• Title/Summary/Keyword: Reduction agent

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(Pyridine)(tetrahydroborato)zinc Complex, [Zn(BH4)2(py)], as a New Stable, Efficient and Chemoselective Reducing Agent for Reduction of Carbonyl Compounds

  • Zeynizadeh, Behzad;Faraji, Fariba
    • Bulletin of the Korean Chemical Society
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    • 제24권4호
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    • pp.453-459
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    • 2003
  • (Pyridine)(tetrahydroborato)zinc complex, $[Zn(BH_4)_2(py)]$, as a stable white solid, was prepared quantitatively by complexation of an equimolar amount of zinc tetrahydroborate and pyridine at room temperature. This reagent can easily reduce variety of carbonyl compounds such as aldehydes, ketones, acyloins, α-diketones and a, β-unsaturated carbonyl compounds to their corresponding alcohols in good to excellent yields. Reduction reactions were performed in ether or THF at room temperature or under reflux conditions. In addition, the chemoselective reduction of aldehydes over ketones was accomplished successfully with this reducing agent.

Development of a Functional Complexity Reduction Concept of MMIS for Innovative SMRs

  • Gyan, Philip Kweku;Jung, Jae Cheon
    • 시스템엔지니어링학술지
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    • 제17권2호
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    • pp.69-81
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    • 2021
  • The human performance issues and increased automation issues in advanced Small Modular Reactors (SMRs) are critical to numerous stakeholders in the nuclear industry, due to the undesirable implications targeting the Man Machine Interface Systems (MMIS) complexity of (Generation IV) SMRs. It is imperative that the design of future SMRs must address these problems. Nowadays, Multi Agent Systems (MAS) are used in the industrial sector to solve multiple complex problems; therefore incorporating this technology in the proposed innovative SMR (I-SMR) design will contribute greatly in the decision making process during plant operations, also reduce the number MCR operating crew and human errors. However, it is speculated that an increased level of complexity will be introduced. Prior to achieving the objectives of this research, the tools used to analyze the system for complexity reduction, are the McCabe's Cyclomatic complexity metric and the Henry-Kafura Information Flow metric. In this research, the systems engineering approach is used to guide the engineering process of complexity reduction concept of the system in its entirety.

High Level O2배가스중 NO 저감에 대한 선택적비촉매환원 반응특성에 관한 연구 (A Study on Characteristic of NO Reduction by High Level O2Gas in Selective Non-Catalystic Reaction)

  • 이강우;정종현;오광중
    • 한국환경과학회지
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    • 제11권6호
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    • pp.577-582
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    • 2002
  • Selective catalytic reduction and selective non-catalytic reduction processes are mainly used to treat nitrogen oxidants generated from fossil-fuel combustion. Especially, the selective non-catalytic reduction process can be operated more economical and designed more simply than the selective catalytic reduction. For this reason, many researchers carried out to increase the removal efficiency of nitrogen oxidants in the condition of low oxygen concentration by using the selective non-catalytic reduction process. However, this study was flue gas contained high oxygen concentration of 20(v/v%) with ammonia as a reducing agent. Moreover, it carried out experiment with many factors that are reaction temperature, retention time, initial NO concentration, NSR(normalized stoichiometric ratio). It was determined optimal operating conditions to improve NO removal efficiency with SNCR process. The De-NOx efficiency was increased with NSR, initial NO concentration and retention time increasement. This study has NO removal efficiency over 80% in the high oxygen concentration as well as low oxygen concentration. The injection of reducing agent may be considered for SNCR process and facility operation in 850$\^{C}$ of optimal condition.

Marketing to Competitors' Customers using Agent based Modelling and Simulation Driven Strategy

  • Beyari, Hasan
    • International Journal of Computer Science & Network Security
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    • 제21권7호
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    • pp.297-304
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    • 2021
  • In a duopoly situation, one firm can gain competitive advantage by attracting the price-sensitive customers from its competitor leading to higher profits through higher sale revenue for the competing company. A simulation study in which there are two electric car manufacturers with agent based modelling was conducted in order to verify this contention. The first step consisted of defining the baseline. Simulations of 1000 times and agent-based modelling were conducted with the assumption that company 1 reduced its price to the maximum of 20% thereby contributing to the switch-over of a maximum of 40% of the price sensitive customers of company 2. The results of 1000 simulations and agent-based modelling highlighted that price reduction by company 1 resulted in a significant increase in the number of customers, presumably due to switch-over from company 2 and there was a corresponding increase in revenues from both of the sales avenues. Thus, Company 1 achieved competitive advantage by marketing its cars to the customers of Company 2 using price reduction strategy to attract them. This study has ramifications for companies that aim to sway the price sensitive customers from a competitor.

