• 제목/요약/키워드: Relative stability

검색결과 914건 처리시간 0.031초

Novel Imidazolium Ionic Liquids Containing Quaternary Ammonium Iodide or Secondary Amine for Dye-sensitized Solar Cell

  • Seo, Dong-Wan;Lim, Young-Don;Lee, Soon-Ho;Ur, Soon-Chul;Kim, Whan-Gi
    • Bulletin of the Korean Chemical Society
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    • 제32권8호
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    • pp.2633-2636
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    • 2011
  • A new type of ionic liquid based on N-(3-aminepropyl)imidazolium iodide, called IIQAI, which consists of imidazolium and quaternary ammonium salt, and APII-(hydroxyethyl, propyl, hexyl) were synthesized and used as ionic liquid in dye-sensitized solar cells. APII-hexyl is solid, whereas IIQAI, APII-(hydroxyethyl, propyl) are viscous liquids. The synthesized ionic liquid showed relative thermal stability compared to the commercial ionic liquid of DMII. Among them, IIQAI was more stable than the other ionic liquid because of the two salt groups. APII-hydroxyethyl, which contains two hydroxyl groups, showed low viscosity with good flow. New types of ionic liquids were examined by $^1H$-NMR spectroscopy, thermo gravimetric analysis (TGA). IIQAI enabled a solar energy conversion efficiency of 6.3%, which is slightly higher than that of the referenced (DMII, 6.2%).

감마선 조사에 보리의 저장 안전성 (Storge Stability of Barleys Irradiated by Gamma-Ray)

  • 김미라;손인숙
    • 한국식품영양과학회지
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    • 제28권5호
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    • pp.1076-1081
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    • 1999
  • Physicochemical, microbiological, and sensory properties of barleys irradiated by gamma ray at 1.2kGy, 10.1kGy, or 30.5kGy were investigated every 40 days during the storage at 25℃ and 50% relative humidity. Moisture content of the irradiated barleys decreased but crude lipid content increased during the storage. TBA values increased in proportion to the irradiation dose and to the storage period. In Hunter's color, L, a, and b values of 30.5kGy dose irradiated barleys were higher than those of the non irradiated barleys right after irradiation and this trend continued during the storage. Numbers of mesophilic and psychrophilic bacteria in the non irradiated barleys and 1.2kGy dose irradiated barleys were higher than those in the barleys irradiated at 10.1kGy and 30.5kGy during the storage. Numbers of yeasts and molds in the irradiated and non irradiated barleys were low and they did not greatly increase during the storage. In sensory evaluation, acidic odor of the barleys was strong at the 10.1kGy and 30.5 kGy dose irradiation but barley odor and humid odor were not significantly different among the groups depending upon the radiation dose and storage period.

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Field Emission Stability of Carbon Nanotubes Grown by Thermal Chemical Vapor Deposition

  • Kim, B.K.;Kong, B.Y.;Seon, J.Y.;Lee, N.S.;Kim, H.J.;Han, I.T.;Choi, J.H.;Jung, J.E.;Kim, J.M.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.863-866
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    • 2003
  • Multi-walled carbon nanotubes (CNTs) were synthesized on glass substrates in the different ramp-up heating ambient of vacuum, He, Ar, and $N_{2}$ by thermal chemical vapor deposition. CNTs with higher crystallinity were developed in the buffer gases with faster growth rates than in vacuum. Field emission characteristics were strongly related to the relative position of CNT emitters to the cathode electrodes. The areal-spread emission and instability were overcome by locating the emitters far away from the edges of cathode electrodes. The electrical conditioning of emitters improved their emission uniformity over a large area although it decreased the emission current. This study also discussed the long-term stability of CNT emitters.

