• 한국정보과학회논문지:시스템및이론
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• 제32권11_12호
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• pp.692-704
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• 2005

컴퓨터 하드웨어의 급속한 발전으로 그래픽 프로세서 유닛(Graphics Processor Units : GPUs)은 굉장한 메모리 대역폭과 산술 능역을 보유하게 되어 범용 계산에 많이 활용되고 있으며, 특히 계산 집약적인 물리 기반 시뮬레이션(physics based simulation)의 GPU 구현이 활발하게 연구되고 있다. 물리 기반 시뮬레이션의 기본이 되는 미분방정식 풀이 과정에서 삼중대각행렬(tridiagonal matrix) 시스템은 유한차분(finite-difference) 근사에 의해서 자주 나타나는 선형시스템으로 물리 기반 시뮬레이션 관점에서 삼중대각행렬 시스템의 빠른 풀이는 중요한 연구 분야이다. 본 논문에서는 GPU에서 삼중대각행렬 시스템 풀이를 빠르게 구현할 수 있는 방법을 제안한다. 벡터 프로세서(vector processor) 계산에서 삼중대각행렬 시스템 풀이 방법으로 널리 사용되는 cyclic reduction 또는 odd-even reduction 알고리즘을 GPU에서 구현하였다. 본 논문에서 제안한 방법을 삼중대각행렬 시스템 풀이 방법으로 잘 알려져 있는 Thomas 방법과 GPU를 이용한 선형시스템 풀이에서 좋은 성과를 보이고 있는 conjugate gradient 방법과 비교할 때 상당한 성능 향상을 얻을 수 있었다. 또한, 열전도(heat conduction) 방정식, 이류 확산(advection-diffusion) 방정식, 얕은 물(shallow water) 방정식에 의한 물리 기반 시뮬레이션의 GPU 구현에 본 논문에서 제안한 방법을 사용하여 1024x1024 격자의 계산 영역에서 초당 35프레임 이상의 놀라운 성능을 보여주었다.

• STI Policy Review
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• 제4권1호
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• pp.1-13
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• 2013

The Schumpeterian process of "creative destruction", associated with the emergence and diffusion of new radical, so-called "general purpose" technologies, has throughout history impacted wealth and income, jobs creation, jobs displacement, and the emergence and submergence of new hotspots of innovation. Emerging countries have benefited most from such a renewing of those societies' dynamics, leading them to higher levels of economic development and welfare. Doing so they have shown a remarkable capacity in moving upstream in the value chain, from outsourcing of manufacturing activities to autonomous process technology development, product development, design, and applied research. At the same time however, such Schumpeterian processes have now and then turned into exactly opposite processes of "destructive creation." Such processes seem to have become common among what could be called "submerging" economies: innovation only benefitting a few at the expense of many with as a result an opposite pattern of a long term reduction in overall welfare, productivity, and employment growth.

• 대한화학회지
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• 제37권8호
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• pp.735-743
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• 1993

Cofacial bis-cobalt tetraphenylporphyrin(Co-TPP) 유도체 화합물들이 수식된 유리질 탄소 전극과 carbon microelectrode을 작업 전극으로 사용하여 여러가지 pH 용액에서 순환 전압전류법 및 시간 전류법에 의해 산소의 환원반응을 조사하였다. 산성용액에서 monomer인 cobalt tetraphenylporphyrin 화합물이 수식된 전극에서 산소의 환원반응경로는 중간 생성물인 H$_2$O$_2$로 가는 2전자 반응으로, dimer인 cofacial bis-cobalt tetraphenylporphyrin 유도체 화합물들이 수식된 전극에서는 최종 생성물인 H$_2$O로 가는 4전자 반응으로 진행되었다. 이와 같은 산소의 환원반응은 전체적으로 비가역적이며 확산지배적인 반응으로 주어졌다. pH 변화에 따른 산소의 환원전위는 pH 13에서 pH 4 까지는 직선관계가 성립하였으나 강한 산성용액에서는 이들 관계가 성립하지 않았다. 산성용액에서 산소의 환원전위는 알몸 유리질 탄소전극에서 보다 monomer Co-TPP 화합물이 수식된 유리질 탄소전극에서는 400 mV만큼, dimer Co-TPP 화합물이 수식된 전극에서는 750 mV 만큼 더 양전위 방향으로 이동되었다.

