• 제목/요약/키워드: Reduction-diffusion process

검색결과 143건 처리시간 0.023초

실리콘-게르마늄 이종접합 바이폴라 트랜지스터의 신뢰성 현상 (The reliability physics of SiGe hetero-junction bipolar transistors)

  • 이승윤;박찬우;김상훈;이상흥;강진영;조경익
    • 한국진공학회지
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    • 제12권4호
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    • pp.239-250
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    • 2003
  • 실리콘-게르마늄 이종접합 바이폴라 트랜지스터 (SiGe HBT)에서 발생하는 신뢰성 열화 현상을 고찰하였다. SiGe HBT의 경우에 전류이득 감소, AC특성 저하, 오프셋 전압이 자주 관찰되는데 그 원인으로는 각각 에미터-베이스 역 바이어스 전압 스트레스, 과도촉진확산 (transient enhanced diffusion), 공정 변동 (fluctuation)에 따른 베이스-콜렉터 접합 특성 저하를 들 수 있다. 에미터-베이스 접합에 역 바이어스 전압 스트레스가 걸리면 에미터-베이스 접합면의 테두리 부분에서 높은 에너지를 가지는 전자와 정공들이 생성되고, 이들 전자와 정공들이 실리콘-산화막 계면 및 산화막 내부에 전하를 띈 트랩을 생성하기 때문에 재결합에 의한 베이스 누설전류가 증가하여 소자의 전류이득은 크게 감소하게 된다. 에미터-베이스 접합과 외부 베이스의 거리가 임계 값보다 짧을 때에는 소자의 차단주파수($f_t$)가 감소하게 되는데 이것은 외부 베이스 이온주입에 의하여 내부 베이스 내의 도펀트의 확산이 촉진되어 나타나는 현상이다. 외부 베이스 이온주입 에너지가 충분하지 않은 경우에는 콜렉터-베이스 접합의 턴온 전압이 감소하여 전류-전압 특성 곡선에서 오프셋 전압이 발생하게 된다.

Removal of Organic Wax and Particles on Final Polished Wafer by Ozonated DI Water

  • Yi, Jae-Hwan;Lee, Seung-Ho;Kim, Tae-Gon;Lee, Gun-Ho;Choi, Eun-Suck;Park, Jin-Goo
    • 한국재료학회지
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    • 제18권6호
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    • pp.307-312
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    • 2008
  • In this study, a new cleaning process with a low cost of ownership (CoO) was developed with ozonated DI water ($DIO_3$). An ozone concentration of 40 ppm at room temperature was used to remove organic wax film and particles. Wax residues thicker than $200\;{\AA}$ remained after only a commercial dewaxer treatment. A $DIO_3$ treatment in place of a dewaxer showed a low removal rate on a thick wax layer of $8000\;{\AA}$ due to the diffusion-limited reaction of ozone. A dewaxer was combined with a $DIO_3$ rinse to reduce the wax removal time and remove wax residue completely. Replacing DI rinse with the $DIO_3$ rinse resulted in a surface with a contact angle of less than $5^{\circ}$, which indicates no further cleaning steps would be required. The particle removal efficiency (PRE) was further improved by combining a SC-1 cleaning step with the $DIO_3$ rinsing process. A reduction in the process time was obtained by introducing $DIO_3$ cleaning with a dewaxing process.

탄산화 및 동결융해 현상이 콘크리트 중의 염소이온 확산에 미치는 영향 연구 (Influence of Carbonation and Freezing-thawing on the Chloride Diffusion in Concrete)

  • 김동백;권기준;정상화;복훈
    • 한국안전학회지
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    • 제22권3호
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    • pp.57-64
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    • 2007
  • Recently, the corrosion of concrete structures has received great attention related with the deterioration of sea-side structures, such as new airport, bridges, and nuclear power plants. In this regards, many studies have been done on the chloride attack in concrete structures. However, those studies were confined mostly to the single deterioration due to chloride only, although actual environment is rather of combined type. The purpose of the present study is, therefore, to explore the influences of carbonation and freezing-thawing action to chloride attack in concrete structures. The test results indicate that the chloride penetration is more pronounced than the case of single chloride attack when the carbonation process is combined with the chloride attack. It is supposed that the chloride ion concentration of carbonation region is higher than the sound region because of the separation of fixed salts. Though the use of fly ash pronounces the chloride ion concentration in surface, amounts of chloride ion penetration into deep region decreases with the use of fly ash. The small reduction of relative dynamic elastic modulus induced from freezing-thawing increases the chloride ion penetration depths much. The present study allows more realistic assessment of durability for such concrete structures which are subjected to combined attacks of both chlorides and carbonation or freezing-thawing but the future studies for combined environment will assure the precise assessment.

