• 제목/요약/키워드: Reference Electrode

검색결과 282건 처리시간 0.021초

Passive Films on Chromium Studied by Three-parameter Ellipsometry

  • 이경희;백운기
    • Bulletin of the Korean Chemical Society
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    • 제16권3호
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    • pp.214-216
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    • 1995
  • Passive films formed on chromium surface in citrate buffer solution were investigated by means of three-parameter ellipsometry. The citrate buffer was found to be a suitable medium in which oxide film on chromium could be removed by cathodic treatment, providing a reference surface for the optical study. The passive film effectively protecting the chromium surface from corrosion was found to have thicknesses in the range 0.65 to 1.25 nm depending on the potential in the range of -0.20 to 0.60 V (0.1M KCl calomel electrode). The complex refractive index of the passive film did not show significant potential-dependent changes, indicating that the composition of the film material does not depend on potential.

Identification of Partial Discharge Defects based on Back- Propagation Algorithm in Eco-friendly Insulation Gas

  • Sung-Wook Kim
    • Journal of information and communication convergence engineering
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    • 제21권3호
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    • pp.233-238
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    • 2023
  • This study presents a method for identifying partial discharge defects in an eco-friendly gas insulated system using a backpropagation algorithm. Four partial discharge (PD) electrode systems, namely, a free-moving particle, protrusion on the conductor, protrusion on the enclosure, and voids, were designed to simulate PD defects that can occur during the operation of eco-friendly gas-insulated switchgear. The PD signals were measured using an ultrahigh-frequency sensor as a nonconventional method based on IEC 62478. To identify the types of PD defects, the PD parameters of single PD pulses in the time and frequency domains and the phase-resolved partial discharge patterns were extracted, and a back-propagation algorithm in the artificial neural network was designed using a virtual instrument based on LabVIEW. The backpropagation algorithm proposed in this paper has an accuracy rate of over 90% for identifying the types of PD defects, and the result is expected to be used as a reference database for asset management and maintenance work for eco-friendly gas-insulated power equipment.

혈액 및 소변의 Lithium치 측정에 있어서 AAS법과 ISE법의 비교 (Comparison Study of AAS and ISE Method in the Lithium Analysis of Serum and Urine)

  • 이수인;이채훈;김경동;김정숙
    • Journal of Yeungnam Medical Science
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    • 제10권2호
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    • pp.409-416
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    • 1993
  • 이상에서와 같이 lithium치의 측정에 있어서 본 병원에서 기존 이용하던 AAS법이나 ISE법 모두 정밀도나 직선성 평가에 있어 비교적 좋았으나, 정밀도(재현성)에 있어서 ISE법이 AAS법보다 더 우수한 것으로 나왔고 ISE법의 경우 측정방법이 매우 간편하였다. 그러나 ISE법에 의한 혈중 측정치가 AAS법에 의한 것보다 다소 높게 나타났으며, ISE법이 AAS법에 비하여 분석 최하한치가 더 높아 예민도는 상대적으로 낮았다.

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시판되는 각종 음료수내 불소 함량과 소아의 불소섭취에 관한 연구 (A STUDY ON THE FLUORIDE CONTENT OF THE COMMERCIALLY AVAILABLE BEVERAGES AND THE FLUORIDE INTAKE OF CHILDREN)

  • 이미나;이상훈;김종철
    • 대한소아치과학회지
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    • 제24권1호
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    • pp.125-138
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    • 1997
  • Along with recent economic prosperity, the consumption of commercially available beverages has increased dramatically. Beverages on the market are replacing tap water and constituting an increasing large proportion of the total daily fluoride intake. If such changes in the source of fluid intake are not taken into consideration, effective fluoride intake would become difficult in the fluoridated area while there would be confusion as to the basis for proper fluoride supplement prescription in the nonfluoridated area. So, dietary consultation is recommended for every pediatric patient. This study was conducted to provide the reference for dietary consultations on the subject of fluoride supplement using 72 beverages on the market. The fluoride content was measured and the fluoride intake from each age groups was calculated using fluoride ion specific electrode and HMDS-microdiffusion technique. 1. The average fluoride concentration of the 72 beverages was $0.23{\pm}0.10ppm$, from 0.0106ppm to 2.2050ppm. 2. Natural fruit juices, diluted fruit juices, carbonated beverages and mixed beverages showed average fluoride concentration of $0.15{\pm}0.66ppm$, $0.09{\pm}0.11ppm$, $0.15{\pm}0.23ppm$, $0.50{\pm}0.66ppm$, respectively. There were significant differrence between diluted friut juice drinks and mixed beverage, and between the carbonated beverages and mixed beverges(p<0.05). 3. Using available data on the daily total consumption of beverages and the relative consumption of beverages on the market according to age, daily fluoride intake for various age groups was calculated. According to the results, 2 to 3 year-old children need 0.13mgF/day, those between 4 and 6 year-old need 0.15mgF/day, and those between 7 and 10 year-old need 0.17mgF/day.

