• Title/Summary/Keyword: Relaxation time constant

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Static Dielectric Constant and Relaxation Time for the Binary Mixture of Water, Ethanol, N. N-Dimethylformamide, Dimethylsulphoxide, and N, M-Dimethylacetamide with 20Hethoxyethanol

  • Ajay Chaudgari;N. M. More;S. C. Mehrotra
    • Bulletin of the Korean Chemical Society
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    • v.22 no.4
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    • pp.357-361
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    • 2001
  • Frequency spectra of the complex permittivity of 2-methoxyethanol (2-ME) with water, ethanol, dimethylsulphoxide (DMSO), N,N-dimethylformamide (DMF) and N,N-dimethylacatamide (DMA) have been determined over the frequency range of 10 MHz to 20 GHz at 25 $^{\circ}C$, using the Time domain reflectometry method, for 11 concentrations for each system. The static dielectric constant, dielectric constant at microwave frequency, relaxation time, excess dielectric parameters, and Kirkwood correlation factor have been determined. The relaxation in these systems within the frequency range can be described by a single relaxation time constant, using the Debye model. The parameters show a systematic change with the concentration.

Real- Time Estimation of the Ventricular Relaxation Time Constant

  • Chun Honggu;Kim Hee Chan;Sohn Daewon
    • Journal of Biomedical Engineering Research
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    • v.26 no.2
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    • pp.87-93
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    • 2005
  • A new method for real-time estimating left ventricular relaxation time constant (T) from the left ventricular (LV) pressure waveform, based on the isovolumic relaxation model, is proposed. The presented method uses a recursive least squares (RLS) algorithm to accomplish real-time estimation. A new criterion to detect the end-point of the isovolumic relaxation period (IRP) for the estimation of T is also introduced, which is based on the pattern analysis of mean square errors between the original and reconstructed pressure waveforms. We have verified the performance of the new method in over 4,600 beats obtained from 70 patients. The results demonstrate that the proposed method provides more stable and reliable estimation of τ than the conventional 'off-line' methods.

Rheological Properties of Mat-type Seedlings (Mat-묘(苗)의 리올러지 특성(特性))

  • Yi, C.K.;Huh, Y.K.
    • Journal of Biosystems Engineering
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    • v.14 no.1
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    • pp.8-15
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    • 1989
  • Agricultural materials do not react in a purely elastic manner, and their responses when subjected to stress and strain are appeared from a combination of elastic and viscous behavior. Various researchers have studied the mechanical and rheological properties of the many agricultural materials, but those properties are available mostly foreign varieties of agricultural products. Rheological properties of rice seedlings become important to formulate the principles governing their mechanical behavior. The objectives of this study were to experimentally determine the stress relaxation properties of rice seedlings such as three Japonica-type and one Indica ${\times}$ Japonica hybrid in the transplanting age. The results of this study are summarized as follows; 1. The stress relaxation behavior could be described by the generalized Maxwell model. 2. The phenomenon of stress relaxation happened abruptly just after loading and this phenomenon weakened with the loading time lapsed. 3. With increase of the initial stress, the stress relaxation intensity and residual stress increased, while the relaxation time was constant with increased, while the relaxation time was constant with increase of the level of initial stress. 4. With increase of loading rate, the stress relaxation intensity increased, while the relaxation time and residual stress decreased.

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Study of Dynamics of Allyl Chloride-2-Butanone Binary System Using Time Domain Reflectometry

  • Sudake, Y.S.;Kamble, S.P.;Patil, S.S.;Khirade, P.W.;Mehrotra, S.C.
    • Journal of the Korean Chemical Society
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    • v.56 no.1
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    • pp.20-27
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    • 2012
  • Complex permittivity spectra of Allyl Chloride (AC), 2-Butanone (2-BU) and their binary mixtures over the entire range of concentration were obtained using the Time Domain Reflectometry (TDR) technique in microwave frequency range at various temperatures. Static dielectric constant and relaxation time are obtained from complex permittivity spectra. Density ($\rho$) and refractive index ($n_D$) are also measured. These parameters are used to determine excess dielectric constant, excess inverse relaxation time, excess molar volume, excess molar refraction, polarity, Bruggeman factor and thermodynamic parameters viz. enthalpy of activation and entropy of activation. The values of static dielectric constant and relaxation time increases while density and refractive index decreases with the percentage of 2-Butanone in Allyl Chloride increases. Excess parameters were fitted to a Redlich-Kister equation.