물류보안 인증을 위한 정부지원 방안 연구 (A Study on Government Support for Logistics Security)

  • 이돈희
    • 한국산업정보학회논문지
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    • 제21권6호
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    • pp.109-123
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    • 2016
  • 본 연구는 물류보안 인증 획득 기업 및 인증 준비단계에 있는 기업을 위한 정부지원 정책 방안을 도출하고자 기업의 요구사항을 파악하고, 우선순위를 분석하기 위하여 AHP와 QFD 기법을 적용하였다. 분석결과, 물류보안 인증 확산을 위한 기업의 요구사항에 대한 우선순위는 물류보안통합시스템(40.3%), 정부지원체계 강화(32.4%), 인증제도의 운영효과(27.2%) 순위로 분석되었다. AHP 분석 결과를 토대로 QFD 기법을 적용한 상대적 가중치 분석결과에서는 생산성 향상(28.38%), 서비스 수준향상(26.70%), 물류비용 절감(21.60%), 정보기술 선진화(19.68%), 환경보호(3.64%) 등의 순위로 나타났다. 본 연구결과는 물류보안 인증 획득 및 유지관리 개선을 하고자 하는 공급망 내 관련 기업뿐만 아니라 다른 기업들에게 물류보안에 관한 가이드라인을 제공해 줄 수 있으며, 기업경쟁력을 강화시키고 글로벌 시장에서 경쟁우위 기업으로 성장할 수 있는 발전 도모에 활용될 수 있다.

2024 Al 합금의 고온 정상크리이프 중의 내부응력의 탄성 및 회복에 관한 연구 (Internal Stress, Anelasticity and Recovery in Steady State Creep of 2024 Al Alloy at High Temperature)

  • 박경동;오세욱;강상훈
    • 대한기계학회논문집
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    • 제10권3호
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    • pp.292-297
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    • 1986
  • 본 연구에서는 2024 Al 합금에 대하여 260-380.deg. C의 온도 범위 및 2~5kgf/ m $m^{2}$의 부과응력 범위에서 실시한 고온 정상 크리이프 변형 중의 내부응력 .sigma. $_{i}$,의탄성 변형 .epsilon.$_{A}$ 및 회복율 r의 측정 실험을 통하여 이들 상호간의 관계 를 살펴 보고자 한다.다.다.

PLASTICITY-BASED WELDING DISTORTION ANALYSIS OF THIN PLATE CONNECTIONS

  • Jung, Gonghyun;Tsai, Chon L.
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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    • pp.694-699
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    • 2002
  • In autobody assembly, thin-wall, tubular connections have been used for the frame structure. Recent interest in light materials, such as aluminum or magnesium alloys, has been rapidly growing for weight reduction and fuel efficiency. Due to higher thermal expansion coefficient, low stiffness/strength, and low softening temperature of aluminum and magnesium alloys, control of welding-induced distortion in these connections becomes a critical issue. In this study, the material sensitivity to welding distortion was investigated using a T-tubular connection of three types materials; low carbon steel (A500 Gr. A), aluminum alloy (5456-H116) and magnesium alloy (AZ91C-T6). An uncoupled thermal and mechanical finite element analysis scheme using the ABAQUS software program was developed to model and simulate the welding process, welding procedure and material behaviors. The predicted angular distortions were correlated to the cumulative plastic strains. A unique relationship between distortion and plastic strains exists for all three materials studied. The amount of distortion is proportional to the magnitude and distribution of the cumulative plastic strains in the weldment. The magnesium alloy has the highest distortion sensitivity, followed by the other two materials with the steel connection having the least distortion. Results from studies of thin-aluminum plates show that welding distortion can be minimized by reducing the cumulative plastic strains by preventing heat diffusion into the base metal using a strong heat sink placed directly beneath the weld. A rapid cooling method is recommended to reduce welding distortion of magnesium tubular connections.

