• Title/Summary/Keyword: Relative permeability

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Characterization of Ferrallitique Soils (Ferrallitique토양(土壤)의 특성(特性)에 관(關)한 연구(硏究))

  • Sin, Cheon-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.3
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    • pp.260-264
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    • 1985
  • Ferrallitique soils are real tropical soils, with an oxic B horizon such a horizon is at least 30cm thick, has > 15% clay, diffuse horizon boundaries, no weatherable minerals and a CEC of clay < 16 me per 100g. These soils are in general the real reddish or yellowish very uniform tropical clay soils with an orchric A horizon and a deep B horizon, otherwise almost characterless. The soil profile looks uniform and maybe some metres thick. It is well drained, has a good permeability and a stable structure. As there is little or no weatherable mineral, because these soils are old and exhausted of bares, natural fertility is very low. There has been a complicated process of soil formation. Intensive and continuous weathering over a very long period has resulted in leaching of bases and silica, in relative accumulation of resquioxides and in formation of kaolinitic clay. Until recently, there has been much confusion in classifing and naming tropical soils. Particularily what are now Ferralsols in the FAO scheme, and Oxisols in Soil Taxonomy. Old names of various classification system are: Lateritic soils, Latosols, Ferrallitic soils. For agriculture, these soils are important, but chemically very poor, not only because of a low CEC but also because of deficiency of bases, especially Ca, Mg, and K, strong P fixation and high exchangeable Al percentage.

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An Applicable Method of an Electromagnetic Wave Absorber for SAR Reduction in the Human Head Exposed to Electromagnetic Fields Radiated by a Cellular Phone (휴대폰 전자파에 노출된 두부내 SAR 저감을 위한 전자파 흡수체 적용 방법 연구)

  • 이윤경;백락준;홍진옥;육재림;윤현보
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.14 no.8
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    • pp.884-890
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    • 2003
  • In order to reduce the specific absorption rate(SAR) in a human head exposed to electromagnetic fields radiated by a cellular phone, we have analyzed an electromagnetic wave absorber attached to the handset. A manufactured electromagnetic wave absorber was composed of Mn - Zn, which had complex relative permittivity of 7.30-j0.05 and permeability of 2.20-i1.55. The SAR value from the electromagnetic wave absorber attachment was calculated by using the nonuniform finite difference time domain(FDTD) algorithm and measured by phantom model at 835 MHz. The SAR reduction due to the electromagnetic wave absorber are about 18 % at 835 MHz. The V.S.W.R and radiation pattern of antenna are good agreement with the normal antenna. The gain reduction due to the electromagnetic wave absorber are only 0.3 dB at 835 MHz. But the sensitivity of cellular phone generally improves about 1 dB.

Optimization of Distillation-Pervaporation Membrane Hybrid Process for Separation of Water/Organic Solvent Mixtures (물/유기용매 분리를 위한 증류-투과증발막 혼성공정의 최적화)

  • Yang, Jeongin;Han, Myungwan
    • Korean Chemical Engineering Research
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    • v.56 no.1
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    • pp.29-41
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    • 2018
  • Separating a mixture having an azeotrope or low relative volatility with single distillation column is difficult. Separating water-acetic acid mixture and water-ethanol mixture with a distillation column consumes a lot of energy. Pervaporation membrane can be used to separate the mixture in the concentration region where separation is difficult with distillation. We simulated a distillation-membrane hybrid process where membrane is located on the head of the distillation column for efficient separation of water-acetic acid and water-ethanol mixture. Permeability data were obtained from experiments and literature. We formulated an optimization problem for the process with total annual cost (TAC) as an objective function and major design variables as optimization variables. Major optimization variable affecting TAC of the hybrid process was shown to be distillate concentration. We also suggested a simplified optimization procedure to get a close-to-optimal solution.

