• Korean Chemical Engineering Research
• /
• v.55 no.3
• /
• pp.379-384
• /
• 2017

An electrochemical reduction of a mixture of NiO and rare earth oxides has been conducted to increase the reduction degree of rare earth oxides. Cyclic voltammetry (CV) measurement was carried out to determine the electrochemical reduction behavior of the mixed oxide in molten LiCl medium. Constant voltage electrolysis was performed with various supplied charges to understand the mechanism of electrochemical reduction of the mixed oxide as a working electrode. After completion of the electrochemical reduction, crystal structure of the reaction intermediates was characterized by using an X-ray diffraction method. The results clearly demonstrate that the rare earth oxide was converted to RE-Ni intermetallics via co-reduction with NiO.

• Journal of Powder Materials
• /
• v.31 no.2
• /
• pp.163-168
• /
• 2024

As the demand for lithium-ion batteries for electric vehicles is increasing, it is important to recover valuable metals from waste lithium-ion batteries. In this study, the effects of gas flow rate and hydrogen partial pressure on hydrogen reduction of NCM-based lithium-ion battery cathode materials were investigated. As the gas flow rate and hydrogen partial pressure increased, the weight loss rate increased significantly from the beginning of the reaction due to the reduction of NiO and CoO by hydrogen. At 700 ℃ and hydrogen partial pressure above 0.5 atm, Ni and Li₂O were produced by hydrogen reduction. From the reduction product and Li recovery rate, the hydrogen reduction of NCM-based cathode materials was significantly affected by hydrogen partial pressure. The Li compounds recovered from the solution after water leaching of the reduction products were LiOH, LiOH·H₂O, and Li₂CO₃, with about 0.02 wt% Al as an impurity.

• Fashion & Textile Research Journal
• /
• v.21 no.1
• /
• pp.36-45
• /
• 2019

In 2000s, the rapid growth of domestic and foreign fast fashion brands led to an increase in the frequency of shopping for consumers and a significant reduction in the average life span of fashion products. As the kinds and quantity of fashion products owned by individuals increase, the problem of rational clothing management becomes a new concern. The purpose of this study was to investigate the demographic, socio-psychological and purchase behavior factors influencing the frequency of closet cleanup behavior. A total of 278 questionnaires were analyzed. Frequency, exploratory factor analysis, reliability, t-test and regression analysis were used for data analysis using SPSS 22.0. This study results were as follows. First, the frequency of women's closet cleanup behavior was higher than that of men's closet cleanup behavior. Second, the number of brothers and sisters significantly affected the frequency of closet cleanup behavior. Third, the stronger the attachment to fashion products, the higher the frequency of closet cleanup behavior. Fourth, the lower the fashion product retention tendency, the higher the frequency of closet cleanup behavior. Fifth, the higher the frequency of purchasing fashion products, the higher the frequency of closet cleanup behavior. The results of current study provide various implications for educators and marketers who are interested in reasonable management behavior of fashion goods.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.3 no.2
• /
• pp.85-93
• /
• 2005

Isotopes of alkali and alkaline earth metals (AM and AEM) are the main contributors to the heat load and the radiotoxicity of spent fuel (SF) . These components are separated from the SF and dissolved in a molten LiCl in an electrolytic reduction process. A mass transfer model is developed to describe the diffusion behavior of Cs, Sr, and Ba in the SF into the molten salt. The model is an analytical solution of Fick's second law of diffusion for a cylinder which is the shape of a cathode in the electrolytic reduction process. And the model is also applied to depict the concentration profile of the oxygen ion which is produced by the electrolysis of Li$_{2}$O. The regressed diffusion coefficients of the model correlating the experimentally measured data are evaluated to be greater in the order of Ba, Cs, and Sr for the metal ions and the diffusion of the oxygen ion is slower than the metal ions which implies that different mechanisms govern the diffusion of the metal ions and the oxygen ions in a molten LiCl.

• Structural Engineering and Mechanics
• /
• v.52 no.6
• /
• pp.1157-1176
• /
• 2014

The objective of this research is to develop a practical design and assessment approach of steel frames with steel slit walls (SSWs) that focuses on the damage-control behavior to enhance the structural resilience. The yielding sequence of SSWs and frame components is found to be a critical issue for the damage-control behavior and the design of systems. The design concept is validated by the full-scale experiments presented in this paper. Based on a modified energy-balance model, a procedure for designing and assessing the system motivated by the framework regarding the equilibrium of the energy demand and the energy capacity is proposed. The damage-control spectra constructed by strength reduction factors calculated from single-degree-of-freedom systems considering the post stiffness are addressed. A quantitative damage-control index to evaluate the system is also derived. The applicability of the proposed approach is validated by the evaluation of example structures with nonlinear dynamic analyses. The observations regarding the structural response and the prediction during selected ground motions demonstrate that the proposed approach can be applied to damage-control design and assessment of systems with satisfactory accuracy.

