• 한국대기환경학회지
• /
• 제28권5호
• /
• pp.527-537
• /
• 2012

The increasing consumption of pseudo-petroleum products (PPP) has been disturbing the national petroleum market. The use of PPP lead to tax evasion, disturbance of sound trading principles, component corrosion of cars, and explosion accident. Also, PPP have emitted hazardous air pollutants (HAP) including the carcinogenic aromatic hydrocarbons, PAHs and aldehydes more than regular-petroleum products. It thus has potentials to cause many environmental and health care problems. In this study, benzene, toluene and xylene emissions from road transport vehicles due to the use of pseudo-gasoline are estimated for the year 2008. The results of our study provide emission estimates of benzene, toluene and xylene for the year as 405, 1,711, 717 tonne/yr, respectively for regular-gasoline. BTX emissions are calculated as 452~515, 1,882~2,264 and 732~752 tonne/yr when the amount of pseudo-gasoline is estimated to account for 6~13% for regular-gasoline consumption. BTX emissions increased as much as 12~27, 10~32, 2~5% by using pseudo-gasoline. It is found that the pseudo-gasoline should be the key component to produce HAP in urban area.

• 한국안전학회지
• /
• 제33권2호
• /
• pp.45-51
• /
• 2018

This study was conducted to assess the hazards of gasoline in relevance to the changes in octane numbers, and gasoline's spontaneous ignition temperature and instantaneous ignition temperature were measured. Spontaneous ignition temperature of regular gasoline was $301^{\circ}C$ for sample quantity of $100{\sim}125{\mu}{\ell}$. Spontaneous ignition temperature of middle gasoline was $380^{\circ}C$ for sample quantity of $125{\mu}{\ell}$ and that of premium gasoline was $400^{\circ}C$. As gasoline's octane numbers increased, their spontaneous ignition temperatures increased, and their instantaneous ignition temperature were almost identically $499^{\circ}C$ for sample quantity of $125{\mu}{\ell}$. In addition, activation energies of regular gasoline, middle gasoline, and premium gasoline were 10.48 Kcal/mol, 16.89 Kcal/mol, and 24.55 Kcal/mol respectively.

• 자원ㆍ환경경제연구
• /
• 제25권4호
• /
• pp.495-516
• /
• 2016

본 연구는 국제 원유가격의 변동에 따른 수송용 유류제품 가격의 비대칭성(rockets and feather)을 오차수정모형을 사용하여 분석한다. 회귀분석결과에 따르면, 모든 수송용 유류제품에서 비대칭성 현상이 일관성 있게 나타났으며, 특히 고급휘발유에서는 타 유종에 비해서 비용 상승기와 비용 하강기에 모두에서 비용의 변화의 충격에 민감하게 반응하는 것으로 추정되었다. 이는 비용상승기의 경우, 마진이 높은 고급휘발유의 특성상, 이를 빠르게 반영하는 것은 이윤극대화를 추구하는 기업의 합리적인 반응일 것으로 추정된다. 그러나 비용이 하락할 경우에 고급휘발유가 타 유종에 비해서 빠르게 하락하는 현상은, 고급휘발유 가격이 상승할 때, 일반휘발유로 이동했던 소비자들과 고급휘발유에 대한 잠재적 수요를 가진 일반 휘발유 소비자들을 고급휘발유 소비로 끌어들일 수 있는 유인이 존재하기 때문으로 판단된다.

• 한국안전학회지
• /
• 제25권4호
• /
• pp.13-18
• /
• 2010

To investigate electrostatic ignition hazards of commercial gasoline used in the gas station, experiments were conducted dealing with the minimum ignition energy(MIE) of several kinds of gasoline under the various temperature. The conductivity of gasoline that was required for an accurate risk assessment as well as the MIE were also examined. The solvent ignitability apparatus which can heat up the inside of the vessels up to $210^{\circ}C$ was used in this study. Four kinds of premium gasoline and four kinds of regular gasoline, differing with respect to the companies, were used as test specimens. The following results were obtained: (1) all gasoline specimens were so sensitive that even an electrostatic discharge with a very low energy, such as about 0.5mJ, could ignite them. The ignitability of premium gasoline was constant irrespective of the companies. On the other hand, the ignitability of regular gasoline was variable depending on the company. (2) The MIE of all specimens depended markedly on the temperature; in other words, an increase in temperature decreases the ignition energy value. (3) The conductivity values of all specimens were low. Those must be taken into consideration in electrostatic risk assessment.

