• Title/Summary/Keyword: Reinforced Rubber

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Effect of Carbon Black Concentration and Monomer Compositional Ratio on the Flow Behavior of Copoly(styrene/butyl methacrylate) Particles (카본블랙의 농도 및 단량체 구성비에 따른 스티렌-부틸메타크릴레이트 공중합체 입자의 유동성)

  • Park, Moon-Soo;Moon, Ji-Yeon
    • Elastomers and Composites
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    • v.45 no.2
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    • pp.122-128
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    • 2010
  • We measured shear viscosity of copoly(styrene(St)/butyl methacrylate(BMA)) (co-PSB) particles, with a capillary rheometer at $170^{\circ}C$, prepared by suspension polymerization with hydrophobic silica as a stabilizer. co-PSB particles with the weight average molecular weights of lower than 74,800 g/mol displayed a Newtonian behavior at low shear rates. With the weight average molecular weight exceeding 136,800 g/mol, co-PSB particles showed shear thinning against shear rates and the absolute value of the slopes between shear viscosity vs. shear rate increased. When the ratio between St and BMA changed from 7/3 to 5/5 to 3/7, shear viscosity and glass transition decreased despite similar molecular weights. When the ratio was 1/9, it showed a large increase in initial shear viscosity despite reduced glass transition. Shear viscosity exhibited an increase in proportion to carbon black concentration. The effect of carbon black concentration on the shear viscosity of co-PSB composites was less pronounced compared to varying molecular weights and/or compositional ratio.

A Study on the Warpage in Injection Molded Part for Various Part Designs and Non Reinforced Resins (비 보강 수지의 종류와 사출성형품의 설계에 따른 휨의 연구)

  • Lee, M.;Kim, J.H.;Park, S.R.;Lyu, M.Y.
    • Elastomers and Composites
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    • v.44 no.4
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    • pp.373-377
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    • 2009
  • Most of the plastics products are being manufactured by injection molding. Warpage in injection molded affects the product dimension and it causes assembling problem. In this study, warpages in the injection molded part been studied. Specimens are rectangular flat shapes with and without ribs. Amorphous polymers (PC and ABS) and crystalline polymers (PP and PA66) were used for material. Flat shape with ribs showed higher warpage than flat shape without ribs by 6 to 9%. The specimens with ribs that are located parallel to the flow direction has higher warpage than specimens with ribs that are located perpendicular to the flow direction by 25 to 39%. Crystalline polymers have higher warpage than amorphous polymers by 23 to 67%. Warpage decreases as packing time increases and it increases as injection temperature increases.

The Functionalization and Preparation Methods of Carbon Nanotube-Polymer Composites: A Review (탄소나노튜브-폴리머 복합체의 기능화와 제조방법)

  • Oh, Won-Chun;Ko, Weon-Bae;Zhang, Feng-Jun
    • Elastomers and Composites
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    • v.45 no.2
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    • pp.80-86
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    • 2010
  • Carbon nanotubes (CNTs) exhibit excellent mechanical, electrical, and magnetic properties as well as nanometer scale diameter and high aspect ratio, which make them an ideal reinforcing agent for high strength polymer composites. The functionalized CNTs are believed to be very promising in the fields such as preparation of functional and composite materials. CNT-Polymer composites are expected to have good processability characteristics of the polymer and excellent functional properties of the CNTs. However, since CNTs usually form stabilized bundles due to Van der Waals interactions, are extremely difficult to disperse and align in a polymer matrix. The biggest issues in the preparation of CNT-reinforced composites reside in efficient dispersion of CNTs into a polymer matrix, and the alignment and control of the CNTs in the matrix. There are several methods for the dispersion of nanotubes in the polymer matrix such as solution mixing, bulk mixing, melt mixing, in-situ polymerization and chemical functionalization of the carbon nanotubes, etc. These methods and preparation of high performance CNT-polymer composites are described in this review.

Displacement-based design approach for highway bridges with SMA isolators

  • Liu, Jin-Long;Zhu, Songye;Xu, You-Lin;Zhang, Yunfeng
    • Smart Structures and Systems
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    • v.8 no.2
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    • pp.173-190
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    • 2011
  • As a practical and effective seismic resisting technology, the base isolation system has seen extensive applications in buildings and bridges. However, a few problems associated with conventional lead-rubber bearings have been identified after historical strong earthquakes, e.g., excessive permanent deformations of bearings and potential unseating of bridge decks. Recently the applications of shape memory alloys (SMA) have received growing interest in the area of seismic response mitigation. As a result, a variety of SMA-based base isolators have been developed. These novel isolators often lead to minimal permanent deformations due to the self-centering feature of SMA materials. However, a rational design approach is still missing because of the fact that conventional design method cannot be directly applied to these novel devices. In light of this limitation, a displacement-based design approach for highway bridges with SMA isolators is proposed in this paper. Nonlinear response spectra, derived from typical hysteretic models for SMA, are employed in the design procedure. SMA isolators and bridge piers are designed according to the prescribed performance objectives. A prototype reinforced concrete (RC) highway bridge is designed using the proposed design approach. Nonlinear dynamic analyses for different seismic intensity levels are carried out using a computer program called "OpenSees". The efficacy of the displacement-based design approach is validated by numerical simulations. Results indicate that a properly designed RC highway bridge with novel SMA isolators may achieve minor damage and minimal residual deformations under frequent and rare earthquakes. Nonlinear static analysis is also carried out to investigate the failure mechanism and the self-centering ability of the designed highway bridge.