• Structural Engineering and Mechanics
• /
• v.75 no.2
• /
• pp.229-237
• /
• 2020

The steel slit shear wall (SSSW), made by cutting vertical slits in a steel plate, is increasingly used for the seismic protection of building structures. In the domain of thin plate shear walls, the out-of-plane buckling together with the potential fracture developed at slit ends at large lateral deformation may result in degraded shear strength and energy dissipation, which is not desirable in view of seismic design. To address this issue, the present study proposed a new type of SSSW made by intentionally introducing initial out-of-plane folding into the originally flat slitted plate. Quasi-static cyclic tests on three SSSWs with different amplitudes of introduced out-of-plane folding were conducted to study their shear strength, elastic stiffness, energy dissipation capacity and buckling behavior. By introducing proper amplitude of out-of-plane folding into the SSSW fracture at slit ends was eliminated, plumper hysteretic behavior was obtained and there was nearly no strength degradation. A method to estimate the shear strength and elastic stiffness of the new SSSW was also proposed.

• Transactions of Materials Processing
• /
• v.17 no.4
• /
• pp.272-277
• /
• 2008

A constitutive equation of the electrical steel strip used for a raw material of transformer is proposed. The stress-strain behavior of electrical steel strip is quite different from that of common carbon steel and/or alloy steel. A series of tensile tests were performed with the specimens made from cold rolled strip. Several thicknesses of the strip were produced by a two-high (with upper and lower rolls) cold rolling pilot mill as reduction ratio increases from 10% to 90%. Its initial thickness of the strip was 2.5mm. Tensile specimens are cut out from the cold rolled strips. Mechanical properties of the steel are examined through rolling direction. Ramberg-Osgood model and the proposed equation are combined to describe the total behavior of stress-strain including instability region. The stress-strain curves calculated from the present constitutive equation are compared with those from experimentally obtained at each test condition of reduction ratios of specimen. Results show that the predicted stress-strain curves are in overall in a good agreement with measured ones.

• Transactions of the Korean Society for Noise and Vibration Engineering
• /
• v.19 no.6
• /
• pp.634-640
• /
• 2009

Helmholtz resonator has been used, especially in intake and exhaust systems of vehicles, due to its good noise reduction characteristics at low frequencies. Many approaches have been developed to predict the acoustic behavior of the resonator with the assumption that there is no leakage from the resonator. However, its behavior may be affected by leakage which may exist in manufacturing processes or on purpose. This study investigates the effect of leakage on the noise reduction characteristics of Helmholtz resonator with two practical examples. One is a resonator with a gap between baffle and housing of the resonator and the other one is a resonator with two drain holes on the baffle. The measured transmission loss shows that the resonance frequencies are considerably shifted to higher frequency due to the leakage. The Boundary Element Method was applied to predict the transmission loss of the Helmholtz resonator with drain holes. The comparison between the measured and predicted transmission loss shows that the acoustic impedance of the holes is essential for accurate predictions of the transmission loss.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.18 no.3
• /
• pp.415-420
• /
• 2020

Strontium is known as a salt-soluble element during the electrolytic oxide reduction (EOR) process. The chemical behavior of SrO during EOR was investigated via thermodynamic calculations to provide quantitative data on the chemical status of Sr. To achieve this, thermodynamic calculations were conducted using HSC chemistry software for various EOR conditions. It was revealed that SrO reacts with LiCl salt to produce SrCl₂, even in the presence of Li₂O, and that the ratio of SrCl₂ depends on the initial concentration of Li₂O dissolved in LiCl. It was found that SrO reacts with Li to produce Sr during EOR and that the reduced Sr reacts with LiCl salt to produce SrCl₂. As a result, the proportions of metallic forms were lower in Sr than in La and Nd under various EOR conditions. The thermodynamic calculations indicated that the three chemical forms of SrO, SrCl₂, and Sr co-exist in the EOR system under an equilibrium with Li, Li₂O, and LiCl.

• Journal of Powder Materials
• /
• v.27 no.3
• /
• pp.193-197
• /
• 2020

Porous Cu-14 wt% Co with aligned pores is produced by a freeze drying and sintering process. Unidirectional freezing of camphene slurry with CuO-Co₃O₄ powders is conducted, and pores in the frozen specimens are generated by sublimation of the camphene crystals. The dried bodies are hydrogen-reduced at 500℃ and sintered at 800℃ for 1 h. The reduction behavior of the CuO-Co₃O₄ powder mixture is analyzed using a temperature-programmed reduction method in an Ar-10% H₂ atmosphere. The sintered bodies show large and aligned parallel pores in the camphene growth direction. In addition, small pores are distributed around the internal walls of the large pores. The size and fraction of the pores decrease as the amount of solid powder added to the slurry increases. The change in pore characteristics according to the amount of the mixed powder is interpreted to be due to the rearrangement and accumulation behavior of the solid particles in the freezing process of the slurry.