• 제목/요약/키워드: Regioselective arylation

검색결과 2건 처리시간 0.015초

Rhodium-Catalyzed Highly Regioselective C-H Arylation of Imidazo[1,2-a]pyridines with Aryl Halides and Triflates

  • Liu, Yi;He, Lin;Yin, Guoqiang;Wu, Guojie;Cui, Yingde
    • Bulletin of the Korean Chemical Society
    • /
    • 제34권8호
    • /
    • pp.2340-2342
    • /
    • 2013
  • A convenient Rh-catalyzed C-H arylation of imidazo[1,2-a]pyridines with a variety of aryl halides or triflates has been reported. This process afforded a range of biaryl compounds in excellent yields and showed high activity and broad scope.

Facile Access to a Variety of 2,5-Biaryl-1,2,4-triazol-3-ones via Regioselective N-Arylation of Triazolones

  • Park, Ji-Yeon;Chae, Jung-Hyun
    • Bulletin of the Korean Chemical Society
    • /
    • 제31권8호
    • /
    • pp.2143-2146
    • /
    • 2010
  • A selective synthetic method of the 2,5-biaryltriazolones has been developed via copper-catalyzed N-arylation reaction. Aryltriazolones, which were readily prepared from commercially available compounds, were N-arylated to 2,5-biaryltriazolones with high regioselectivity. This approach allows for access to a variety of 2,5-biaryl-1,2,4-trizol-3-ones in a simple and practical manner.