A Study on Electrostatic Degradation Properties of Silicone Rubber due to Reinforcing Agent (보강제 변화에 따른 실리콘 고무의 정전기 열화 특성에 관한 연구)

  • Lee, Sung Ill
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.2
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    • pp.120-125
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    • 2015
  • In this study, we have come to the following conclusions regarding to the electrification properties (electrostatic electrification voltage and electrification relaxation time) of electrostatics in the three type of specimen (size: $4cm{\times}4cm{\times}0.103cm$) of silicone rubber which is mixed with the ATH (Aluminium Trihydrate(Al($OH_3$)) of 30 phr, 60 phr, 120 phr as reinforcing filler. The electrification properties of electrostatics were measured for the different mixing ratio of ATH with the applied voltage of DC 10 kV at the temperature range of $10^{\circ}C{\sim}30^{\circ}C$ and humidity range of 60%~80%. When the temperature remained constant, the electrical resistance decreased as the humidity increasing in the range of 60%, 70%, 80%. In contrast, when the humidity remained constant, the electrical resistance increased as the temperature increasing in the range of $10^{\circ}C$, $20^{\circ}C$, $30^{\circ}C$. Regarding these results, may be it is because the absorption of O-H molecule appeared in the silicone specimen. It was confirmed that when the temperature remained constant, the electrification relaxation time decreased as the humidity increased. In contrast, when the humidity remained constant, the electrification relaxation time increased as the temperature increased.

The Properties of Na-Ca Exchange Current in Single Atrial Cells of ,The Rabbit (토끼 단일 심방근 세포에서 Na-Ca 교환전류의 특성에 관한 연구)

  • Youm, Wook;Ho, Won-Kyung;Suh, Kyung-Phill
    • Journal of Chest Surgery
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    • v.22 no.4
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    • pp.548-561
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    • 1989
  • In single atrial cells isolated from the rabbit the properties of inward current of Na-Ca exchange were investigated using the whole cell voltage clamp technique. The current was recorded during repolarization following brief 2 ms depolarizing pulse to +40 mV from a holding potential of * 70 mV. Followings are the results obtained: 1. When stimulated every 30 seconds, the inward currents were activated and reached peak values 6-12 ms after the beginning of depolarizing pulse. The mean current amplitude was 342 pA/cell. 2. The current decayed spontaneously from the peak activation and the time course of the relaxation showed two different phases fast and slow phase. The time constants were 10-18 ms and 60-140 ms, respectively. 3. The recovery of inward current was tested by paired pulse of various intervals. The peak current recovered exponentially with time constant of 140 ms and 1 p M isoprenaline accelerated the recovery process. 4. Relaxation time course was also affected by pulse interval and time constant of the fast phase was reduced almost linearly according to the decrease of pulse interval between 30 sec and 1 sec. 5. The peak activation was increased in magnitude by long prepulse stimulation, 5 p M Bay K, 1 p M isoprenaline or internal and external application of c-AMP. 6. The relaxation time constant of the fast phase was prolonged by 5 p M Bay K or c-AMP, and shortened by isoprenaline. However the time course of the slow relaxation phase was not so much changed. From the above results, it could be concluded that increase of the calcium current by Bay K or c-AMP results in the potentiation and prolongation of intracellular calcium transient, and the facilitation of Ca uptake by SR might be a mechanism of shortening the time constant of current relaxation by short interval stimulation or isoprenaline.

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A Study on Development of Miniature Size Surface Charge Electrostatic Induction Motor (소형표면전하유도형 정전모터의 개발을 위한 연구)

  • 이동훈
    • Journal of Advanced Marine Engineering and Technology
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    • v.19 no.2
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    • pp.81-91
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    • 1995
  • A miniature size electrostatic induction motor has been fabricated and studied with emphasis on the role of the surface resistivity, the relative dielectric constant of the rotor surface materials and the rotor liner materials, which control the charge induction and relaxation on the rotor surface and the field intensity between the rotor and the stator. It is found that the higher resitivity and/or the higher relative dielectric constant, concurrently the longer relaxation time constant of the rotor surface materials make the motor speed get higher speed. In case of discrete coated rotor surface it is found that the motor speed was increased logarithmically as narrow as width of the discrete coated Ti. And the degree of width of discrete coated Ti to the axial direction of the rotor was $60^{\circ}$ and $150^{\circ}$, the motor has got a 125% higher than that at the degree of $0^{\circ}$.