• 분석과학
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• 제15권2호
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• pp.97-101
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• 2002

Co(II)착물들을 세자리 Schiff base-NOIPH, 네자리 Schiff base-$NOTDH_2$ 및 $TNBPH_4$ 로부터 합성하였으며, 이 착물들의 산화-환원 과정 mecanism을 지지 전해질로서 0.1 M TBAP를 포함한 DMF용액에서 작업전극으로 유리질 탄소전극을 사용하여 순환 전압-전류법과 펄스 차이 전압-전류법에 의해서 알아 보았다. [Co(II)$(NOIP)_2$]와 [Co(II)(NOTD)$(H_2O)_2$] 착물의 환원은 Co(III)/Co(II)의 반응이 비가역적으로 진행되고 Co(II)/Co(I)의 반응이 준가역적으로 진행되는 일전자의 2단계반응이 확산 지배적으로 일어났다. 반면에 [$Co(II)_2$(TNBP)] 착물의 환원반응은 $Co(II)_2$가 Co(II)/Co(I)로 진행되는 준가역적이며 일전자 일단계의 반응이 확산지배적으로 일어났다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.286-287
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• 2012

Reset-first resistive switching mechanism based on reduction reaction in HfO2-x with oxygen drift-diffusion was studied. we first report that the indirect evidence of local filamentary conductive path formation in bulk HfO2 film with local TiOx region at Ti top electrode formed during forming process and presence of anion-migration at interface between electrode and HfO2 during resistive switching through high resolution transmission electron microscopy (HRTEM), electron disperse x-ray (EDX), and electron energy loss spectroscopy (EELS) mapping. Based on forming process mechanism, we expected that redox reaction from Ti/HfO2 to TiOx/HfO2-x was responsible for an increase of initial current with increasing the post-annealing process. First-reset resistive switching in above $350^{\circ}C$ annealed Ti/HfO2 film was exhibited and the redox phenomenon from Ti/HfO2 to TiOx/HfO2-x was observed with high angle annular dark field (HAADF) - scanning transmission electron microscopy (STEM), EDX and x-ray photoelectron spectroscopy. Therefore, we demonstrated that the migration of oxygen ions at interface region under external electrical bias contributed to bipolar resistive switching behavior.

• Bulletin of the Korean Chemical Society
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• 제25권5호
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• pp.715-720
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• 2004

Amineterminated, ethylenediamine core polyamidoamine starburst dendrimers of generation 2 (G2), generation 4 (G4) and generation 6 (G6) have been successfully surface-modified via an amide coupling reaction with 4-ethyl, 4'-(3-propionic) bipyridinium cation and the electrochemical behavior of the resulting dendrimers were investigated in aqueous potassium chloride electrolyte solutions. The 1-[3-(dimethylamino)propyl]-3-ethylcarbodiimide hydrochloride/N-hydroxysuccinimide-mediated reaction resulted in 25-39% end-group functionalization. The water-soluble 4-ethyl, 4'-(3-propylamide) bipyridinium dibromide dendrimers (G2-V2+, G4-V2+ and G6-V2+) were characterized by $^1H$ NMR and UV-Vis spectroscopic methods. The cyclic voltammetric and chronoamperometric experiments were performed to determine the diffusion coefficient and the number of electrons transferred in the process of the first reduction of the viologen-functionalized dendrimers. Adsorption of viologen-functionalized dendrimers at electrode surface was evidenced in the voltammograms. Experimentally determined diffusion coefficients were in good agreement with the values expected from the Stokes-Einstein relation, while the number of electrons transferred concurred with the extent of functionalization determined by $^1H$ NMR and UV-Vis spectra.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2013년도 자성 및 자성재료 국제학술대회
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• pp.89-89
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• 2013

Rare earth (RE) - transition metal based high energy density magnets are of immense significance in various engineering applications. $Nd_2Fe_{14}B$ magnets possess the highest energy product and are widely used in whole industries. Simultaneously, composite alloys that are cheap, cost effective and strong commercially available have drawn great attention, because rare-earth metals are costly, less abundant and strategic shortage. We designed rare-earth free alloys and fabrication process and developed novel route to prepare $Nd_2Fe_{14}B$ powders by wet process employing spray drying and reduction-diffusion (R-D) without the use of high purity metals as raw material. MnAl-base permanent magnetic powders are potentially important material for rare-earth free magnets. We have prepared the nano-sized MnAl powders by plasma arc discharge and micron-sized MnAl powders by gas atomization. They showed good magnetic property, compared with that from conventional processes. $Nd_2Fe_{14}B$ powders with high coercivity of more than 10 kOe were successfully synthesized by adjusting R-D step, followed by precise washing system. It is considered that this process can be applied for the recycling of RE-elements extracted from ewaste including motors.