Development of EM Wave Absorber for Countermeasure against EM Wave Environment of 2.4 GHz Wireless LAN (2.4 GHz 무선LAN 전자파 환경대책용 전파흡수체 개발)

  • Yoon, Sang-Gil;Kim, Dae-Hun;Park, Soo-Hoon;Kim, Dong-Il
    • Journal of Navigation and Port Research
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    • v.33 no.3
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    • pp.193-197
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    • 2009
  • In this paper, the EM wave absorber was designed and fabricated for improvement of Wireless LAN environment at 2.4 GHz. We fabricated several samples in different composition ratios of Sendust and CPE(Chlorinated Polyethylene). Absorption abilities were simulated in accordance with different thicknesses of the prepared absorbers and changed complex relative permittivity and permeability due to composition ratio. The mixing ratio of Sendust and CPE was searched as 80: 20 wt.% by experiments and simulation Then the EM wave absorber was fabricated and tested using the simulated data. As a result, the EM wave absorber was fabricated based on simulated data. Simulated and measured results agreed well. As a result, the developed EM wave absorber with thickness of 3.25 mm has absorption ability of 19 dB at 2.4 GHz.

Polymer Electrolyte Membranes of Poly(Styrene-Butadiene-Styrene) Star Triblock Copolymer for Fuel Cell (연료전지용 Poly(Styrene-Butadiene-Styrene) Star Triblock Copolymer의 고분자 전해질 분리막)

  • Garcia, Edwin D.;Jung, Bumsuk
    • Membrane Journal
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    • v.29 no.5
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    • pp.252-262
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    • 2019
  • A sulfonated star branched poly(styrene-b-butadiene-b-styrene) triblock copolymer (SSBS) was synthesized with varying degrees of sulfonation. The effective sulfonation on the butadiene block was confirmed by FT-IR spectroscopy. Ion exchange capacity by titration was used to determine the degree of sulfonation. The synthesized polymer observed enhanced water uptake and proton conductivity. At room temperature, the SSBS with 25 mol% degree of sulfonation showed an outstanding proton conductivity of 0.114 S/cm, similar to that of commercial membrane, Nafion. The effect of temperature at constant relative humidity on conductivity resulted to a remarkable increase in proton conductivity. Methanol permeability studies showed a value lower than Nafion for all the sulfonated membranes. Structural nature observed using AFM showed that the membranes observed microphase separated nanostructures and the connectivity of the interionic channels.

Durability Evaluation of PEMFC Electrode Using Oxygen as Cathode Gas (PEMFC Cathode 산소 조건에서 전극 촉매 내구성 평가)

  • Oh, Sohyeong;Lim, Daehyeon;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.59 no.1
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    • pp.11-15
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    • 2021
  • In this study, we tried to develop a method of accelerated degradation of the electrode by simply using a electronic loader without using a potentiostat to evaluate the durability of the electrode catalyst. To this end, the durability of the electrode was evaluated by repeating the stepwise voltage change using the self-generated voltage by introducing oxygen without introducing nitrogen into the cathode. For accurate electrode durability evaluation, that is, in order not to deteriorate the polymer membrane, the high voltage was lowered to 0.9 V in stepwise voltage change and the relative humidity was 100% to suppress degradation of the polymer membrane due to radicals. After 30,000 cycles (50 hours) of voltage change, the electrode active area decreased by 41.4%. It was confirmed that the electrode was deteriorated, but the polymer membrane was not deteriorated, that there was no increase in hydrogen permeability, no decrease in membrane thickness, and no increase in HFR(High Frequency Resistance).

Study on the Short Resistance and Shorting of Membrane of PEMFC (PEMFC 고분자 막의 Short 저항 및 Shorting에 관한 연구)

  • Oh, Sohyeong;Gwon, Jonghyeok;Lim, Daehyeon;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.59 no.1
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    • pp.6-10
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    • 2021
  • The shorting resistance (SR) of the PEMFC(Proton Exchange Membrane Fuel Cell) polymer membrane is an important indicator of the durability of the membrane. When SR decreases, shorting current (SC) increases, reducing durability and performance. When SR becomes less than about 0.1 kΩ·㎠, shorting occurs, the temperature rises rapidly, and MEA(Membrane Electrode Assembly) is burned to end stack operation. In order to prevent shorting, we need to control the SR, so the conditions affecting the SR were studied. There were differences in the SR measurement methods, and the SR measurement method, which improved the DOE(Department of Energy) and NEDO(New Energy and Industrial Technology Development Organization) method, was presented. It was confirmed that the SR decreases as the relative humidity, temperature and cell compression pressure increase. In the final stage of the accelerated durability evaluation process of the polymer membrane, SR rapidly decreased to less than 0.1 kΩ·㎠, and the hydrogen permeability became higher than 15 mA/㎠. After dismantling the MEA, SEM(Scanning Electron Microscope) analysis showed that a lot of platinum was distributed inside the membrane.