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배전계통에 사용되는 콘크리트봉 접지전극의 과도 접지임피던스 특성 (Transient Grounding Impedance Characteristics of a Concrete Rod-type Grounding Electrode used for Electric Distribution Systems)

  • 김경철;김종욱;이규진;최종기;최선규;김동명
    • 조명전기설비학회논문지
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    • 제24권2호
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    • pp.9-15
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    • 2010
  • 접지시스템은 전기설비의 기준 전위점을 확보할 뿐만 아니라 대지에 낮은 저항으로 고장전류나 과도전류를 흐르게 한다. 주파수에 대한 함수로 접지 임피던스는 고장이나 과도전류가 넓은 범위의 주파수 성분을 포함하기 때문에 접지성능을 평가하는데 필요하다. 콘크리트봉은 배전계통에서 널리 쓰이는 접지전극중의 하나이다. 본 논문에서는 콘크리트봉의 접지 임피던스를 주파수 60[Hz]에서 100[kHz] 범위까지 측정하여 등가 접지임피던스 모델을 구하였다. 뇌서지가 유입되었을 때 EDSA 프로그램으로 과도접지임피던스의 수치와 파형을 시뮬레이션 하였다.

TheraBand를 이용한 견관절 외전시 삼각근과 극상근의 근전도 변화 (A Changes of Electromyogram Activities in Deltoideus and Supraspinatus During Shoulder Abduction Using TheraBand)

  • 박관용;이석민;이재구
    • 대한물리치료과학회지
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    • 제9권3호
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    • pp.77-87
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    • 2002
  • The purpose of this study was to compare the changes of muscle activities in deltoid with those in supraspinatus using electromyography(EMG) while subjects abducted their shoulder to different angles with different resistance. Methods : 20 volunteers who were comprised of 10 males(mean age: $21.2{\pm}2.0$) and 10 females(mean age: $20.2{\pm}1.6$) were collected. Surface electrodes were attached on deltoid and supraspinatus muscle for recording. Each reference electrode was located 3 cm to the each recording electrode. Muscle action potentials were recorded with changing the angle of shoulder abduction, $30^{\circ}$, $60^{\circ}$, $90^{\circ}$. This procedure was repeated with different resistance 0 pound, 2 pounds, 4.5pounds. The angle of shoulder abduction was determined by clinical goniometer. SPSS(Statistical Program for Social Science)/WIN 10.0 was used for statistics. Analysis included ANOVA, T-test. Results : The following results were obtained in this study. 1. There was significant differences during isometric shoulder abduction $30^{\circ}$, $60^{\circ}$, $90^{\circ}$ comparing muscle activity in deltoid and supraspinatus muscles at 0 pound, 2pound, 4.5pound resistance(p<0.05). 2. There was no useful significant in the deltoid and supraspinatus muscles activity EMG compared by physical condition. 3. Their was significant in the deltoid EMG compared by gender t=-5.41, P<0.01, but no difference in the supraspinatus EMG(P=0.333 >a=0.05). Conclusions: There are many previous studies on influence of shoulder angles and speeds of muscle activity. However most of them placed the focus on isotonic or isokinetic exercise, or shoulder function. But this study was done during isometric exercise, which is better for early assessment and treatment for injured patients. There is strong relationship between the shoulder angle with resistance in deltoid supraspinatus muscle activity. We conclude that it is important to apply isometric shoulder abduction exercise with correct angle and resistance especially in early stage.

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SnAgCu계 무연솔더의 전기화학적 반응에 따른 타펠 특성 (Tafel Characteristics by Electrochemical Reaction of SnAgCu Pb-Free Solder)

  • 홍원식;김광배
    • 한국재료학회지
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    • 제15권8호
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    • pp.536-542
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    • 2005
  • Recently European Council(EU) published the RoHS(restriction of the use of certain hazardous substances in electrical and electronic equipment) which is prohibit the use of Pb, Hg, Cd, $Cr^{+6}$, PBB or PBDE in the electrical and electronic equipments. So EU member States shall ensure that, from 1 July 2006, new electrical and electronic equipment put on the market does not contain 6 hazardous substances. The one of the most important in electronics manufacturing process is soldering. Soldering process use the chemical substances which are applied in fluxing and cleaning processes and it can generate the malfunction of electronics caused by corrosion in the fields conditions. Therefore this study researched on the polarization and Tafel properties of Sn40Pb and Sn3.0Ag0.5Cu(SAC) solder based on the electrochemical theory. We prepared SnPb specimens which was aged in $150^{\circ}C,\;180^{\circ}C$ for 15 minutes ana Sn3.0Ag0.5Cu specimens that was aged in $180^{\circ}C,\;220^{\circ}C$ for 10 minutes. Experimental polarization curves were measured in distilled ionized water and $3.5 wt\%$, 1 mole NaCl electrolyte of $40^{\circ}C$, pH 7.5. Ag/AgCl and graphite were utilized by reference and counter electrode, respectively. To observe the electrochemical reaction, polarization test was conducted from -250 mV to +250 mV. From the polarization curves that were composed of anodic and cathodic curves, we obtained Tafel slop, reversible electrode potential(Ecorr) and exchange current density(Icorr). In these results, corrosion rate for two specimen were compared Sn3.0Ag0.5Cu with SnPb solders