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Structural and Magnetic Properties of Fe50Cr50 Alloys Prepared by Mechanical Alloying Method

  • Yang, Dong-Seok;Park, Ji-Yeon;Yoo, Yong-Goo;Kim, Kyeong-Sup;Yu, Seong-Cho
    • Journal of Magnetics
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    • 제15권3호
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    • pp.108-111
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    • 2010
  • Fe50Cr50 metastable alloys were prepared by the mechanical alloying method with milling periods of 1, 2, 4, 6, 12 and 24 hours, respectively. The structural evolution was analyzed by the extended x-ray absorption fine structure (EXAFS). In this work, the EXAFS analysis provided the local structural information around Fe central atom. The saturation magnetization was also measured by VSM. The magnetization decreased as the process mechanical alloying progressed. The magnetic property was related to the local structural variation as a function of processing time. The analysis showed that the diffusion Cr atoms into Fe clusters caused the reduction of magnetization. EXAFS analysis exhibited that the local ordering of magnetic atoms caused the magnetic ordering. Also, EXAFS analysis showed that the long range order of Fe atoms was destroyed completely in 24 hour milling.

미분탄 입자들의 배열이 미분탄 연소에 미치는 영향 (Effects of Coal Particle Array on Coal Combustion)

  • 조종표;김호영;정진택
    • 대한기계학회논문집B
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    • 제29권12호
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    • pp.1321-1328
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    • 2005
  • The burning characteristics of interacting coal particles in a convective flow are numerically investigated at various Reynolds numbers. The transient combustion of 2-dimensionally arranged particles, both the fixed particle distances of 5 radii to 20 radii horizontally and 4 radii to 24 radii vertically, is studied. The results obtained from the present numerical analysis indicate that the transient flame configuration and retardation of particle temperature augmentation with the horizontal or vertical particle spacing substantially influence devolatilization process and carbon conversion ratio of interacting particles. Volatile release and carbon conversion ratio of the second particle with decreasing horizontal and vertical particle spacing decrease gradually, whereas those of the first particle with decreasing vertical particle spacing increase due to flow acceleration. When the vertical particle spacing is smaller than $6R_0$, volatile release and carbon conversion ratio of the second particle decrease due to reduction of flame penetration depth and interference of oxygen diffusion by the first particle.

초미세 결정립을 가지는 몰리브덴의 제조 및 기계적 특성 (Fabrication of Ultra Fine Grained Molybdenum and Mechanical Properties)

  • 김세훈;서영익;김대건;석명진;김영도
    • 한국분말재료학회지
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    • 제17권3호
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    • pp.235-241
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    • 2010
  • Mo nanopowder was synthesized by ball-milling and subsequent hydrogen-reduction of $MoO_3$ powder. To fabricate ultra fine grained molybdenum, two-step sintering and spark plasma sintering process were employed. The grain size of specimen by two-step sintering and spark plasma sintering was around $0.6\;{\mu}m$ and $0.4\;{\mu}m$, respectively. Mechanical properties of ultra fine grained Mo with relative density of above 90% were significantly improved at room and high temperatures comparing to commercial bulk Mo of 99% relative density. This result was mainly explained by the grain size refinement due to diffusion-controlled sintering.

Electrochemical dehalogenation of disinfection by-products and iodine-containing contrast media: A review

  • Korshin, Gregory;Yan, Mingquan
    • Environmental Engineering Research
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    • 제23권4호
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    • pp.345-353
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    • 2018
  • This paper summarizes results of research on the electrochemical (EC) degradation of disinfection by-products (DBPs) and iodine-containing contrast media (ICMs), with the focus on EC reductive dehalogenation. The efficiency of EC dehalogenation of DBPs increases with the number of halogen atoms in an individual DBP species. EC reductive cleavage of bromine from parent DBPs is faster than that of chlorine. EC data and quantum chemical modeling indicate that the EC reduction of iodine-containing DBPs (I-DBPs) is characterized by the formation of active iodine that reacts with the organic substrate. The occurrence of ICMs has attracted attention due to their association with the generation of I-DBPs. Indirect EC oxidation of ICMs using anodes that produce reactive oxygen species can result in a complete degradation of these compounds yet I-DBPs are formed in the process. Reductive EC deiodination of ICMs is rapid and its overall rate is diffusion-controlled yet I-DBPs are also produced in this reaction. Further progress in practically feasible EC methods to remove DBPs, ICMs and other trace-level organic contaminants requires the development of novel electrocatalytic materials, elimination of mass transfer limitations via innovative design of 3D electrodes and EC reactors, and further progress in the understanding of intrinsic mechanisms of EC reactions of DBPs and TrOC at EC interfaces.