• Title/Summary/Keyword: Relative stability

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High Temperature Thermodynamics of Aqueous electrolyte Solutions (전해질 수용액의 고온 열역학)

  • Lee, Man Seung
    • Resources Recycling
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    • v.27 no.2
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    • pp.63-67
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    • 2018
  • Gibbs free energy is a measure of relative stability among substances. Since the nature of the ions in aqueous solution is diverse, their thermodynamic data at extensive experimental conditions is scarce. In this work, the calculation procedure was introduced to obtain the absolute and conventional standard molar enthalpies and entropies of hydration of ions from the standard enthalpies and entropies of formation of hydrated ions. The application of correspondence principle to estimate thermodynamic data at high temperature was explained.

Robust Control for SISO Nonlinear System using VSS Theory (VSS 이론을 이용한 SISO 비선형 시스템에 대한 강인성 제어)

  • Im, Kyu-Mann;Kim, Young-Soo
    • Proceedings of the KIEE Conference
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    • 1998.11b
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    • pp.523-525
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    • 1998
  • In this paper, a robust control scheme for a class of SISO nonlinear dynamical system is proposed by using output-feedback linearization method. The presented control scheme is based on the VSS control theory concept. In this control scheme, we assume that the nonlinear dynamical system is minimum phase, i.e., the relative degree of the system is r < n and zero dynamics is stable. We also assume that the states of zero dynamics are not accessible. It is shown that the global asymptotically stability is guaranted under the proposed control scheme. The feasibility of the proposed control scheme is verified through a computer simulation.

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Structures and Spectroscopic Properties of Dicyanoacetylene and Isomers: Density Functional Theory Study (디시아노아세틸렌 및 그 이성체들의 분광학적 성질에 대한 이론 연구)

  • Jeon, In-Sun;Park, Sung-Woo;Lee, Sung-Yul
    • Journal of the Korean Chemical Society
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    • v.48 no.6
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    • pp.568-576
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    • 2004
  • Density functional theory calculations are presented for dicyanoacetylene $N{\equiv}C-C{\equiv}C-C{\equiv}N$ and its geometrical isomers. The structures and harmonic frequencies are computed by the BLYP theory employing the 6-311G^{\ast}$ basis set. A variety of isomers are predicted, and the relative energies are compared to estimate their thermodynamic stability.

The credit market of Russia: the assessment of condition, the development of tendency

  • Vyborova, E.N.
    • East Asian Journal of Business Economics (EAJBE)
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    • v.5 no.2
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    • pp.12-37
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    • 2017
  • The analysis of results of the market of loans granted to legal entities, the physical persons are provided in the work. The assessment of condition of industry segments of the market of the credits of legal entities is carried. The results of assessment of the market of the credits of physical persons by types of the granted loans are provided. The correlation and regression analysis on the industry segments of crediting of legal entities is carried out. The dynamics of development of debt on the industry segments of crediting is determined. The results show that: Hypothesis 1. The amount of the issued credits to the legal entities steadily in-creases on all industries of economy. Communication between the industry segments of market very high. Hypothesis 2. Crediting of physical persons is characterized by relative stability. The structure of overdue debt repeats the structure of the issued credits to the physical persons.

Effects of Natural Independent Visual Background for Reducing Simulator Sickness (자연형 IVB(Independent Visual Background)의 Simulator Sickness 감소효과)

  • 김도회;임정위
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.25 no.3
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    • pp.28-33
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    • 2002
  • Several studies indicated that an independent visual background (IVB) reduced simulator sickness (SS) and balance disturbance associated with exposure to virtual environments (VEs) and motion simulators. A recent study showed that an IVB comprised of an earth-fixed grid was less effective in a complex driving simulator than in a simple VE. Subjects' post-experiment reports indicated that the VE motion "induced" motion of the earth-fixed grid m. This led to the suggestion that an IVB comprised of clouds would be less subject to induced motion and therefore would alleviate nausea more effectively than a grid IVB. Clouds are "natural" and are usually perceived as relatively stable, whereas a grid has no inherent stability. 12 subjects were exposed to complex motion through a simulated environment in a driving simulator under 3 IVB conditions: grid, less clouds, many clouds. They reported less nausea when the many-cloud IVB was used relative to the grid IVB condition. grid IVB condition.