무선통신 효율 향상을 위한 WAP 게이트웨이 에이전트 (Implementation of WAP Gateway Agents for Wireless Communication Efficiency Improvement)

  • 박기현;강동우
    • 인터넷정보학회논문지
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    • 제6권3호
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    • pp.45-54
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    • 2005
  • 최근 무선 인터넷 서비스를 위한 다양한 기반기술이 연구되고 있으며, WAP(Wireless Application Protocol) 포럼에서는 기존의 유선인터넷 프로토콜과 무선 WAP 프로토콜간의 상호변환을 담당하는 WAP 게이트웨이를 제안하였다. 본 논문에서는 제한적인 환경을 가지는 이동무선통신망에서의 효율향상을 위한 방법의 일환으로써, WAP 게이트웨이를 위한 에이전트들을 설계하고 구현하였다. WAP 게이트웨이 에이전트들인 CSA(Client Side Agent)와 SSA(Sewer Side Agent)는 이동 WAP 단말기와 WAP 게이트웨이에 각각 위치하며, 패킷 헤더 데이터축소와 데이터 차이분석을 통한 데이터축소 방법들을 이용하여 이동무선통신 환경에서의 통신효율을 향상시킨다 구현된 에이전트들이 제대로 동작된다는 것을 입증하기 위하여 Phone.com의 인터넷폰 에뮬레이터를 사용하였다. 실험 결과, WAP 게이트웨이만을 이용한 데이터 전송량에 비하여, 본 논문에서 구현한 에이전트들을 이용하면 데이터 전송량을 $20\%$ 내지 $35\%$가량 줄일 수 있음을 알 수 있었다.

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가수분해된 인삼사포닌 4급 암모늄엽과 화장품으로의 응용에 관한 연구 (A Study on the Hydrolyzed Ginseng Saponin-Quaternary and its Application in Cosmetics)

  • 김영대;김창규;이정남;하병조
    • Journal of Ginseng Research
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    • 제13권2호
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    • pp.189-197
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    • 1989
  • A new quaternary ammonium compound, hydrolyzed ginseng-saponin quaternary (HGSQ), from Korean ginseng saponin and 2,3-epoxypropyltrimethylammonium chloride has been developed as a conditioning agent in cosmetics. This structure has a hydrophobic group from the aglycone of ginseng saponin which is biologically active and considered to be the most important component of the Korean ginseng. Its properties : surface tension, critical micelle concentration (CMC), eye irritation, sorption onto hair, force reduction(%) and moisture retention effect were studied. Its cationic character allows the molecule to be more substantive than ginseng saponin. HGSQ had good physical properties and was safe. enough as a cosmetic raw material. Also half-head tests of HGSQ-containing shampoo were carried out to compare the conditioning effects in shampoos. HGSQ was an excellent conditioning agent in shampoo..

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공급망 상생협력 활동과 성과 공유 전략 (Buyer-Supplier Collaboration and Benefit-Sharing Strategy in a Supply Chain)

  • 유승호
    • 한국경영과학회지
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    • 제36권1호
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    • pp.69-84
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    • 2011
  • In this study, based on the principal-agent paradigm, we investigate a joint cost reduction activity in a buyer-supplier supply chain where a buyer motivates its operations department and a supplier to reduce the supply chain's production cost. We construct a benefit-sharing model based on the target cost scheme, a basic philosophy in practice which has not been explored in previous studies. The model also incorporates various supply chain issues such as the cooperation of multiple agents, the opportunity loss, and the degree of strategic relationship between the buyer and the supplier. Based on the analysis of the principal-agent model, we investigate the benefit-sharing rule to control agents' actions, and we also provide important managerial implications into supply chain practices via extensive comparative static analyses.

천연물질을 활용한 웰빙기법 천연염색에 관한 연구 (2) -소엽염색 면직물의 모나자이트 처리효과- (A Study on the Well-being Technique Natural Dyeing with Natural Resources (2) -Effect of Monazite Treatment on the Cotton Fabric with Natural Dyeing using Perilla frutescens var. acuta -)

  • 김상률
    • 한국의류산업학회지
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    • 제12권2호
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    • pp.240-245
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    • 2010
  • The effects of monazite and fixing agents on cotton fabric dyed with Perilla frutescens var. acuta extract were investigated. The proper monazite treatment concentration, temperature and time were 10%(o.w.b.), $50^{\circ}C$ and 60minutes. By various fixing agent treatment, $FeSO_4$ showed a relatively high K/S value and the order of K/S value decreased as follows, cation surface active agents, soybean and NaCl. And the monazite and $FeSO_4$ fixing agent showed higher anion emissity than those of untreated cotton and other fixing agents. The cotton fabrics showed improved color fastness by monazite and fixing agents treatments with the exception of light fastness. And the cotton fabrics fixed with fixing agents were showed effective bacterial reduction with the exception of NaCl.

알칼리 자극제 혼입 고로슬래그 콘크리트의 건조수축과 공극구조 (Drying shrinkage and Pore Structure of Blast Furnace Slag Concrete Mixed Alkaline Stimulation)

  • 박지웅;이건철;고산
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2016년도 추계 학술논문 발표대회
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    • pp.32-33
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    • 2016
  • This purpose of this study is to find the properties of pore structure and length change of blast furnace slag cement added alkali powder stimulant on shrinkage reducing agent presence. In length change, the specimen added alkaline stimulant was smaller than normal blast furnace slag concrete. And the specimen added shrinkage reduction agent was confirmed to show smaller rate of length change than the length. In MIP analysis of 1day-age, 0.1㎛ subsequent pore amount of the specimen added alkaline stimulant was significantly smaller value the normal blast furnace slag concrete specimen.

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