• 한국자동차공학회논문집
• /
• 제14권3호
• /
• pp.178-185
• /
• 2006

This paper investigates the steady-state combustion characteristics of the Homogeneous charge compression ignition(HCCI) engine with variable valve timing(VVT) and dimethyl ether(DME) direct injection, to find out its benefits in exhaust gas emissions. HCCI combustion is an attractive way to lower carbon dioxide($CO_2$), nitrogen oxides(NOx) emission and to allow higher fuel conversion efficiency. However, HCCI engine has inherent problem of narrow operating range at high load due to high in-cylinder peak pressure and consequent noise. To overcome this problem, the control of combustion start and heat release rate is required. It is difficult to control the start of combustion because HCCI combustion phase is closely linked to chemical reaction during a compression stroke. The combination of VVT and DME direct injection was chosen as the most promising strategy to control the HCCI combustion phase in this study. Regular gasoline was injected at intake port as main fuel, while small amount of DME was also injected directly into the cylinder as an ignition promoter for the control of ignition timing. Different intake valve timings were tested for combustion phase control. Regular gasoline was tested for HCCI operation and emission characteristics with various engine conditions. With HCCI operation, ignition delay and rapid burning angle were successfully controlled by the amount of internal EGR that was determined with VVT. For best IMEP and low HC emission, DME should be injected during early compression stroke. IMEP was mainly affected by the DME injection timing, and quantities of fuel DME and gasoline. HC emission was mainly affected by both the amount of gasoline and the DME injection timing. NOx emission was lower than conventional SI engine at gasoline lean region. However, NOx emission was similar to that in the conventional SI engine at gasoline rich region. CO emission was affected by the amount of gasoline and DME.

• 오토저널
• /
• 제3권2호
• /
• pp.18-26
• /
• 1981

The purpose of this paper is to study the possibility of practical use of gasoline-methanol mixed fuel as an alternative fuel of gasoline engines in the light of engine performances and harmful exhaust emissions as well as mixings and separations of the mixed fuels. When the methanol of 99.8% purity is mixed with super or regular gasoline available on the market today, the experimental results obtained without modifying carburetor in this study are as follows; 1.The separation ratio depends upon the gasoline-methanol mixing ratio only, regardless of fuel temperature and fuel additives for preventing separation of phase. 2.The critical absorption ratio is affected by the gasoline-methanol mixing ratio, its temperature and the quantity of fuel additives. 3.Concerning the distillation temperature, the initial point of all sorts of fuels is almost same,but 10% point and 35-60% point of mixed fuels are lower than those of gasoline only. 4.In case of throttle valve opening set, engine output using the mixed fuels is decreased compared to gasoline, but thermal efficiency is increased as a consequence of decreasing specific energy consumption. 5.In case of fixed load test, thermal efficiency is increased at low engine speed even under low part-load as well as under comparatively high part-load including full load. 6.CO and NOx emissions are reduced remarkably with the mixed fuels.

