• Bulletin of the Korean Chemical Society
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• v.33 no.8
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• pp.2494-2498
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• 2012

Preparation of several new spirocyclic mercapto derivatives is described. Thiol protection on multi-carbonyl compounds allows of high sulfur content necessary to induce high refractive index. Condensation of 1,3-dimercapto-2-propanol and cyclohexanone followed by successive oxidation and thioacetalization affords a dispirocycle with four sulfurs. Selective S,S-protection of cyclohexane-1,4-dione is achieved with 1,3-dimercapto-2-propanol and 2,3-dimercapto-1-propanol to provide dispirocycles with four sulfurs. Olefine-oxidation of norbornene gives a useful dialdehyde intermediate which is transformed to 1,3-dithiolane for a linearly-bound-cyclic molecule. Refractive index of linearly-bound-cycles was below 1.60 and dispirocycles exhibited high refractive index of 1.57-1.69.

• Journal of the Korean Ceramic Society
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• v.46 no.1
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• pp.10-15
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• 2009

We have fabricated silicon-rich silica thin films via RF magnetron sputtering using a SiO target. Thickness evolution and microstructure change of such $SiO_x$ (1$SiO_x$ thin films turned out to be mainly responsible for the increase of refractive index.

• Korean Chemical Engineering Research
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• v.59 no.4
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• pp.644-651
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• 2021

Alkyl amines are widely used in various industries. Nowadays these are also used in CO₂ capture technology because amines react with CO₂ and remove it from the flue gas. To make the amines more compatible towards this technology, physico chemical properties may be altered by mixing with other solvents. In the present report, we measured the refractive properties of pure diisopropylamine (DIPA) (1) + isomeric butanol (2) at 298.15 K to 308.15 K. The 𝚫n values were positive for DIPA + n-butanol or sec-butanol or isobutanol or tert-butanol mixtures. The measured data was correlated with Redlich-Kister equation. The excess molar volume data were predicted from refractive index data using Nakata and Sakurai model. The experimental data were also predicted by various correlations, and the prediction capability of these correlations was reported through standard deviation. Further, the deviation in refractive index (𝚫n) data was interpreted by the consideration of specific molecular interactions between DIPA and isomeric butanol.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.11a
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• pp.120-123
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• 2002

In this study it had an excellent optical characteristic, it followed in the creation rate and the refractive index regulation to the ease. Chalcogenide produced the $As_{45}Se_{45}Te_{10}$ thin film and the $MgF_{2}$ thin film. It measured thin film plan simulation, and the thin film has a 1 -dimensional photonic band gap. The chalcogenide $As_{45}Se_{45}Te_{10}$ thin film was measured with the fact that it has a high refractive index (2.6~2.9). The $As_{45}Se_{45}Te_{10}$ and $MgF_{2}$ thin film, have a high refractive index and a low refractive index, it used a simulation and planed period 5-pairs structure, the result was from 500nm to 800nm. It will be able to confirm the characteristic which most of the incidence light reflects, the He-Ne (632.8nm) laser was irradiated in the thin film which stabilized the thin film. $As_{45}Se_{45}Te_{10}$ (high refractive index layer: H) and $MgF_{2}$ (low refractive index layer: L) results which plans the thin film with glass/LHLHLLHLHL/air structure, 632.8nm against transmitance, increased a lot. An application possibility with the filter against a specific wave length was confirmed.

• Journal of Korean Ophthalmic Optics Society
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• v.5 no.2
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• pp.151-155
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• 2000

We calculated a refractive index of the lens surface by measuring a spectral reflectance for a tinted time on manufacturing of the color lens. The longer a tinted time, the larger a reflectance and reflective index. The refractive index increased for a time up to the colorant's saturation state on the lens surface. The refractive index's change curve of blue color lens for a time depended on the Boltzmann growth curve. then we obtained the parameter's values of $n_{min}=1.482$, $n_{max}=1.497$, $t_c=11.53$ and $d_0=2.287$.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.29 no.3
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• pp.39-44
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• 2015