용융탄산염 연료전지의 분극현상 연구 (A Study on Polarization of the Molten Carvonate Fuel Cell)

  • 남석우;서상혁;임태훈;오인환;홍성안;임희천
    • 한국수소및신에너지학회논문집
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    • 제3권2호
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    • pp.55-62
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    • 1992
  • 본 연구에서는 용융탄산염 연료전지의 각 구성요소에서 발생하는 분극현상을 조사하였다. 기준 전극을 부착한 단위전지를 제작하고 전류단락법을 이용하여 전지의 내부저항에 의한 전압손실 및 그이외의 과전압을 측정하였다. $150mA/cm^2$의 전류밀도에서 anode의 과전압은 60mV이하였으나 cathode의 과전압은 130mV 정도로 크게 나타났으며, 전지의 내부저항에 의한 과전압도 170mV정도로커서 cathode의 성능 개선 빛 내부저항의 감소가 필요함을 알았다. 박막 모델을 사용하여 전극의 과전압을 실험치와 근접하게 예측할 수 있었으며, 전극 전해질 계면의 면적 및 전해질 박막의 두께를 조절하여 과전압이 최소가 되도록 전극의 구조를 조절하는 것이 매우 중요함을 알 수 있었다.

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마이크로 프로세서 기반 Lock-In-Amp를 이용한 텍스타일 직물전극의 체온 측정에 관한 연구 (A Study on Body Temperature Measurement of Woven Textile Electrode Using Lock-In-Amp based on Microprocessor)

  • 이강휘;이성수;이정환;송하영
    • 전기학회논문지
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    • 제66권7호
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    • pp.1141-1148
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    • 2017
  • Generally, a thermistor made by sintering a metal oxide is widely used to measure the ambient temperature. This thermistor is widely used not only for industrial use but also for medical use because of its excellent sensitivity, durability, temperature change characteristics and low cost. In particular, the normal body temperature is 36.9 degrees relative to the armpit temperature, and it is most closely related to the circulating blood flow. Previous studies have shown that body temperature changes during biomechanical changes and body temperature changes by anomalous signs or illnesses. Therefore, in this study, we propose a Lock-In-Amp design to detect minute temperature changes of clothing and thermistor wired by a preacher as a method to regularly measure body temperature in daily life. Especially, it is designed to measure the minute resistance change of the thermistor according to body temperature change even in a low-cost microprocessor environment by using a micro-processor-based Lock-In-Amp, and a jacquard and the thermistor is arranged so as to be close to the side, so that the reference body temperature can be easily measured. The temperature was measured and stored in real time using short-range wireless communication for non - restraint temperature monitoring. A baby vest was made to verify its performance through temperature experiments for infants. The measurement of infant body temperature through the existing skin sensor or thermometer has limitations in monitoring infant body temperature for a long time without restriction. However, it can be overcome by using the embroidery fabric based micro temperature monitoring wireless monitoring device proposed in this study.

Plasma nitriding on chromium electrodeposit

  • Wang Liang;K.S. Nam;Kim, D.;Kim, M.;S.C. Kwon
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2001년도 추계학술발표회 초록집
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    • pp.29-30
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    • 2001
  • This paper presents some results of plasma nitriding on hard chromium deposit. The substrates were C45 steel and $30~50{\;}\mu\textrm{m}$ of chromium deposit by electroplating was formed. Plasma nitriding was carried out in a plasma nitriding system with $95NH_3{\;}+{\;}SCH_4$ atmosphere at the pressure about 600 Pa and different temperature from $450^{\circ}C{\;}to{\;}720^{\circ}C$ for various time. Optical microscopy and X-ray diffraction were used to evaluate the characteristics of surface nitride layer formed by nitrogen diffusion from plasma atmosphere inward iCr coating and interface carbide layer formed by carbon diffusion from substrate outward Cr coating. The microhardness was measured using microhareness tester at the load of 100 gf. Corrosion resistance was evaluated using the potentiodynamic measurement in 3.5% NaG solution. A saturated calomel electrode (SiCE) was used as the reference electrode. Fig.1 shows the typical microstructures of top surface and cross-section for nitrided and unnitrided samples. Aaer plasma nitriding a sandwich structure was formed consisting of surface nitride layer, center chromium layer and interface carbide layer. The thickness of nitride and carbide layers was increased with the increase of processing temperature and time. Hardness reached about 1000Hv after nitriding while 900Hv for unnitrided hard chromium deposit. X-ray diffraction indicated that surface nitrided layer was a mixture of $Cr_2N$ and CrN at low temperature and erN at high temperature (Fig.2). Anodic polarization curves showed that plasma nitriding can greatly improve the corrosion resistance of chromium e1ectrodeposit. After plasma nitriding, the corrosion potential moved to noble direction and passive current density was lower by 1 to 4 orders of magnitude compared with chromium deposit(Fig.3).

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