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외란관측기를 이용한 볼스크류 구동 2축 서보계의 최적튜닝 (Optimal Tuning of a Ballscrew Driven Biaxial Servo System)

  • 신동수;정성종
    • 한국생산제조학회지
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    • 제20권5호
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    • pp.589-597
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    • 2011
  • In this paper, optimal tuning of a cross-coupled controller linked with the feedforward controller and the disturbance observer is studied to improve contouring and tracking accuracy as well as robustness against disturbance. Previously developed integrated design and optimal tuning methods are applied for developing the robust tuning method. Strict mathematical modeling of the multivariable system is formulated as a state-space equation. Identification processes of the servomechanism are conducted for mechanical servo models. An optimal tuning problem to minimize both the contour error and settling time is formulated as a nonlinear constrained optimization problem including the relevant controller parameters of the servo control system. Constraints such as relative stability, robust stability and overshoot, etc. are considered for the optimization. To verify the effectiveness of the proposed optimal tuning procedure, linear and circular motion experiments are performed on the xy-table. Experimental results confirm the control performance and robustness despite the variation of parameters of the mechanical subsystems.

Effects of Light on Disassembly of Chloroplast during Senescence of Detached Leaves in Phaseolus vulgaris

  • Lee Dong-Hee;Hong Jung-Hee;Kim Young-Sang
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • 제1권2호
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    • pp.69-80
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    • 1997
  • Effects of light on leaf senescence of Phaseolus vulgaris were investigated by measuring the disassembly of chlorophyll-protein complexes in detached leaves which had been kept in the dark or under light. The loss of chlorophyll accompanied by degradation of chlorophyll-protein complexes. PSI (photosystem I) complex containing LHCI (light harvesting complex of PSI) apoproteins was rapidly decreased after the early stage of dark-induced senescence. RC(reaction center)-Core3 was slightly increased until 4 d and slowly decreased thereafter. As disassembly of LHCII trimer progressed after the late stage of senescence, there was a steady increase in the relative amount of SC(small complex)-2 containing LHCII monomer. On the other hand, white and red light adaptation caused the structural stability of chlorophyll-protein complexes during dark-induced senescence. Particularly, red light was more effective in the retardation of LHCII breakdown than white light, whereas white light was slightly effect in protecting the disassembly of PSI complex compared to red light. These results suggest, therefore, that light may be a regulatory factor for stability of chlorophyll-protein complexes in the senescent leaves.

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Protein Cyclization Enhanced Thermostability and Exopeptidase-Resistance of Green Fluorescent Protein

  • Zhao, Zhonglin;Ma, Xin;Li, Liang;Zhang, Wei;Ping, Shuzhen;Xu, Ming-Qun;Lin, Min
    • Journal of Microbiology and Biotechnology
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    • 제20권3호
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    • pp.460-466
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    • 2010
  • A mutant of green fluorescent protein ($GFPmut3^*$) from the jellyfish Aequorea victoria was cyclized in vitro and in vivo by the use of a naturally split intein from the dnaE gene of Synechocystis species PCC6803 (Ssp). Cyclization of $GFPmut3^*$ was confirmed by amino acid sequencing and resulted in an increased electrophoretic mobility compared with the linear $GFPmut3^*$. The circular $GFPmut3^*$ was $5^{\circ}C$ more thermostable than the linear form and significantly more resistant to proteolysis of exopeptidase. The circular $GFPmut3^*$ also displayed increased relative fluorescence intensity. In addition, chemical stability of $GFPmut3^*$ against GdnHCl revealed more stability of the circular form compared with the linear form.

우리나라에 도입된 스트로브잣나무의 산지-시험지간 상호작용 (Interaction Between Provenance and Site of Eastern White Pine (Pinus strobus) Imported into Korea)

  • 최형순;유근옥;현정오;김인식;조도현
    • 한국농림기상학회지
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    • 제13권4호
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    • pp.185-191
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    • 2011
  • This study was conducted to investigate growth performance and provenance by site interaction in Pinus strobus (Eastern White Pine) provenance tests for selecting superior provenances in Korea. P. strobus was planted in 1972 at four test sites in Korea and the growth was analyzed at age 39. The growth of P. strobus was positively correlated with relative humidity and precipitation and negatively correlated with temperature of the test sites. The portion of interaction term of the total variation explained 2.5% in height and 24.6% in diameter of the total variation according to the regression analysis. The method of combined stability and performance index (CSPi) ranked the North Carolina provenance as the best provenance with good adaptability.