Optical characteristics including the radiant flux and viewing angle of UV LEDs were investigated according to both silicone encapsulants with different refractive indexes and lens shapes. Lead frame was fabricated using the enhanced heat dissipation characteristics with a heat slug structure and the reflector based on EMC(Epoxy Mold Compound) material. Four types of lens shapes were designed and their optical characteristics depending on the refractive index of silicone encapsulants were evaluated. The maximum radiant flux can be achieved when the height of lens are 1.32mm and 1.08mm for silicone encapsulants with low and high refractive indexes, respectively. Depending on the encapsulating method, the viewing angle changes from $148.9^{\circ}$ to $130.2^{\circ}$ for low refractive index and from $145.3^{\circ}$ to $136.8^{\circ}$ for high refractive index. As a result, it is found that the optical characteristics of UV LEDs can be controled through both encapsulating method and the refractive index of encapsulants.

• Polymer(Korea)
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• v.34 no.6
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• pp.588-593
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• 2010

New seven acrylic monomers with covalently bonded silicon, germanium, and tin were prepared for high refractive index materials. The monomers were copolymerized with a cross-linkable comonomer (Trimer) to prepare UV-films for optical characterization. The refractive index of the copolymers increased in proportion to the monomer content and extrapolated to determine that of homopolymer. $Ph_3Si$, $Ph_3Ge$, and $Ph_3Sn$ groups contributed to increase the refractive index of acrylic polymer, in which $Ph_3Sn$ was more effective than $Ph_3Ge$. The index increment confidently occurred with $Bu_3Sn$ attachment in comparison with aliphatic acrylic polymers. $Ph_3SnS$-attached acrylate polymer showed a refractive index of 1.671 at 589 nm. The index change was similarly observed at various different wavelengths (656, 830, 1310, and 1550 nm).

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.19 no.8
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• pp.599-606
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• 2007

An experimental study was performed to measure a ice concentration of ice slurry flowing in a pipe in a real time. In the present paper, we suggested a measuring method by a refractive index and compared it to other methods by a freezing point and a density. To measure the refractive index of the solution, ice particles in the ice slurry should be completely removed and a hydro-cyclone was introduced instead of a mesh. The measuring method through the refractive index coincided with the density method using the real-time solution density within ${\pm}5%$ error range, having the error range less than the other two methods. In the other hand, the measuring method through the density has a good resolution, but the result using the initial density of the solution was different more than 10% error from that using the real-time density. And it has an error range 1.5 times greater than the method through the refractive index.

• Polymer(Korea)
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• v.33 no.5
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• pp.413-419
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• 2009

As the refractive index of the prism layer becomes higher, the optical performance of the prism sheet gets better and the efficiency of the LCD backlight unit is improved. In order to increase the refractive index of the prism layer, the ultraviolet curing type resins were prepared by mixing high refractive index materials containing aromatic groups and the multi-functional reactive diluents. By using 9,9-bis [4-(2-acryloyloxyethoxy)phenyl] fluorene, the refractive index of the prism layer was increased up to 1.58 and the brightness of the backlight unit was improved. Since the light source used in the backlight unit caused the yellowing in the prism sheet and deteriorated the brightness accordingly, the hindered amine light stabilizer was used to improve the yellowing resistance successfully.

• Korean Journal of Optics and Photonics
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• v.7 no.4
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• pp.357-362
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• 1996

The thickness and the spectrum of the complex refractive index in the region 1.5~4.5 eV, of an MNA/PMMA thin film fabricated by spin casting are determined. The film thickness and the refractive index in its transparent region is calculated by modeling the spectroscopic ellipsometry data. The extinction coefficient spectrum is obtained from the absorption spectrum in its non-transparent region. The best fit oscillator parameters of the classical Lorentz oscillator and a quantum mechanical oscillator are found. The complex refractive index spectrum by these oscillators are compared. The present technique can be applied to get the thickness and the complex refractive index of unknown polymer films and thus it will be useful in optical characterization of those films.