• 한국자동차공학회논문집
• /
• 제14권4호
• /
• pp.149-156
• /
• 2006

This paper investigates the steady state combustion characteristics of LPG homogeneous charge compression ignition(HCCI) engine with variable valve timing(VVT) and dimethyl ether(DME) direct injection, to find out the benefits in exhaust gas emissions. VVT is one of the attractive ways to control HCCI engine. Hot internal residual gas which is controlled by VVT device, makes fuel is evaporated easily, and ignition timing is advanced. Regular gasoline and liquefied petroleum gas(LPG) were used as main fuel and dimethyl ether(DME) was used as ignition promoter in this research. Operating range and exhaust emissions were compared LPG HCCI engine with gasoline HCCI engine. Operating range of LPG HCCI engine was wider than that of gasoline HCCI engine. The start of combustion was affected by the intake valve open(IVO) timing and the ${\lambda}TOTAL$ due to the latent heat of vaporization, not like gasoline HCCI engine. At rich operation conditions, the burn duration of the LPG HCCI engine was longer than that of the gasoline HCCI engine. CAD at 20% and 90% of the mass fraction burned were also more retarded than that of the gasoline HCCI engine. And carbon dioxide(CO2) emission of LPG HCCI engine was lower than that of gasoline HCCI engine. However, carbon oxide(CO) and hydro carbon(HC) emission of LPG HCCI engine were higher than that of gasoline HCCI engine.

• 한국자동차공학회논문집
• /
• 제14권6호
• /
• pp.9-16
• /
• 2006

Variable valve timing is one of the attractive ways to control homogeneous charge compression ignition (HCCI) engine. Hot internal residual gas which can be controlled by variable valve timing(VVT) device, makes fuel evaporated easily, and ignition timing advanced. Regular gasoline was used as main fuel and di-methyl ether(DME) was used as ignition promoter in this research. HCCI engine operating range is limited by high combustion peak pressure and engine noise. High combustion pressure can damage the engine during operation. To avoid engine damage, the rich limits have to define using various methods. Peak combustion pressure, rate of cylinder pressure rise was considered to determine rich limit of engine operating range. Knock probability was correlated with the rate of cylinder pressure rise as well as the peak combustion pressure.

• International Journal of Automotive Technology
• /
• 제7권3호
• /
• pp.295-301
• /
• 2006

A new combustion method of high compression ratio SI engine was studied and proposed in order to achieve high thermal efficiency, comparable to that of CI engine. Compression ratio of SI engine is generally restricted by the knocking phenomena. A combustion chamber profile and a cranking mechanism were studied to avoid knocking with high compression ratio. Because reducing the end-gas temperature will suppress knocking, a combustion chamber was considered to have a wide surface at the end-gas region. However, wide surface will lead to large heat loss, which may cancel the gain of higher compression ratio operation. Thereby, a special cranking mechanism was adapted which allowed the piston to move rapidly near TDC. Numerical simulations were performed to optimize the cranking mechanism for achieving high thermal efficiency. An elliptic gear system and a leaf-shape gear system were employed in numerical simulations. Livengood-Wu integral, which is widely used to judge knocking occurrence, was calculated to verify the effect for the new concept. As a result, this concept can be operated at compression ratio of fourteen using a regular gasoline. A new single cylinder engine with compression ratio of twelve and TGV(Tumble Generation Valve) to enhance the turbulence and combustion speed was designed and built for proving its performance. The test results verified the predictions. Thermal efficiency was improve over 10% with compression ratio of twelve compared to an original engine with compression ratio of ten when strong turbulence was generated using TGV, leading to a fast combustion speed and reduced heat loss.

• Tribology and Lubricants
• /
• 제23권6호
• /
• pp.306-311
• /
• 2007

This paper presents the friction characteristics of pb-fres pin bushing bearings for an automotive gasoline engine. The external load is 100 N to 600 N and the speed of the pin bushing bearing is 1000 rpm to 3000 rpm against the rubbing surfaces. And the contact modes of rubbing surfaces between a piston pin and a pb-free pin bushing specimen are a dry friction, an oil lubricated friction and a mixed friction that is starved by a lack of engine oil. Two influential factors of a contact rubbing modes and a material property are very important parameters on the tribological performance of a friction characteristic between a piston pin and a pb-free pin bushing. The experimental result shows that the pin bushing speed of 2000 rpm shows a typical oil film lubricated sliding contact mode in which means that as the applied load is increased, the friction loss is increasing. But other contact mode depending on the speed and the load may affect to the fiction coefficient without a regular and uniform trend. In summary, the oil lubricated rubbing surface definitely decreases a running-in period in short and increase oil film stiffness, and this may leads the reduction of a friction loss.