• Title/Summary/Keyword: Reduction-diffusion method

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Fabrication of Antibacterial Biodegradable films Using a Radiation-induced Reduction Method

  • Jung, Chan-Hee;Cho, Yong-Jun;Jung, Jin-Mook;Hwang, In-Tae
    • Journal of Radiation Industry
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    • v.7 no.2_3
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    • pp.141-147
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    • 2013
  • The simple and facile radiation technique of the preparation of antibacterial biodegradable polymer films containing silver nanoparticles (Ag NPs) was described. The biodegradable poly(butylene adipate-co-terephthalate) (PBAT) films containing silver trifluoroacetate (Ag TFA) were prepared by a solvent casting method, and then the films were irradiated by electron beams at the various doses ranging from 20 to 200 kGy to form Ag NPs in the biodegradable polymers. The results of UV-vis and FE-SEM/EDX analyses revealed that the Ag NPs were successfully formed in the PBAT matrix during the electron beam irradiation, and their amounts were dependant on the absorbed dose and Ag TFA concentrations. Furthermore, on the basis of the results of the antibacterial test through disk diffusion and colony counting test, the irradiated PBAT/Ag TFA films exhibited the antibacterial property due to the formation of Ag NPs.

Estimation of Suspended Solids Concentration Caused by Stream Bed Excavation Works through the Application of the Fickian Diffusion Model (Fick 확산 모형을 이용한 하상 굴착 공사로부터의 부유물질 농도 산정)

  • An, Myeong-Gil
    • Journal of Korea Water Resources Association
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    • v.30 no.6
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    • pp.621-628
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    • 1997
  • Excavation works on stream beds have been done for various reasons including aggregate collection, sediment dredging, bridge constructions, or laying pipes under the ground. These activities may cause significant loadings of SS (suspended solids) resulting in water pollution and other detrimental effects to the surrounding environment. This research investigates application potential of a fickian diffustion model, derived from two dimensional advection-diffusion equation through some simplifying assumptions, as a planning tool for the estimation of SS loadings from excavation works and evaluation fo pollution prevention measures in case that sophisticated numerical simulation models are not applicable due to various practical reasons. Through a case study of the Juncheon stream in the Donghae City on the Kangwondo Province, this study demonstrates applicability of the fickian diffustion model as a practical method for the preliminary estimation of Ss loadings from excavation works and evaluation of performance of fabrics made of synthetic fiber for the reduction of downstream SS concentration with deficient field data.

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Analysis of Chloride ion Penetration of Marine Concrete Structure (해양 콘크리트 구조물의 염소이온 침투해석)

  • 한상훈;박우선;김동현
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.15 no.2
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    • pp.71-79
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    • 2003
  • The estimation functions were proposed for calculating diffusion coefficient, chloride binding, and evaporable water. The program estimating chloride ion penetration was developed on the basis of these functions and the effects of humidity, curing temperature, water-cement ratio, and $C_3$A on chloride penetration were analyzed. The relative humidity increases the depth of chloride ion penetration and the trend becomes greater with aging. On the contrary, the influence of curing temperature on chloride ion penetration decreases with aging. By the way, the rise of $C_3$A in cement increases total chloride concentration on the surface as the bound chloride concentration increases but it decreases total chloride concentration on the inner part as the diffusion velocity of free chloride decreases. The fall of water-cement ratio decreases the chloride penetration depth rapidly. Therefore, the reduction of water-cement ratio may be the most effective method for reducing of the steel corrosion by chloride penetration.

