• Bulletin of the Korean Chemical Society
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• 제11권4호
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• pp.343-347
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• 1990

A thermal decomposition of the tert-butoxy radical has been studied in the gas phase over the pressure range of 1-200 torr at $413_{\circ}K$ using di-tert-butyl peroxide + trimethylsilane mixtures. The relative rate constants were obtained by studying the competitive reactions between tert-butoxy radical decomposition 4(t-BuO·→ CH_3COCH_3 + CH_3·)$ and hydrogen abstraction reaction from trimethylsilane $(t-BuO·+ HSi(CH_3)_3 → t-BuOH + Si(CH_3)_3)·).$ The conventional RRKM calculations were carried out to compare the observed fall-off behavior of the decomposition rate constant $({\kappa}_d)$ with the theoretical predictions using reasonable values of input parameters. In all cases the calculated half-rate pressure $(P_{1/2})$ were significantly higher than those observed. The failure of RRKM to reproduce the fall-off behavior led us to suggest that not all of vibrational modes contribute to excitation (leading to decomposition) on the same time scale.

• Communications for Statistical Applications and Methods
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• 제31권1호
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• pp.105-127
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• 2024

We propose recurrent neural network (RNN) methods for forecasting realized volatility (RV). The data are RVs of ten major stock price indices, four from the US, and six from the EU. Forecasts are made for relative ratio of adjacent RVs instead of the RV itself in order to avoid the out-of-scale issue. Forecasts of RV ratios distribution are first constructed from which those of RVs are computed which are shown to be better than forecasts constructed directly from RV. The apparent asymmetry of RV ratio is addressed by the Piecewise Min-max (PM) normalization. The serial dependence of the ratio data renders us to consider two architectures, long short-term memory (LSTM) and gated recurrent unit (GRU). The hyperparameters of LSTM and GRU are tuned by the nested cross validation. The RNN forecast with the PM normalization and ratio transformation is shown to outperform other forecasts by other RNN models and by benchmarking models of the AR model, the support vector machine (SVM), the deep neural network (DNN), and the convolutional neural network (CNN).

• 한국안광학회지
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• 제7권2호
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• pp.169-174
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• 2002

Photochromic lens의 광감성 평가 방법을 만들고, 이를 적용시키기 위하여 Photochromic lens에 UV light source을 조사하였다. UV light 광원을 조사 전과 후의 darkening과 fading 상태의 transmittance(T%)의 파장 의존성을 spectrophotometer, light source, power meter, detecter로 구성된 광학적 장치로 측정한다. 조사 직전의 최대 $T%{\times}{\lambda}$ 면적과 saturated state면적의 상대적 비율을 이용한다. Photochromic lens에서 조사시간 의존성의 평가는 darkening 효율도 ($K_d$)값 ($(1-C_1/A_1)/t_{on}$과 fading 효율도($K_f$)값 ($(C_2/A_2)/t_{on}$을 도입하였다. Darkening과 fading 상태에서 transmittance(T%)의 파장의존성은 $T_m+T_1{\exp}[-(x_0-t)/a]$의 형태를 갖는다. Photochromic lens에서 광감성의 평가 parameter Z, $K_d$, $K_f$를 적용한 결과 각 평가 지수 값을 얻을 수 있다.

• 천문학회보
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• 제38권2호
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• pp.52.2-52.2
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• 2013

We explore the relative importance of the role of small-scale environment and large-scale environment in triggering nuclear activity of the local galaxies using a volume-limited sample with $M_r$ < -19.5 and 0.02 < z < 0.0685 selected from the Sloan Digital Sky Survey Data Release 7. The active galactic nuclei (AGN) host sample is composed of Type II AGNs identified with flux ratios of narrow emission lines with S/N > 6 and the central velocity dispersion of the sample galaxies is limited to have a narrow range between 130 < ${\sigma}$ < 200($km\;s^{-1}$), corresponding to 7.4 < $log(M_{BH}/M_{\odot})$ < 8.1 in order to fix the mass of the supermassive black hole at the center of its host galaxy. In this study, we find that the AGN fraction ($f_{AGN}$) of late-type galaxies are larger than of early-type galaxies and that for target galaxy with late-type nearest neighbor, $f_{AGN}$ starts to increase as the target galaxy approaches the virial radius of the nearest neighbor (about a few hundred kpc scale). The latter result may support the idea that the hydrodynamic interaction with the nearest neighbor as well as tidal interaction and merger also plays an important role in triggering the nuclear activity of galaxy. We also find that early-type cluster galaxies show decline of AGN activity compared to ones in lower density regions, whereas the direction of dependence of AGN activity for late-type galaxies is opposite.