Magnetization Behavior of Ultra-thin FexCo1-x Alloy on Cr (100) Surface

  • Hossain, M.B.;Kim, C.G.;Chun, B.S.;Kim, W.;Hwang, C.Y.
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2013년도 임시총회 및 하계학술연구발표회
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    • pp.15-16
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    • 2013
  • Magnetization behavior of ultra thin $Fe_xCo_{1-x}$ alloy (where x varies from 0 to 100) has been investigated as functions of composition on Cr (100) substrate by using in situ surface magneto optical Kerr effect (SMOKE). It's always show in plane uniaxial magnetic anisotropy at room temperature (RT) & Low temperature (LT). It is observed that composition dependent coercive force maximum at about 30 at % Co and 70 at % Co atomic ratio and minimum near equiatomic site. The relative magnetic moments as composition variation also show magnetization collapse near equiatomic site. The magnetization behaviors of Fe-Co alloy on Cr (100) due to composition varies are supported the order-disordering as well as structural stability bcc (ferromagnetic)/fcc (anti-ferromagnetic) phase stability magnetism.

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Immobilized Saccharomyces cerevisia의 반응특성에 관한 연구 (Studies on the Reactive Characteristics of Immobilized Saccharomyces cerevisia in Ethanol Production)

  • 김성기
    • 한국환경보건학회지
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    • 제18권1호
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    • pp.84-94
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    • 1992
  • In an attempt to develop the immobilized biocatalysts based on immobilized Saccharomyces cerevisiae, immobilized yeast was investigated with respect to the conditions affected to ethanol productivities. Saccharomyces cerevisiae was immobilized in the form of the beads by magnetic-calcium alginate, non magnetic-calcium alginate and acrylamide polymerization. Magnetic immobilized yeast, nonmagnetic immobilized yeast and polyacrylamide immobilized yeast were compared in respect of their pH stability, thermostability, heat tolerance, the relation between the concetration of native yeast and retained activity of immobilized yeast, the activity depending on bead size of immobilized yeast, and the effects of magnesium and cobalt on the activities. The more small bead had retained the higher activity for the three kinds of immobilized yeast. In case of 1.0mm diameter of beads, the retained activity was 40~50% for the all groups. The pH stability profile for the immobilized yeast showed a broad range of optimun activity while the native yeast gave a sharp pick for its optimun pH value. The thermostability was at the range of 25~55$^{\circ}$C for the immobilized yeast groups. It was investigated that the influent magnesium and cobalt concentration, and the relative activity have an influent on heat tolerance at steady state. Both protein content released from immobilized yeast and activity of immobilized yeast were changed after activation of immobilized yeast cell.

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함수특성곡선을 고려한 불포화토 사면의 안정성 연구 (A study on the Stability Analysis of Slope in Unsaturated Soil Based on the Soil-Water characteristic curve)

  • 윤민기;김종성;김효중;이영생
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2008년도 추계 학술발표회
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    • pp.1029-1037
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    • 2008
  • The finite element analysis of transient water flow through unsaturated soils was used to investigate effects of hydraulic characteristics, initial relative degree of saturation, methods to consider boundary condition, and rainfall intensity and duration on water pressure in slopes. The finite element method with shear strength reduction technique was used to evaluate the stability of slopes under rainfall. The slope-related disasters in Korea usually occur between July and September during the typhoon and localized heavy rain. This means that the rainfall is the most important factor that leads to the slope-related disasters. The slope-related disasters can happen at very short time and lead to big damage. To forecast the change of the heave of the groundwater in slope the Seep/w program was used.

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