• 제목/요약/키워드: Relaxation rate

검색결과 459건 처리시간 0.023초

An NMR Study of Unequal Site Exchange of 9-Methyl Group in Triptycene by Spin-Lattice Relaxation and 2D-EXSY Experiments

  • Cho, Jang-Geun;Ahn, Sang-Doo
    • 한국자기공명학회논문지
    • /
    • 제11권1호
    • /
    • pp.1-9
    • /
    • 2007
  • An unequal site exchanging system induced by restricted rotation of 9-methyl group in 1,8-dichloro-9-triptycene has been studied by spin-lattice relaxation and 2D-EXSY experiments. The exchange rate obtained from relaxation studies is very well coincident to the result of line shape analysis, and the difference of the relaxation times ($T_1$) in two different sites has an important role to analyze 2D-EXSY experimental data.

  • PDF

불면호소 환자에 대한 근수완훈련의 효과 (The Effect of Muscle Relaxation Training on the Patients with Insomnia Complaints)

  • 김대숙;이길자
    • 대한간호학회지
    • /
    • 제19권2호
    • /
    • pp.191-202
    • /
    • 1989
  • This study was peformed to examine the effect of muscle relaxation training on patients with insomnia complaint. The subjects were selected those who have taken poor sleep below 240-300 minutes. per day, between 16-15ages, without organic brain syndroms. Using the Budzinski's muscle relaxation training tapes the patients have been gotten the muscle relaxation training daily during four weeks and examined the state anxiety with Spielberger's Trait-State Anxiety Scale, and investigated Sleep amounts, Blood pressure, Pulse rates, Respiratory rates before and after the muscle relaxation training. The results were as follow : 1. The mean of the State anxiety after the muscle relaxation training(41.8$\pm$6.4) was significantly lower than that of before training (54.2$\pm$7.0) (p<0.001). 2. The mean of systolic blood pressure after the training (114.$\pm$7.8mmHg) was significantly lower than that of before training (139.0$\pm$9.8) (P<0.001). 3. The mean of Pulse rate after the traing (89.2$\pm$3.0) was significantly lower than that of before training (103.9$\pm$7.4) (P<0.001). 4. The mean of Respiratory rate after the training(18.6$\pm$1.0) was significantly lower than that of before training(22.8$\pm$1.3) (P<0.001). 5. The mean of Sleep amount after the muscle relaxation training (459.8$\pm$52.4 minutes) was significantly increased than that of before training (287.3$\pm$30.3) (P<0.001).

  • PDF

ACCELERATION OF ONE-PARAMETER RELAXATION METHODS FOR SINGULAR SADDLE POINT PROBLEMS

  • Yun, Jae Heon
    • 대한수학회지
    • /
    • 제53권3호
    • /
    • pp.691-707
    • /
    • 2016
  • In this paper, we first introduce two one-parameter relaxation (OPR) iterative methods for solving singular saddle point problems whose semi-convergence rate can be accelerated by using scaled preconditioners. Next we present formulas for finding their optimal parameters which yield the best semi-convergence rate. Lastly, numerical experiments are provided to examine the efficiency of the OPR methods with scaled preconditioners by comparing their performance with the parameterized Uzawa method with optimal parameters.

점진적(漸進的) 근육이완법(筋肉弛緩法)이 자율신경계(自律神經系)에 미치는 영향(影響) (The Effect of Progressive Muscle Relaxation Therapy on Autonomic Nerve System)

  • 이재혁;이제균
    • 동의신경정신과학회지
    • /
    • 제18권1호
    • /
    • pp.111-122
    • /
    • 2007
  • Objective : Progressive muscle relaxation(PMR) therapy is the way of mind and body self-regulation which makes major muscles tension to be comfortable condition. It was considered to be important to check the level of relaxation in objective validity. Therefore, Heart rate variability(HRV) is the valuable measurement to investigate the effect of progressive muscle relaxation therapy on autonomic nerve system. Method : I studied 38 subjects. The subjects were measured HRV at first. And then, Using a CD player, the subjects listened to recorded PMR program for 15 minutes. After this progress, I rechecked HRV. Results : heart rate item of HRV was significantly decreased. Also, the numerical value of SDNN(standard deviation of all NN intervals) and SDSD(standard deviation of differences between adjacent NN intervals) items of HRV were showed significantly increased in all subjects after PMR. Conclusion : It indicated that PMR is efficient for inspiring resistance of the stress and a sense of stability, and PMR is a valuable method to reduce the mind stress and stiffness of body muscle.