• 한국재료학회지
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• 제9권1호
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• pp.42-45
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• 1999

The room temperature optical transmission spectra of GaN /InGaN/GaN single quantum wells (SQW) and InGaN/GaN heterostructures grwon by low pressure metalorganic chemical vapor deposition have been measured. The dependence of the absorption edges of the GaN/InGaN/GaN SQW on the well width has been determined from the transmission spectra. The result shows that the absorption edge of GaN/InGaN/GaN SQW shifts towards lower energy as increasing the well width. The dependence of the absorption edges of the InGaN/GaN heterostructures on InN mole fraction has also been determined from the transmission spectra. The result is compared with calculated values obtained from Vegards's laws. Our result shows a good agreement with the calculated values.

• 한국방사선학회논문지
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• 제12권1호
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• pp.79-83
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• 2018

본 논문에서는 OSL 도트 선량계의 교정인자, 흡수선량 선형성, 피크전압 선형성, 각도 변화에 의한 흡수선량 변화를 측정하고 분석했다. 의료용 X 선발생 장치를 사용하여 조사에 노출 선량 보정 계수, 흡수선량 선형성, 피크 전압 선형성은 모두 IEC-62387-1 (2007) 기준을 만족하였다. 기준 방사선 노출과 관련하여 0도, 30도 및 60도에서 선량계 방향에 대한 기준은 -29 % (${\pm}30^{\circ}$) 및 + 67 % (${\pm}60^{\circ}$)이었다. 30도에서 측정된 값은 기준보다 -8 % 낮고 60도에서 기준보다 -18 % 낮게 나타났다. 그러므로 OSL 도트 선량계 사용 시 방향에 따른 영향을 보정하여야 한다.

• 폴리머
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• 제33권4호
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• pp.326-332
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• 2009

새로운 감습성 단량체인 N-methacryloyl-N'-ethyl-N'-propyl piperazinium bromide(MANEPPB)를 N-methacryloyl-N'-ethyl piperazine(MANEP)와 1-bromopropane의 4차염화 반응에 의하여 합성하였다. MANEPPB/MMA/AA=60/35/5, 70/25/5, 80/15/5, 90/5/5 및 95/0/5 조성의 전해질 공중합체를 감습막으로 사용하기 위하여 제조하였다. 상기 감습액에 아지리딘 가교제인 trimethylolpropane tris(2-methyl-1-aziridinopropionate)(TTAP)를 혼합하여 금 전극 위에 침적법에 의하여 도포하고 가교반응을 진행하여 습도센서를 제조 하였다. 상대습도에 대한 습도센서의 저항을 측정하였을 때, $20{\sim}90%RH$ 상대습도 영역에서 $10^3$의 저항 값이 변화하였으며, 이것은 상용 습도센서로서 대기의 습도를 측정하는데 요구되는 특성을 보여주었다. 그 밖에 온도 의존성, 주파수 의존성, 히스테리시스, 응답 및 회복 속도 그리고 내수성을 측정하여 습도센서로서 특성을 평가하였다.

• 한국대기환경학회지
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• 제29권3호
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• pp.264-274
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• 2013

This study investigates long-term trends and characteristics of aerosol light scattering coefficient at Seoul and Baengnyeongdo in order to understand aerosol optical and radiative properties around Korea. The analysis period is limited to one year of 2011. First, the aerosol scattering coefficients (${\sigma}_{sp}$) of both sites show strong linear dependence on the $PM_{2.5}$ mass concentrations with significant correlations between both. Further, correlations and sensitivity between ${\sigma}_{sp}$ and $PM_{2.5}$ increase with relative humidity, implying both relationships are strongly dependent upon moisture amounts in the atmosphere. This study applied 3-step careful quality control procedures to the analysis of ${\sigma}_{sp}$ for the insurance of data confidence. For the relationship analysis of extinction coefficients (${\sigma}_{ext}$) to visibility and aerosol optical depth, ${\sigma}_{sp}$ observed at 3 p.m. have been used with help of aerosol absorption coefficients (${\sigma}_{ap}$) in order to remove its dependence upon relative humidity, and also those of rainy period have been excluded. As expected, ${\sigma}_{ext}$ estimated are inversely proportional to visibility observation by eye. Finally, aerosol extinction coefficients have been vertically integrated with an assumption of nearly well-mixed within an e-folding height to determine aerosol optical depth, and compared with those retrieved from sunphotometer. The results show a reasonable agreement in spite of an inherent difference of each definition. We expect these findings would help to eventually understand aerosol radiative forcing and its effect on the regional climate change around Korea.