Relationships between the measures of GPS positioning error (GPS 위치결정 오차의 평가척도 사이의 관계)

  • Park, Chan-Sik;Kim, Il-Sun;Lee, Jang-Gyu;Jee, Gyu-In
    • Journal of Institute of Control, Robotics and Systems
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    • v.4 no.2
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    • pp.220-225
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    • 1998
  • In GPS (Global Positioning System) positioning, various measures can be used to select satellites or to evaluate the positioning results. Among these, GDOP (Geometric Dilution of Precision) and RGDOP (Relative GDOP) are the most frequently used. Although these measures are frequently used, the relationship between them is not clearly known. Moreover, the condition number is used as a traditional measure of numerical stability in solving linear equations. Sometimes, the volume of a tetrahedon made by the line of sight vector is used for simplicity. All of these measures share some common properties as well as differences. The relationships between these measures are analyzed in this paper.

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A Formation Guidance Law Design Based on Relative-Range Information for Swam Flight (군집비행을 위한 상대 거리정보 기반의 편대 유도기법 설계)

  • Kim, Sung-Hwan;Jo, Sung-Beom;Park, Sang-Hyuk;Kim, Do-Wan;Ryoo, Chang-Kyung
    • Journal of Institute of Control, Robotics and Systems
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    • v.18 no.2
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    • pp.87-93
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    • 2012
  • In this paper, a formation guidance method for UAVs (Unmanned Aerial Vehicles) to simulate the formation flight of birds proposed. The proposed method solves all issues of approaching for formation, formation keeping, and scarce chance to be collided with each UAV during formation process. Also, we design the feedforward controller to compensate the change of speed and heading for maneuvering of the leader UAV and the feedback controller to consider the response lag of the system. The stability and performance of the proposed controller is verified via numerical simulations of the full 6-Dof model of UAV.

MO Studies of Configurations and Conformations (Ⅶ). Composite ${\pi}$ Structure Analysis of Nonbonded Interactions (配置와 形態에 關한 分子軌道論的 硏究 (濟7報). 非結合相互作用의 複合파이構造 分析)

  • Ikchoon Lee;Bon-Su Lee
    • Journal of the Korean Chemical Society
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    • v.24 no.2
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    • pp.101-107
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    • 1980
  • Composite ${\pi}$-structure analysis has been proposed for predicting relative isomer stabilities based on nonbonded effects: all the possible crowded ${\pi}$-structures are identified for each isomer, and the systems are represented by abbreviated notation of $(n{\pi}/m)$ : then using simple rules and additivity of the nonbonded effects, the order of stability can be determined. A number of examples are given in support of this analytical procedure.

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Quantitative Separation of Some Transition Metals by Cation Exchange Chromatography (陽이온 交換크로마토그라피에 의한 轉移元素의 分離)

  • Kim, Tong-Yup;Cha, Ki-Won;Park, Kee-Chae
    • Journal of the Korean Chemical Society
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    • v.8 no.2
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    • pp.62-64
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    • 1964
  • The cation exchange chromatographic studies for the analysis of transition metals have been described. The quantitative separation of a mixture of Fe(Ⅲ), Cu(II), Zn(II), Ni(II), Cd(II), Co(II) and Mn(II) has been obtained by elution, through a 28cm column of the resin, Dowex 50 ${\times}$ 4 (100∼200 mesh), using 0.45 M $NaNO_3$+0.05 M Na-tartrate solution as eluent, starting with the eluent of pH 3.5, followed stepwise by pH 4.0 and 4.5. A comparison between the calculated and the observed peak positions in the elution curve has been shown. The relative stability constants for tartrate complexes of some transition metals have been calculated by using distribution ratios obtained in this separation procedure.

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Buckling analysis of partially embedded pile in elastic soil using differential transform method

  • Catal, Seval;Catal, Hikmet Huseyin
    • Structural Engineering and Mechanics
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    • v.24 no.2
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    • pp.247-268
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    • 2006
  • The parts of pile, above the soil and embedded in the soil are called the first region and second region, respectively. The forth order differential equations of both region for critical buckling load of partially embedded pile with shear deformation are obtained using the small-displacement theory and Winkler hypothesis. It is assumed that the behavior of material of the pile is linear-elastic and that axial force along the pile length and modulus of subgrade reaction for the second region to be constant. Shear effect is included in the differential equations by considering shear deformation in the second derivative of the elastic curve function. Critical buckling loads of the pile are calculated for by differential transform method (DTM) and analytical method, results are given in tables and variation of critical buckling loads corresponding to relative stiffness of the pile are presented in graphs.