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Stress dependent relaxation time in large deformation

  • Waluyo, Sugeng
    • Structural Engineering and Mechanics
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    • v.61 no.3
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    • pp.317-323
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    • 2017
  • This work presents a new strategy to model stress dependent relaxation process in large deformation. The strategy is relied on the fact that in some particular soft materials undergoing large deformation, e.g., elastomers, rubbers and soft tissues, the relaxation time depends strongly on stress levels. To simplify the viscoelastic model, we consider that the relaxation time is the function of previous elastic deviatoric stress state experienced by materials during loading. Using the General Maxwell Model (GMM), we simulate numerically conditions with the constant and the stress dependent relaxation time for uniaxial tension and compression loading. Hence, it can be shown that the proposed model herein not only can represent different relaxation time for different stress level but also maintain the capability of the GMM to model hysteresis phenomena.

A Study on High Temperature Creep and Stress Relaxation Properties of Zr-4 (Zr-4의 고온 크리프 및 응력이완 특성에 관한 연구)

  • Oh, Sea-Kyoo;Park, Chung-Bae;Han, Sang-Deok
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.28 no.1
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    • pp.71-78
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    • 1992
  • Zr-4 used for a cladding and an end plug of reactor component has creep deformation under operation at high temperature. Creep is regarded as the time dependent deformation of a material under constant applied stress. Although the major source of the deformation of zirconium component in water-cooled reactors is irradiation creep, the thermal creep may give a rise to significant deformation in reactor component especially at relatively high temperatures and at various constant stresses, and therefore it must be predicted accurately. Stress relaxation is the time dependent change of stress at constant strain and it is a process related intimately to creep. In this paper, the creep behavior and stress relaxation of Zr-4 is examined at the temperature of 50$0^{\circ}C$ that is 40% of the absolute melting temperature of Zr-4 under the stress below yield stress and under the various constant strains. The results obtained are summarized as follows: 1) With an increase of stress, the steady state creep rate increases and the creep rupture time decreases. 2) The steady state creep rate $\varepsilon$(%/s) for the stress $\sigma$sub(c) (kgf/mm super(2)) of Zr-4 increases outstandingly. All the empirical equations computed for Zr-4 increases outstandingly. All the empirical equations computed for Zr-4 are in accord with Norton's model equation($\varepsilon$=K$\sigma$ sub(c) super (n)). The constants of materials computed are as follows: K=3.9881$\times$10 super(-5), n=1.9608 3) The rupture time T sub(r) (hr) decreases linearly with the increase of stress on the log-log scaled graph. The empirical equations computed for Zr-4 are in accord with Bailey's model equation (T sub(r)=K sub(1)$\sigma$sub(c) super(m)). The constants of materials computed are as follows: K sub(1)=1.2875$\times$10 super(16), m=-3.467 4) It seems clear that the strain could be quantitatively dependent on the high temperature creep properties such as creep stress, rupture time, steady state creep rate and total creep rate. It is found that these relationships are linear on the log-log graph. 5) In stress relaxation test, as the critical constant strain that can be allowed to the specimen is larger, stress relaxation becomes more rapid, and as the constant strain is smaller, the stress relaxation becomes slower.

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Observation of Methyl Radical Recombination Following Photodissociation of CH3I at 266 nm by Time-Resolved Photothermal Spectroscopy

  • Suh, Myung-Koo;Sung, Woo-Kyung;Li, Guo-Sheng;Heo, Seong-Ung;Hwang, Hyun-Jin
    • Bulletin of the Korean Chemical Society
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    • v.24 no.3
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    • pp.318-324
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    • 2003
  • A time-resolved probe beam deflection (PBD) technique was employed to study the energy relaxation dynamics of photofragments produced by photodissociation of $CH_3I$ at 266 nm. Under 500 torr argon environment, experimental PBD transients revealed two energy relaxation processes; a fast relaxation process occurring within an acoustic transit time (less than 0.2 ㎲ in this study) and a slow relaxation process with the relaxation time in several tens of ㎲. The fast energy relaxation of which signal intensity depended linearly on the excitation laser power was assigned to translational-to-translational energy transfer from the photofragments to the medium. As for the slow process, the signal intensity depended on square of the excitation laser power, and the relaxation time decreased as the photofragment concentration increased. Based on experimental findings and reaction rate constants reported previously, the slow process was assigned to methyl radical recombination reaction. In order to determine the rate constant for methyl radical recombination reaction, a theoretical equation of the PBD transient for a radical recombination reaction was derived and used to fit the experimental results. By comparing the experimental PBD curves with the calculated ones, the rate constant for methyl recombination is determined to be $3.3({\pm}1.0)\;{\times}\;10^6\;s^{-1}torr^{-1}$ at 295 ± 2 K in 500 torr Ar.