  • PDF

Mat-묘(苗)의 리올러지 특성(特性) (Rheological Properties of Mat-type Seedlings)

  • 이정기;허윤근
    • Journal of Biosystems Engineering
    • /
    • 제14권1호
    • /
    • pp.8-15
    • /
    • 1989
  • Agricultural materials do not react in a purely elastic manner, and their responses when subjected to stress and strain are appeared from a combination of elastic and viscous behavior. Various researchers have studied the mechanical and rheological properties of the many agricultural materials, but those properties are available mostly foreign varieties of agricultural products. Rheological properties of rice seedlings become important to formulate the principles governing their mechanical behavior. The objectives of this study were to experimentally determine the stress relaxation properties of rice seedlings such as three Japonica-type and one Indica ${\times}$ Japonica hybrid in the transplanting age. The results of this study are summarized as follows; 1. The stress relaxation behavior could be described by the generalized Maxwell model. 2. The phenomenon of stress relaxation happened abruptly just after loading and this phenomenon weakened with the loading time lapsed. 3. With increase of the initial stress, the stress relaxation intensity and residual stress increased, while the relaxation time was constant with increased, while the relaxation time was constant with increase of the level of initial stress. 4. With increase of loading rate, the stress relaxation intensity increased, while the relaxation time and residual stress decreased.

  • PDF

벼의 리올러지 특성(特性)(I) -곡립(穀粒)의 응력이완(應力弛緩)- (Rheological Properties of Rough Rice(I) -Stress Relaxation of Rough Rice Kernel-)

  • 김만수;김성래;박종민
    • Journal of Biosystems Engineering
    • /
    • 제15권3호
    • /
    • pp.207-218
    • /
    • 1990
  • Grains display characteristics of both elastic bodies and viscous fluids when they are subjected to mechanical treatments in harvesting, handling, and processing. This viscoelastic behavior of grains when mechanically stressed must be fully understood to establish maximum machine efficiency and have a minimum degree of grain damage and the highest quality of the final product. The studies were conducted to examine the effect of the moisture content, the loading rate and the initial deformation on the stress relaxation behavior of whole kernel of rough rice, and develop the rheological model to represent its stress relaxation behavior. The following results were obtained from the study. 1. Moisture content had the greatest influence on the initial portion of the relaxation curve. With elapsing time the lower moisture content resulted in the lower residual stress for the Japonica-type rough rice and vice versa for the Indica-type rough rice. But within the ranges of moisture content tested, the degree of stress relaxation per unit strain on the Indica-type rough rice was a little higher than those on the Japonica-type rough rice. 2. The slower loading rate resulted in less initial stress. The decreasing trend of residual stress for all the samples tested with increasing loading rate was shown. 3. The higher initial deformation for all the samples resulted in less initial stress. The increasing of amount of stress relaxation per unit strain with increase of initial stress indicated that viscoelastic properties of rough rice depended not only upon duration of load applied but also initial stress applied. This means that rough rice is nonlinear viscoelastic material. 4. The compression stress relaxation properties of rough rice kernel can be described by a generalized Maxwell model representing by the Maxwell elements.

  • PDF

Observation of Methyl Radical Recombination Following Photodissociation of CH3I at 266 nm by Time-Resolved Photothermal Spectroscopy