• 산업진흥연구
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• 제6권4호
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• pp.39-45
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• 2021

본 연구는 위니캇의 이론을 중심으로 상담자의 중간대상 역할을 문헌연구를 통하여 제시하였다. 발달과정에서 유아가 어머니와 절대적 의존에서 상대적 의존으로 넘어갈 때 불안을 겪는데 이때 중간대상인 인형, 손 빨기 등이 유아의 불안을 감소시킨다. 이처럼 상담자의 중간 대상 역할은 상실 경험에 대한 분리불안과 우울 불안을 완충시켜주고, 전능 환상에서 현실 세계로 매개하여준다. 중간대상은 새로운 대상으로 현실에서 적응하도록 이바지 하는 기능을 가지고 있다. 그리고 중간대상과 중간현상을 통하여 분리 개별화 단계로 이어진다. 전능한 창조와 파괴, 그리고 현실에 적응하기 위해 존재하는 실제적인 타자에 대한 감각을 체득한다고 할 수 있다. 충분히 좋은 어머니는 유아의 전능성을 의미 있게 만들어 준다. 이러할 때 참자기는 유아의 약한 자아를 성장하게 하여 자신의 삶을 살도록 이끌어 준다. 어머니가 유아의 욕구를 채워주지 못할 경우 환상과 자발적 충동이 결핍된다. 즉, 어머니가 유아의 욕구를 반영해 주지 못할 때 유아가 어머니의 기분을 살피게 되어 참자기를 포기하고 거짓 자기를 만들게 된다. 절대적 의존기의 병리는 충분히 좋은 어머니의 공감과 안아주는 환경의 실패로 인해 발생한다. 이때 아이는 전능 환상의 붕괴를 경험하고 멸절 불안을 경험하게 된다. 그러므로 상담현장에서 상담자의 중간대상 역할을 통해서 내담자의 분리불안과 우울 불안을 감소시켜서 편안하고 안정된 환경을 제공할 때 효율적인 상담을 진행할 수 있다.

• The Korean Journal of Physiology and Pharmacology
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• 제7권5호
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• pp.267-273
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• 2003

We have investigated the effect on inducing substate(s) of positively charged residues replaced in position 172 of the second transmembrane domain in murine inward rectifier potassium channels, formed by stable or transient transfection of Kir2.1 gene in MEL or CHO cells. Single channel recordings were obtained from either cell-attached patches or inside-out patches excised into solution containing 10 mM EDTA to rule out the effect of $Mg^{2+}$ on the channel gating. The substate(s) could be recorded with all mutants D172H, D172K and D172R. The unitary current-voltage (I-V) relation was not linear with D172H at $pH_i$ 6.3, whereas the unitary I-V relation was linear at $pH_i$ 8.0. The relative occupancy at $S_{LC}$ was increased from 0.018 at $pH_i$ 8.0 to 0.45 at $pH_i$ 5.5. In H-N dimer, that was increased from 0.016 at $pH_i$ 8.0 to 0.23 at $pH_i$ 5.5. The larger the size of the side chain or $pK_a$ with mutants (D172H, D172K and D172R), the more frequent the transitions between the fully open state and substate within an opening. The conductance of the substate also depended upon the pKa or the size of the side chain. The relative occupancy at substate $S_{LC}$ with monomer D172K (0.50) was less than that in K-H dimer (0.83). However, the relative occupancy at substate with D172R (0.79) was similar to that with R-N dimer (0.82). In the contrary to ROMK1, positive charge as well as negative charge in position 172 can induce the substate rather than block the pore in murine Kir2.1. The single channel properties of the mutant, that is, unitary I-V relation, the voltage dependence of the mean open time and relative occupancy of the substates and the increased latency to the first opening, explain the intrinsic gating observed in whole cell recordings.