• Journal of Astronomy and Space Sciences
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• v.25 no.3
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• pp.267-282
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• 2008

The GNSS (Global Navigation Satellite System) signal is delayed by the neutral atmosphere at the troposphere, so that the delay is one of major error sources for GNSS precise positioning. The tropospheric delay is an integrated refractive index along the path of GNSS signal. The refractive index is empirically related to standard meteorological variables, such as pressure, temperature and water vapor partial pressure, therefore the tropospheric delay could be calculated from them. In this paper, it is presented how to generate meteorological data where observation cannot be performed. KASI(Korea Astronomy & Space Science Institute) has operated 9 GPS (Global Positioning System) permanent stations equipped with co-located MET3A, which is a meteorological sensor. Meteorological data are generated from observations of MET3A by Ordinary Kriging. To compensate a blank of observation data, simple models which consider periodic characteristics for meteorological data, are employed.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.25 no.4
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• pp.81-96
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• 2020

Berthlot's reaction spectrophotometric method is generally used for the analysis of dissolved ammonium in seawater, but in recent years, a fluorescence method using an orthophthaldialdehyde-sulfite (OPA) fluorescent reagent is actively used internationally. In this study, we investigated the effects of the detection limit between the analysis methods, the reagent refractive index inherent in the spectrophotometric method, and the use of different calibration curves to understand the cause of the difference in dissolved ammonium concentration (about 0.31 𝜇M) observed in the seawater samples and a nutrient reference material between two institutions (KIOST (spectrophotometric method, one-order linear regression gradient only), Australia CSIRO (fluorescence method, quadratic formula)) conducted onboard the Australian R/V Investigator in 2017. The method detection limit (0.063 𝜇M) and the reagent refractive index background value (0.054 𝜇M) of the spectrophotometric method measured in this study could explain the difference in dissolved ammonium concentration values of the two institutes about 20% and 17%, respectively. However, when the concentration of the calibration curve of the spectrophotometric method was calculated using the same quadratic as the fluorescence method or the slope and intercept of linear regression, the difference in the dissolved ammonium concentration between the two institutions was reduced to less than the detection limit of the spectrophotometric method. Therefore, the difference in the concentration of dissolved ammonium between the two institutions, found in the nutrient reference materials and the seawater field sample during the international onboard nutrient inter-comparison experiment, may be attributed to be the effect of the different calibration curves used in the two methods rather than the effect of the difference in two analytical methods. When comparing the dissolved ammonium data from seawater samples in the future, it is recommended to pay attention to the information on the baseline, number of standard solutions, and calibration curve used in the analysis.