• Journal of Electrochemical Science and Technology
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• v.13 no.4
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• pp.462-471
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• 2022

In this study, the electrochemical impedance characteristics of CO₂/H₂O co-reduction to produce CO/H₂ syngas were investigated in a low-temperature single cell. The effect of the operating conditions on the single-cell performance was evaluated at different feed concentrations and cell voltages, and the corresponding electrochemical impedance spectroscopy (EIS) data were collected and analyzed. The Nyquist plots exhibited two semicircles with separated characteristic frequencies of approximately 1 kHz and tens of Hz. The high-frequency semicircles, which depend only on the catholyte concentration, could be correlated to the charge transfer processes in competitive CO₂ reduction and hydrogen evolution reactions at the cathodes. The EIS characteristics of the CO₂/H₂O co-reduction single cell could be explained by the equivalent circuit suggested in this study. In this circuit, the cathodic mass transfer and anodic charge transfer processes are collectively represented by a parallel combination of resistance and a constant phase element to show low-frequency semicircles. Through nonlinear fitting using the equivalent circuit, the parameters for each electrochemical element, such as polarization resistances for high- and low-frequency processes, could be quantified as functions of feed concentration and cell voltage.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.187.1-187.1
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• 2011

RDF(Refuse-Derived Fuel) is a fuel of pelletized form made of combustible solid wastes and can not only be used as alternative energy to fossil fuel but also solve troubles in thermal uses of incinerator. As the first stage for obtaining elementary data required to develop criteria of raw materials appropriate to RDF combustion facilities actively spread recently in Korea, preliminary experiments were conducted on CO, SOx, NOx and HCl production and reduction characteristics in combustion of RDF. RDF samples weighing 2~3 g per a sample were manufactured in a lab-scale way and combustion tests of RDF were carried out in electric furnace with quartz tube of 50 mm inside diameter.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.3
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• pp.174-182
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• 2007

Fuel reforming technology for the fuel cell vehicles could be applied to internal combustion engine for the reduction of engine out emissions. Since syngas which is reformed from fossil fuel has hydrogen as a major component, it has abilities to enhance the combustion characteristics with wide flammability and high speed flame propagation. In this study, syngas was added to a gasoline engine to improve combustion stability and exhaust emissions of idle state. Syngas fraction is varied to 0%, 50%, 100% with various ignition timing and excess air ratio. Combustion stability, exhaust emissions, fuel consumption and exhaust gas temperature were measured to investigate the effects of syngas addition on idle performance. Results showed that syngas has ability to widely extend lean operation limit and ignition retard range with dramatical reduction of engine out emissions.

• Journal of the Korean Ceramic Society
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• v.55 no.1
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• pp.50-54
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• 2018

This study investigated the long-term durability of catalyst(Pd or Fe)-infiltrated solid oxide cells for $CO_2$/steam co-electrolysis. Fuel-electrode supported solid oxide cells with dimensions of $5{\times}5cm^2$ were fabricated, and palladium or iron was subsequently introduced via wet infiltration (as a form of PdO or FeO solution). The metallic catalysts were employed in the fuel-electrode to promote $CO_2$ reduction via reverse water gas shift reactions. The metal-precursor particles were well-dispersed on the fuel-electrode substrate, which formed a bimetallic alloy with Ni embedded on the substrate during high-temperature reduction processes. These planar cells were tested using a mixture of $H_2O$ and $CO_2$ to measure the electrochemical and gas-production stabilities during 350 h of co-electrolysis operations. The results confirmed that compared to the Fe-infiltrated cell, the Pd-infiltrated cell had higher stabilities for both electrochemical reactions and gas-production given its resistance to carbon deposition.

• Journal of the Semiconductor & Display Technology
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• v.7 no.4
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• pp.45-49
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• 2008

For the commercialization of polymer electrolyte membrane fuel cell (PEMFC), some serious problems such as the decrease of platinum use as catalysts and a larger overpotential of oxygen reduction reaction (ORR) at cathode must be solved. In this study, 20%Pt/C and 20%PtCo/C catalysts for the cathode of PEMFC were synthesized from the chemical reduction method and evaluated using an electrochemical measurement. The ORR activity of synthesized 20%Pt/C and 20%PtCo/C had higher than that of the 20%Pt/C on the market. The synthesized 20%PtCo/C with the cobalt concentration (Pt:Co atomic ratio) from 5 to 20% showed the highest ORR activity.