  • Suh, Myung-Koo;Sung, Woo-Kyung;Li, Guo-Sheng;Heo, Seong-Ung;Hwang, Hyun-Jin
    • Bulletin of the Korean Chemical Society
    • /
    • 제24권3호
    • /
    • pp.318-324
    • /
    • 2003
  • A time-resolved probe beam deflection (PBD) technique was employed to study the energy relaxation dynamics of photofragments produced by photodissociation of $CH_3I$ at 266 nm. Under 500 torr argon environment, experimental PBD transients revealed two energy relaxation processes; a fast relaxation process occurring within an acoustic transit time (less than 0.2 ㎲ in this study) and a slow relaxation process with the relaxation time in several tens of ㎲. The fast energy relaxation of which signal intensity depended linearly on the excitation laser power was assigned to translational-to-translational energy transfer from the photofragments to the medium. As for the slow process, the signal intensity depended on square of the excitation laser power, and the relaxation time decreased as the photofragment concentration increased. Based on experimental findings and reaction rate constants reported previously, the slow process was assigned to methyl radical recombination reaction. In order to determine the rate constant for methyl radical recombination reaction, a theoretical equation of the PBD transient for a radical recombination reaction was derived and used to fit the experimental results. By comparing the experimental PBD curves with the calculated ones, the rate constant for methyl recombination is determined to be $3.3({\pm}1.0)\;{\times}\;10^6\;s^{-1}torr^{-1}$ at 295 ± 2 K in 500 torr Ar.

측방향하중(側方向荷重)에 의한 벼줄기의 역학적특성(力學的特性)에 관한 연구(I) -이완거동 분석- (Study on the Mechanical Properties of the Rice Plants Subjected to Radial Load -Analysis of Relaxation Behavior-)

  • 허윤근
    • Journal of Biosystems Engineering
    • /
    • 제18권4호
    • /
    • pp.402-409
    • /
    • 1993
  • During all mechanical processes rice plants are subjected to verious forces such as natural load of wind and mechanical load of agricultural machines. A force is always accompanied by deformation, which must be either sufficiently great for pressing or sufficiently slight in order to avoid damage. The mechanical behavior of the rice plants is determined by three variables : force, deformation and time. And they must be studied using rheological methods to determine their viscoelastic properties. This study is conducted to experimentally determine the mechanical and rheological properties of the rice stalks subjected to radial load. The force relaxation tests are performed under constant deformation, during which the reduction of forces over time is measured. The mechanical models were developed from the abtained data. The results were as follows : 1. The relaxation behavior of a rice stalk in radial compession may be described by a generalized Maxwell model consisting of 3 Maxwell elements in parallel. 2. Relaxatiom intensity always decreased with increased time of relaxation. 3. The rate of deformation has a significant effect on the relaxation behavior. having increasing pattern with an increase in rate of deformation. 4. The relaxation intensity and residual deformation increased with increased initial load. 5. The relaxtion of the intermediate portion of stalk was bigger tham that of the upper and lower portions.

  • PDF

자연점토의 변형률속도 의존적인 압밀거동의 해석 (Modeling Strain Rate-dependent Behavior in Consolidation of Natural Clay)

  • 김윤태
    • 한국지반공학회논문집
    • /
    • 제15권6호
    • /
    • pp.17-28
    • /
    • 1999
  • 본 연구에서는 자연점토의 압밀에 대한 변형률속도의 영향을 해석하기 위하여 비선형 점탄소성 모델을 제안하였다. 연약지반의 점소성 거동은 유일한 유효응력-변형률-변형률속도 (equation omitted)의 관계식으로부터 구할 수 있다. Berthierville 점토에 대한 크리프실험, 다단계 하중실험, Relaxation실험과 같은 실내실험결과와 수치해석결과를 비교하였다. 제안된 점탄소성 모델을 사용하여 자연점토의 압밀거동을 비교적 정확히 예측할 수 있다.

  • PDF

Collision-Induced Electronic Relaxation of Thiophosgene (S₁)

  • 김택수;Choi, Young S.
    • Bulletin of the Korean Chemical Society
    • /
    • 제17권8호
    • /
    • pp.745-749
    • /
    • 1996
  • Fluorescence from the electronically excited thiophosgene (Cl2CS) in its first excited singlet state (S1) is efficiently quenched by collision. Rates of the collision-induced electronic relaxation were obtained for various vibrational levels in the S1 state by measuring the fluorescence lifetimes. We found that the relaxation process is strongly energy-dependent; the rate consistently increases by a factor of ~40 with the increase of vibrational energy from 0 to 1450 cm-1. Collision-induced intersystem crossing from the S1 to the first triplet state (T1) is attributed to the major process responsible for the electronic relaxation.