Anti-Porcine Epidemic Diarrhea Virus (PEDV) Activity and Antimicrobial Activities of Artemisia dubia Essential Oil (참쑥(Artemisia dubia) 오일의 돼지 유행성 설사 바이러스(Porcine Epidemic Diarrhea Virus)에 대한 항바이러스 항균활성)

  • Kim, Jong-Im
    • Microbiology and Biotechnology Letters
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    • v.40 no.4
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    • pp.396-402
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    • 2012
  • The chemical composition, anti-porcine epidemic diarrhea virus (PEDV) activity and antimicrobial activity of Artemisia dubia essential oil were evaluated in this study. Fifty eight compounds from A. dubia essential oil were identified through analysis by gas chromatography-mass spectrometry (GC-MS). The major constituents of the oil were camphor (17.18 %), germacrene-D (15.70%), trans (${\beta}-$) racaryophyllene (6.79%), ene thujones (6.57%), 1, 8-cineole (5.94%) and camphene (5.08%). The essential oil was evaluated for antiviral activity against PEDV in Vero cells using a cytopathic effect (CPE) reduction method. The oils actively inhibited PEDV replication with a 50% inhibitory concentration ($IC_{50}$) of 43.7 ${\mu}^3/mL$. The 50% cytotoxicity concentration ($CC_{50}$) of the oils was over 100 ${\mu}/mL$ and the derived therapeutic index was >2.3. Similar analysis of the ribavirin revealed that they have a relatively weaker efficacy when compared to the oils. The antimicrobial activity of the essential oil against 5 microorganisms was evaluated by the disc diffusion method. The essential oil exhibited antimicrobial activity against 5 tested microorganisms with a clear zone of 8-22 mm. Among the tested microorganisms, Streptococcus pyogenes was the most sensitive and Candida albicans the least. Therefore, in can be concluded that essential oils of A. dubia may have interesting applications for microbial control or the control of PEDV-derived diseases.

Overexpression, Purification, and Preliminary X-Ray Crystallographic Studies of Methionine Sulfoxide Reductase B from Bacillus subtilis

  • Park, Ae-Kyung;Shin, Youn-Jae;Moon, Jin-Ho;Kim, Young-Kwan;Hwang, Kwang-Yeon;Chi, Young-Min
    • Journal of Microbiology and Biotechnology
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    • v.18 no.1
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    • pp.59-62
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    • 2008
  • The peptide methionine sulfoxide reductases (Msrs) are enzymes that catalyze the reduction of methionine sulfoxide back to methionine. Because of two enantiomers of methionine sulfoxide (S and R forms), this reduction reaction is carried out by two structurally unrelated classes of enzymes, MsrA (E.C. 1.8.4.11) and MsrB (E.C. 1.8.4.12). Whereas MsrA has been well characterized structurally and functionally, little information on MsrB is available. The recombinant MsrB from Bacillus subtilis has been purified and crystallized by the hanging-drop vapor-diffusion method, and the functional and structural features of MsrB have been elucidated. The crystals belong to the trigonal space group P3, with unit-cell parameters a=b=136.096, $c=61.918{\AA}$, and diffracted to $2.5{\AA}$ resolution using a synchrotron-radiation source at Pohang Light Source. The asymmetric unit contains six subunits of MsrB with a crystal volume per protein mass $(V_M)\;of\;3.37{\AA}^3\;Da^{-1}$ and a solvent content of 63.5%.

Contrast enhancement of color images using modified error diffusion (변형된 오차확산을 이용한 컬러 영상의 콘트라스트 개선)

  • Lee, Ji-Won;Park, Rae-Hong
    • Journal of Broadcast Engineering
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    • v.13 no.5
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    • pp.651-661
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    • 2008
  • This paper proposes a novel contrast enhancement (CE) algorithm for color images using the modified error diffusion (ED). After conventional color histogram equalization (HE), artifacts such as false contours are produced in the contrast enhanced image. The proposed CE algorithm using the modified ED consists of two parts: CE and ED. In the first part, a low-contrast input image is enhanced by the conventional HE method. In the second part, we use the modified ED algorithm. The inputs of the second part are the average and scaled difference images of the original color input image and the HE image, in which the scaled color difference image is diffused by the ED algorithm. In the proposed algorithm, the modified ED algorithm reduces the artifacts produced in the HE image, and increases the number of color levels. Computer simulations with a number of low-contrast color images show the effectiveness of the proposed CE method in terms of the visual quality as well as the probability mass function. It can be used as a post-processing for CE with simultaneous artifact reduction in various display devices.