Development of Water-lubricated Plastic Bearings (수-윤활용 플라스틱 베어링 개발에 관한 연구)

  • Hosung Kong;Hung-gu Han
    • Tribology and Lubricants
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    • v.39 no.6
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    • pp.235-243
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    • 2023
  • This paper presents the fabrication process of water-lubricated plastic bearings. Plastic bearings require good mechanical properties and tribological properties as well as elasticity and shock resistance, especially when lubricated in dirty water conditions. In this study, sleeve-type plastic bearings are produced by winding a prepreg sheet, which primary contains nitrile rubber (NBR)-modified epoxy, self-lubricating fillers, and various types of lattice-structured reinforcing fibers such as carbon, Aramid, and polyethylene terephthalate. A thermosetting epoxy is chemically modified with NBR to impart elasticity and low-friction characteristics in water conditions. Experimental investigations are conducted to examine the mechanical and tribological characteristics of the developed bearing materials, and the results are compared with the characteristics of a commercial plastic bearing (Thordon SXL), well known as a water-lubricated bearing. A Thordon bearing (mainly composed of polyurethane) exhibits an extremely low load-bearing capacity and is thus only suitable for medium loading (1~10MPa). The tribological characteristics of the test materials are evaluated through Falex block-on-ring (LFW-1) friction and wear tests. The results indicate that friction exhibited by the carbon-fiber-reinforced NBR-10wt.%-modified epoxy composite material, incorporated with the addition of 20wt.% UHMWPE and 6wt.% paraffin wax, is lower than that of the Thorden bearings, whereas its wear resistance surpass that of Thorden ones. Because of these features, the load carrying capacity of the fabricated composite (>10MPa) is higher than that of the Thorden bearings. These results confirm the applicability of water-lubricated plastic bearing materials developed in this study.

Interfacial and Mechanical properties of Different Heat Treated Wood and Evaluation of Bonding Property between Stone and Wood for Rock Bed (열처리 조건에 따른 목재의 계면과 기계적 물성 및 돌침대용 석재/목재간 접착제에 따른 접착력 평가)

  • Kwon, Dong-Jun;Shin, Pyeong-Su;Choi, Jin-Yeong;Moon, Sun-Ok;Park, Joung-Man
    • Journal of Adhesion and Interface
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    • v.16 no.2
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    • pp.69-75
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    • 2015
  • Stone board for the rock bed was needed to reduce weight using thin thickness and reinforced materials. In this work, stone/wood board for rock bed was studied. Stone and wood were attached to reduce total weight of stone for rock bed. For reinforcing wood heat treatment method was used to change surface and mechanical properties. Mechanical strength of heat treated wood increased more than neat condition. The optimum heat treatment condition was set on $100^{\circ}C$ under tensile, flexural loads whereas surface energy was also obtained by contact angle measurement. Optimum adhesive condition was to get the maximum adhesion between stone and wood. Lap shear test was performed for stone/wood board with different adhesives such as amine type epoxy, polyurethane, chloro-rubber and vinyl chloride acetate type. Fracture surface of lap shear test was shown at wood fracture part on stone using amine type epoxy adhesive. It was found that for high adhesion between stone and wood the optimum adhesive was epoxy type for the rock bed.

Preparation and Characterization of Wood Polymer Composite by a Twin Screw Extrusion (이축 압출공정을 이용한 Wood Polymer Composite의 제조 및 특성 분석)

  • Lee, Jong-Hyeok;Lee, Byung-Gab;Park, Ki-Hun;Bang, Dae-Suk;Jhee, Kwang-Hwan;Sin, Min-Cheol
    • Elastomers and Composites
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    • v.46 no.3
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    • pp.211-217
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    • 2011
  • Wood Polymer Composite (WPC) has attracted a great deal of attention in environmental industries due to renewable resources, processability, excellent physical properties and logging regulations for application to housing units and engineering construction materials. In this study, commercial WPCs were prepared by using a modular intermeshing co-rotating twin screw extruder. The effect of three main factors such as wood flour contents, coupling agent concentrations and pre-treatment of wood flour on the properties of WPCs was extensively investigated. It was found that tensile strength and thermal stability were decreased with increasing wood flour contents whereas the water absorption was increased. Addition of maleic anhydride grafted polypropylene (PP-g-MA) into WPC exhibited better physical properties. On the contrary, the water absorption was slightly decreased with PP-g-MA. Finally the sample, which was prepared with pre-treated wood flour, represented the highest tensile strength. However, the water absorption of the sample was increased due to the transition of crystalline structure of cellulose.