• 대한금속재료학회지
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• 제46권5호
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• pp.296-303
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• 2008

Hydrogen permeation through dense palladium-based membranes has attracted the attention of many scientists largely due to their unmatched potential as hydrogen-selective membranes for membrane reactor applications. Although it is well known that the permeation mechanism of hydrogen through Pd involves various processes such as dissociative adsorption, transitions to and from the bulk Pd, diffusion within Pd, and recombinative desorption, it is still unclear which process mainly limits hydrogen permeation at a given temperature and hydrogen partial pressure. In this study, we report an all-electron density-functional theory study of hydrogen permeation through Pd membrane (using VASP code). Especially, we focus on the variation of the energy barrier of the penetration process from the surface to the bulk with hydrogen coverage, which means the large reduction of the fracture stress in the brittle crack propagation considering Griffith's criterion. It is also found that the penetration energy barrier from the surface to the bulk largely decreases so that it almost vanishes at the coverage 1.25, which means that the penetration process cannot be the rate determining process.

• 대한화학회지
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• 제37권4호
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• pp.462-469
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• 1993

Cofacial bis-cobalt tetraphenylporphyrin 유도체 화합물들이 수식된 유리질 탄소 전극과 microelectrode에서 순환 전압 전류법 및 시간 전류법에 의해 산소의 환원 반응을 조사하였다. Microelectrode를 사용하여 시간-전류법에 의해 얻은 전자수 n값들은 유리질 탄소 전극을 사용하여 순환 전압 전류법들에 의해 얻은 결과들과 다소 다른 값으로 나타났다. 알카리성 용액에서 monomer인 cobalt tetraphenylporphyrin 화합물이 수식된 전극에서 산소의 호나원 반응 경로는 중간 생성물인 $H_2O_2$로 가는 2 전자반응으로 진행되었고, dimer인 cofacial bis-cobalt tetraphenylporphyrin 유도체 화합물들이 수식된 전극에서는 최종 생성물인 $H_2O$로 가는 4 전자 반응으로 진행되었다. 이와 같은 산소의 환원 반응은 전체적으로 비가역적으로 확산 지배적인 반응으로 주어졌다.

• 지질공학
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• 제29권4호
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• pp.367-381
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• 2019

We investigate pore pressure conditions and reservoir compaction associated with oil and gas production using 3 different permeability models, which are all based on one-dimensional radial flow diffusion model, but differ in considering permeability evolution during production. Model 1 assumes the most simplistic constant and invariable permeability regardless of production; Model 2 considers permeability reduction associated with reservoir compaction only due to pore pressure drawdown during production; Model 3 also considers permeability reduction but due to the effects of both pore pressure drawdown and coupled pore pressure-stress process. We first derive a unified stress-permeability relation that can be used for various sandstones. We then apply this equation to calculate pore pressure and permeability changes in the reservoir due to fluid extraction using the three permeability models. All the three models yield pore pressure profiles in the form of pressure funnel with different amounts of drawdown. Model 1, assuming constant permeability, obviously predicts the least amount of drawdown with pore pressure condition highest among the three models investigated. Model 2 estimates the largest amount of drawdown and lowest pore pressure condition. Model 3 shows slightly higher pore pressure condition than Model 2 because stress-pore pressure coupling process reduces the effective stress increase due to pore pressure depletion. We compare field data of production rate with the results of the three models. While models 1 and 2 respectively overestimates and underestimates the production rate, Model 3 estimates the field data fairly well. Our result affirms that coupling process between stress and pore pressure occurs during production, and that it is important to incorporate the coupling process in the permeability modeling, especially for tight reservoir having low permeability.