application of SFCL to power system has been delayed due to both the limited space for the SFCL's installation and its longer recovery time after the fault removal. In order to solve these problems, a hybrid type SFCL was developed. In this paper, we studied the operation characteristics of the hybrid SFCL with first half cycle non-limiting operation by modelling using PSCAD/EMTDC and experiment. It was shown through the simulation using PSCAD/EMTDC and the simulated experiment that the fault current limiting and the fast recovery operations of the hybrid SFCL with the first half cycle non-limiting operation were achieved.

• Environmental Engineering Research
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• v.19 no.3
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• pp.205-214
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• 2014

Petroleum a vital commodity affecting every aspect of 21st century. Toxicity and adverse effects of sulphur as catalyst in petroleum products is of great concern required development of techniques for desulphurization in compliance with the International standards. Installation of desulphurizing units costs over $200 million per unit placing economic burden on developing countries like Pakistan. Present study analysis of commercial fuels (station petrol and jet fuel JP8) on gas chromatography-mass spectrometry (GC-MS) identified sulphur concentration of 19.94 mg/L and 21.75 mg/L, respectively. This scenario urged the researcher to attempt synthesis of material that is likely to offer good adsorption capacity for sulphur. Following protocol of sol-gel method, transition metals (Ni, Cu, Zn) solution is gelated with tetraethoxysilane (TEOS; silica precursor) using glycerol. Fourier transform infrared spectroscopy (FTIR) spectra revealed bonding of Zn-O, Cu-O, and Ni-O by stretching vibrations at $468cm^{-1}$, $617cm^{-1}$, and $468cm^{-1}$, respectively. Thiophene and Benzothiophene mixed in n-heptane and benzene (4:1) for preparation of Model Fuels I and II, respectively. Each of silica based metal was applied as adsorbent in batch mode to assess the removal efficiency. Results demonstrated optimal desulphurization of more than 90% following efficacy order as Si-Ni > Si-Zn > Si-Cu based adsorbents. Proposed multilayered (Freundlich) adsorption mechanism follows ${\pi}$-complexation with pseudo secnd order kinetics.

• Journal of Applied Biological Chemistry
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• v.43 no.1
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• pp.18-24
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• 2000

A one-dimensional transport of displacing monovalent ion, $A^+$, and a trivalent ion being displaced, $B^{3+}^ in a porous exchange system such as soil was approximated using the Crank-Nicolson implicit finite difference technique and the Thomas algorithm in tandem. The variations in the concentration profile were investigated by varying the ion-exchange equilibrium constant (k) of ion-exchange reactions, the influent concentrations, and the cation exchange capacity (CEC) of the exchanger, under constant flux condition of pore water and dispersion coefficient. A higher value of k resulted in a greater removal of the native ion, behind the sharper advancing front of displacing ion, while the magnitude of the penetration distance of $A^+$ was not great. As the CEC increased, the equivalent fraction of $B^{3+}^ initially in the soil was greater, thus indicating that a higher CEC adsorbed trivalent cations preferentially over monovalent ions. Mass balance error from simulation results was less than 1%, indicating this model accounted for instantaneous charge balance fairly well.

• Journal of the Korea Institute of Military Science and Technology
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• v.16 no.4
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• pp.560-565
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• 2013

Biological decontamination means the removal of microorganisms from the inanimate object such as building or equipment. In this study, hydrogen peroxide vapor efficacy test using VHP 1000ED system(Steris LifeSciences) were conducted for G. stearothermophilus spore with agent materials(aluminum, stainless steel, poly-carbonate, viton, silicone, kapton and glass). Total recovered spores exposed to hydrogen peroxide vapor(1.0 g/min) during 7, 15, 30, 60 min were calculated. As a result, all agent materials were totally decontaminated within 60 min at 1.0 g/min concentration with 35% hydrogen peroxide vapor. Finally, we could confirmed that hydrogen peroxide vapor possess sporicidal capacity of G. stearothermophilus and found the optimum decontamination conditions with VHP1000ED system.

• Smart Structures and Systems
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• v.7 no.5
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• pp.329-348
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• 2011

Large-scale earthquakes pose serious threats to infrastructure causing substantial damage and large residual deformations. Superelastic (SE) Shape-Memory-Alloys (SMAs) are unique alloys with the ability to undergo large deformations, but can recover its original shape upon stress removal. The purpose of this research is to exploit this characteristic of SMAs such that concrete Beam-Column Joints (BCJs) reinforced with SMA bars at the plastic hinge region experience reduced residual deformation at the end of earthquakes. Another objective is to evaluate the seismic performance of SMA Reinforced Concrete BCJs repaired with flowable Structural-Repair-Concrete (SRC). A $\frac{3}{4}$-scale BCJ reinforced with SMA rebars in the plastic-hinge zone was tested under reversed cyclic loading, and subsequently repaired and retested. The joint was selected from an RC building located in the seismic region of western Canada. It was designed and detailed according to the NBCC 2005 and CSA A23.3-04 recommendations. The behaviour under reversed cyclic loading of the original and repaired joints, their load-storey drift, and energy dissipation ability were compared. The results demonstrate that SMA-RC BCJs are able to recover nearly all of their post-yield deformation, requiring a minimum amount of repair, even after a large earthquake, proving to be smart structural elements. It was also shown that the use of SRC to repair damaged BCJs can restore its full capacity.