Physical Properties of Liquid Ammonia Wood for Bending (휨가공을 위한 액체암모니아 처리재의 물리적 성질)

  • Kang, Ho-Yang
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.1
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    • pp.52-60
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    • 2003
  • The physical properties of small hardwood and softwood specimens treated with liquid ammonia were investigated. The specimens treated for 4 or 18 hours were compared with the controls. The EMCs of the liquid ammonia treated specimens were higher than those of the controls when conditioned at the same humidities. However once oven-dried they didn't show any significant differences in EMCs. With the increase of liquid ammonia treatment time specimens shrank in radial and tangential directions, but not in longitudinal direction. As liquid ammonia treatment time increased the ultrasonic velocities of specimens decreased and their densities increased, thus their dynamic MOEs decreased. For chestnut specimens the presteamed were more plasticized than the liquid ammonia treated. Incising on the surfaces of specimens didn't improve liquid ammonia permeability in both hardwoods and softwoods. Liquid ammonia treatment was very effective for plasticizing 5 mm thick softwoods. Relative dielectric constants and thermal conductivities were measured with both liquid ammonia treated and control specimens.

Effects of bis(2-ethylhexyl) phthalate(DEHP) on plant soil-borne pathogenic bacterium Pectobacterium carotovorum in vitro (Bis(2-ethylhexyl) phthalate가 in vitro에서 식물 토양병원성 세균 Pectobacterium carotovorum에 미치는 영향)

  • Yu-Ri Kim;Sang Tae Kim;Mee Kyung Sang
    • Korean Journal of Environmental Biology
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    • v.40 no.4
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    • pp.398-404
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    • 2022
  • Bis(2-ethylhexyl) phthalate (DEHP) is one of the plasticizers used in the polyvinyl chloride(PVC) industry. It is known to be easily released into the environment. In this study, we investigated effects of DEHP on growth, metabolic pathway, and virulence gene expression in soil-borne bacterial plant pathogen, Pectobacterium carotovorum SCC1 using in vitro assays. As a result, DEHP at 20 ㎍ mL-1 did not affect the growth, cell membrane permeability, or ATPase activity of P. carotovorum SCC1. However, it decreased succinyl-CoA synthase (SCS) activity in the tricarboxylic acid (TCA) cycle. Relative expression levels of virulence genes encoding pectate lyase and pectin were differentially influenced by DEHP treatment. These results suggest that biological characteristics of P. carotovorum might be influenced by DEHP in soil.

Preparation of Hypoallergenic Whey Protein Hydrolysate by a Mixture of Alcalase and Prozyme and Evaluation of Its Digestibility and Immunoregulatory Properties

  • Jiyeon Yang;Se Kyung Lee;Young Suk Kim;Hyung Joo Suh;Yejin Ahn
    • Food Science of Animal Resources
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    • v.43 no.4
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    • pp.594-611
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    • 2023
  • Whey protein (WP) has nutritional value, but the presence of β-lactoglobulin (β-LG) and α-lactalbumin (α-LA) cause allergic reactions. In this study, hypoallergenic whey protein hydrolyate (HWPH) was prepared by decomposing β-LG and α-LA of WP using exo- and endo-type proteases. The enzyme mixing ratio and reaction conditions were optimized using response surface methodology (RSM). Degradation of α-LA and β-LG was confirmed through gel electrophoresis, and digestion, and absorption rate, and immunostimulatory response were measured using in vitro and in vivo systems. Through RSM analysis, the optimal hydrolysis conditions for degradation of α-LA and β-LG included a 1:1 mixture of Alcalase and Prozyme reacted for 10 h at a 1.0% enzyme concentration relative to substrate. The molecular weight of HWPH was <5 kDa, and leucine was the prominent free amino acid. Both in vitro and in vivo tests showed that digestibility and intestinal permeability were higher in HWPH than in WP. In BALB/c mice, as compared to WP, HWPH reduced allergic reactions by inducing elevated Type 1/Type 2 helper T cell ratio in the blood, splenocytes, and small intestine. Thus, HWPH may be utilized in a variety of low allergenicity products intended for infants, adults, and the elderly.