• Journal of the Korean Institute of Gas
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• v.24 no.4
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• pp.25-31
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• 2020

Experimental investigations were conducted to examine the combustion characteristics of a swirl-stabilized double cone premixed burner nozzle used for industrial gas turbines for power generation. Several variants with different fuel injection patterns are tested to compare the combustion characteristics such as NOx and CO emissions, stability, and wall temperature distributions. Main results show that NOx emissions and stability are decreased either when the fuel hole diameter is decreased with the same number of fuel holes, or when the number of fuel holes is reduced with the same total area of fuel holes, both of which are due to a higher penetration of fuel into the air stream. Not only is NOx reduced but also stability is enhanced when the fuel hole diameter varies in an alternating manner with the same total area of fuel holes, showing that NOx reduction is due to a higher penetration of mean fuel injection path while stability enhancement is due to a lowered penetration of minimum fuel injection path.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2002.04b
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• pp.7-7
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• 2002

Recently social demand to achieve low fuel consumption and clean emission requires the development of new generation vehicle beyond the conventional vehicle concept. In this point, new generation vehicle is newly designed as electric vehicle, hybrid electric vehicle, fuel cell electric vehicle or 3 liter car etc. In order to develop new generation vehicle, it is very important to develop new materials and process technologies now. In this paper these new technologies are presented focusing on weight reduction specially. Steel body can be achieved 20-25% weight reduction by adoption of high strength steel and new process technologies, i.e tailored blank and hydroforming. Aluminium body can be achieved 40-50% weigt down by use of all aluminium monocoque body or aluminium space frame with aluminium panel. Plasitic composite body can be achieved 30% weight reduction comparing with conventional steel body.

• Korean Journal of Materials Research
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• v.21 no.3
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• pp.180-185
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• 2011

This study is aimed to increase the activity of cathodic catalysts for PEMFCs(Polymer Electrolyte Membrane Fuel Cells). we investigated the temperature effect of 20wt% Pt/C catalysts at five different temperatures. The catalysts were synthesized by using chemical reduction method. Before adding the formaldehyde as reducing agent, process was undergone for 2 hours at the room temperature (RT), $40^{\circ}C$, $60^{\circ}C$, $80^{\circ}C$ and $100^{\circ}C$, respectively. The performances of synthesize catalysts are compared. The electrochemical oxygen reduction reaction (ORR) was studied on 20wt% Pt/C catalysts by using a glassy carbon electrode through cyclic voltammetric curves (CV) in a 1M H2SO4 solution. The ORR specific activities of 20wt% Pt/C catalysts increased to give a relative ORR catalytic activity ordering of $80^{\circ}C$ > $100^{\circ}C$ > $60^{\circ}C$ > $40^{\circ}C$ > RT. Electrochemical active surface area (EAS) was calculated with cyclic voltammetry analysis. Prepared Pt/C (at $80^{\circ}C$, $100^{\circ}C$) catalysts has higher ESA than other catalysts. Physical characterization was made by using X-ray diffraction (XRD) and transmission electron microscope (TEM). The TEM images of the carbon supported platinum electrocatalysts ($80^{\circ}C$, $100^{\circ}C$) showed homogenous particle distribution with particle size of about 2~3.5 nm. We found that a higher reaction temperature resulted in more uniform particle distribution than lower reaction temperature and then the XRD results showed that the crystalline structure of the synthesized catalysts are seen FCC structure.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.1
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• pp.186-192
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• 2007

In general, pulsation damper is installed in fuel rail for conventional MPI engine to decrease undesirable noise in vehicle cabin room. However, pulsation damper is so expensive that there are prevailing studies to reduce fuel pressure pulsations with integrated damping effect. This paper is one of basic studies for development of fuel rail to abate pulsations with self-damping effect. Primarily, the pressure pulsation characteristics was investigated with aspect ratio of cross section, wall thickness, and materials of fuel rail. A high aspect ratio or thin wall was found to absorb the pressure pulsations effectively. But volume effects on the fuel pressure pulsation reductions were not especially significant than cross section effects because volume increment rate is larger than pressure pulsation reduction rate. The fuel rail made of aluminum is effective for reduction of pressure pulsation than that of low-carbon steel. Pressure change period increases on the basis of same lengths of supply line and fuel rail as the volume is enlarged and/or the thickness of wall is thinned.

• Design & Manufacturing
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• v.13 no.4
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• pp.17-22
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• 2019

Currently, studies on weight reduction and fuel efficiency increase are the most important topics in the automotive industry and many studies are under way. Among them, weight reduction is the best way to raise fuel efficiency and solve environmental pollution and resource depletion. Materials such as aluminum, magnesium and carbon curing materials can be found in lightweight materials. Among these, research on improvement of bonding technology and manufacturing method of materials and improvement of material properties through study of ultrahigh strength steel sheet is expected to be the biggest part of material weight reduction. As the strength of the ultra hight strength steel sheet increases during forming, it is difficult to obtain the dimensional accuracy as the elastic restoring force increases compared to the hardness or high strength steel sheet. It is known that the spring back phenomenon is affected by various factors depending on the raw material and processing process. We have conducted analytical evaluations and studies to analyze the springback that occurs according to the cross-sectional shape of the ultra high tensile steel sheet.