The Effect of Heat Loss on the Radial Heat Flow in the Flash Method (반경방향 열흐름 섬광법에서 열손실의 영향)

  • 이홍주;김순규
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.2
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    • pp.257-264
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    • 1989
  • For the extension of the flash method the heat diffusion equation with heat loss and with an arbitrary heat pulse is mathematically analyzed. In the analysis the heat loss includes the axial and radial directions on the front, rear and peripheral surfaces. The heat pulse is irradiated from the source to the front surface of the sample and the heat receiving area on the front surface is controlled by the apertures of an optical system. From this analysis the thermal diffusivity of the samples can be determined more precisely than before by the data reduction method using various percent time. The data can be obtained by the extended radial flash technique adjusted correctly the heating area on the central part of the front surface with a proper aperture or the conventional axial flash technique heated uniformly all parts of the front surface.

Anormal Dielectric and Insulation Properties of Semiconductor/XLPE (반도전층/XLPE 의 불규칙한 유전 및 절연 특성)

  • Lee, Jong-Chan;Kim, Kwang-Soo;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05c
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    • pp.53-57
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    • 2002
  • Reduction of insulation thickness would be beneficial not only for increasing the cable length but would also improve its thermal performance. An interfacial diffusion method was devised to reduce insulation thickness by improving the interfacial properties of XLPE cable insulation. In this paper, to evaluate superficially the interface properties between XLPE insulation and semiconducting layer, the dielectric and insulation properties of tan${\delta}$ and volume resistance were measured with temperature dependence. Above the results, dielectirc and insulation properties with semiconductor/XLPE were more anormal than its bulk caused by the interfacial properties.

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Morphologically Controlled Growth of Aluminum Nitride Nanostructures by the Carbothermal Reduction and Nitridation Method

  • Jung, Woo-Sik
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1563-1566
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    • 2009
  • One-dimensional aluminum nitride (AlN) nanostructures were synthesized by calcining an Al(OH)(succinate) complex, which contained a very small amount of iron as a catalyst, under a mixed gas flow of nitrogen and CO (1 vol%). The complex decomposed into a homogeneous mixture of alumina and carbon at the molecular level, resulting in the lowering of the formation temperature of the AlN nanostructures. The morphology of the nanostructures such as nanocone, nanoneedle, nanowire, and nanobamboo was controlled by varying the reaction conditions, including the reaction atmosphere, reaction temperature, duration time, and ramping rate. Iron droplets were observed on the tips of the AlN nanostructures, strongly supporting that the nanostructures grow through the vapor-liquid-solid mechanism. The variation in the morphology of the nanostructures was well explained in terms of the relationship between the diffusion rate of AlN vapor into the iron droplets and the growth rate of the nanostructures.

FT-IR Studies of Molybdena Supported on Titania

  • Kim, Kwan;Lee,, Soon-Bo
    • Bulletin of the Korean Chemical Society
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    • v.12 no.1
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    • pp.17-22
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    • 1991
  • Fourier transform infrared spectroscopy has been applied to the characterization of titania supported molybdena. The equilibrium adsorption method seemed to produce molybdena species homogeneously dispersed on the support. Even under an oxidizing environment, molybdena species appeared to be able to possess coordinatively unsaturated $Mo^{5+}$ ions owing to the natures of TiO$_2$, i.e. oxygen deficiency and permeability toward oxygen diffusion. At the initial stage of reduction, the terminal double bond oxygen ( Mo=O ) seemed to be removed, generating presumably $Mo^{4+}$. The carbonyl bands at 2198 and 2190 $cm^{-1}$ observed after CO exposure were attributed to the $Mo^{5+}{\cdots}CO\;and\;Mo^{4+}\;{\cdots}CO$ complexes, respectively, while the band pair at 2136 and 2076 $cm^{-1}$ to $Mo^{4+}(CO)_2$.