• Title/Summary/Keyword: Reduction agent

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Individual and combined effect of Portland cement and chemical agents on unconfined compressive strength for high plasticity clayey soils

  • Yilmaz, Yuksel;Eun, Jongwan;Goren, Aysegul
    • Geomechanics and Engineering
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    • v.16 no.4
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    • pp.375-384
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    • 2018
  • Unconfined compressive strength (UCS) of high plasticity clayey soil mixed with 5 and 10 % of Portland cement and four chemical agents such as sodium hexametaphosphate, aluminum sulfate, sodium carbonate, and sodium silicate with 0, 5, 10, and 20% concentrations was comparatively evaluated. The individual and combined effects of the cement and chemical agents on the UCS of the soil mixture were investigated. The strength of the soil-cement mixture generally increases with increasing the cement content. However, if the chemical agent is added to the mixture, the strength of the cement-chemical agent-soil mixture tends to vary depending on the type and the amount of the chemical agent. At low concentrations of 5% of aluminum sulfate and 5% and 10% of sodium carbonate, the average UCS of the cement-chemical agent-soil mixture slightly increased compared to pure clay due to increasing the flocculation of the clay in the mixture. However, at high concentrations (20%) of all chemical agents, the UCS significantly decreased compared to the pure clay and clay-cement mixtures. In the case of high cement content, the rate of UCS reduction is the highest among all cement-chemical agent-soil mixtures, which is more than three times higher in comparison to the soil-chemical agent mixtures without cement. Therefore, in the mixture with high cement (> 10%), the reduction of the USC is very sensitive when the chemical agent is added.

Characterizations of Pt-SPE Electrocatalysts Prepared by an Impregnation-Reduction Method for Water Electrolysis (함침-환원법으로 제조된 수전해용 Pt-SPE 전극촉매의 특성)

  • Jang, Doo-Young;Jang, In-Young;Kweon, Oh-Hwan;Kim, Kyoung-Eon;Hwang, Gab-Jin;Kang, An-Soo
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.4
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    • pp.440-447
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    • 2006
  • Solid polymer electrolyte(SPE) membrane with electrodes embedded on both faces offer unique possibilities for the electrochemical cells like water electrolyzer with fuel cell. The Nafion 117 membrane was used as the SPE, and $Pt(NH_3)_4Cl_2$ and $NaBH_4$ as the electrocatalysts and reducing agent, respectively. The 'impregnation-reduction(I-R) method' has been investigated as a tool for the preparation of electrocatalysts for water electrolyzer by varying the concentration of reducing agent and reduction time at fixed concentration of platinum salt, 5 mmol/L. Pt-SPE electrocatalysts prepared by non-equilibrium I-R method showed the lowest cell voltage of 2.17 V at reduction time, 90 min and with concentration of reducing agent 0.8 mol/L and the cell voltage with those by equilibrium I-R method was 2.42 V at reduction time, 60 min and with concentration of reducing agent 0.8 mol/L. The cell voltage were obtained at a current density $1\;A/cm^2$ and $80^{\circ}C$. In water electrolysis, hydrogen production efficiency by Pt-SPE electrocatalyst is 68.2% in case of non-equilibrium I-R method and 61.2% at equilibrium I-R method.

Bactericidal Effect of Waterless Alcohol Gel Hand Washing Agent (물 없이 사용하는 알코올 젤의 손소독 효과에 관한 연구)

  • Jeong, Jae-Sim;Kim, Duck-Hee;Kim, Mi-Na;Choe, Myoung-Ae
    • Journal of Korean Biological Nursing Science
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    • v.4 no.2
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    • pp.127-137
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    • 2002
  • The purpose of this study was to compare the hand disinfection effect of waterless alcohol gel hand washing agent with that of soap and water, 4% chlorhexidine gluconate, and 10% povidone-iodine. Hands of fourty subjects were artificially contaminated with Acinetobacter baumannii $5m{\ell}$ and randomly distributed to each hand washing methods. Samples were collected from gloved hand by glove juice sampling procedure. Mean log reduction after hand washing were compared with baseline values. Number of microorganisms were converted to log and tested by ANOVA in SPSSWIN 10.0. Mean log reduction of soap and water, alcohol gel, 4% chlorhexidine gluconate, 10% povidone-iodine were $2.76{\pm}0.62$, $2.97{\pm}0.56$, $4.66{\pm}1.70$, $4.60{\pm}0.91$, respectively. The bactericidal effect of alcohol gel was similar to that of soap and water, but the effect was much less than chlorhexidine gluconate and povidone-iodine(p<0.001). In terms of microorganism reduction, the efficacy of waterless alcohol gel was almost the same as soap and water hand washing. Further evaluation of the bactericidal effect of waterless alcohol gel is needed because waterless alcohol gel is simple, convenient, and non-irritating hand washing agent and also very effective in busy hospital environment.

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Study on Performance of pH Reduction for Recycled Aggregate by Using Phosphate of Ammonium (인산암모늄을 사용한 순환골재의 pH 저감 성능 검토)

  • Gao, Shan;Lee, Gun-Cheol;Park, Ji-Woong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.106-107
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    • 2016
  • Construction waste is recycled and used for the efficient and eco-friendly disposal of construction waste increasing due to reconstruction and redevelopment project and so on. There is recycled aggregate as a typical case. And this recycled aggregate shows strong alkalinity due to calcium hydroxide, and causes many environmental problems. Therefore, this is a study on reduction in the strong alkalinity of recycled aggregate by using phosphate of ammonium in order to reduce the pH of recycled aggregate. Besides, a possibility that a pH reducing agent of recycled aggregate could be applied to a site was evaluated. As a result, it was possible to verify that pH decreased as the percentage of pH reducing agent increased. It is thought that the pH reducing agent can be applied to a site by methods such as immersion and spray using the pH reducing agent in the process of producing recycled aggregates.

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Order Reduction Paradigm for Consensus of Neutrally Stable Multi-Agent Systems (중립적으로 안정한 다개체 시스템의 일치에 대한 제어기 차수 감소 패러다임)

  • Kim, Hong-Keun;Kim, Seong-Jun;Shim, Hyung-Bo;Back, Ju-Hoon
    • Journal of Institute of Control, Robotics and Systems
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    • v.16 no.3
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    • pp.222-226
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    • 2010
  • In this paper we study the consensus problem of SISO (Single-Input Single-Output) linear multi-agent systems under a fixed weighted undirected network communication. The dynamics of each agent can be of any order, while it is constrained to be neutrally stable. Based on a simple root locus argument, we show that the problem at hand is always solvable if the gain and zeros of the dynamic compensator, of which dimension is the same as the number of plant poles on the imaginary axis, are chosen suitably, finally the result is successfully verified by an example.

Synthesis of Ag Nanopowder for Low Temperature Heat Treatment Prepared by Liquid Phase Reduction Method (액상환원법에 의한 저온 열처리용 Ag 나노분말의 합성)

  • Lee, Jong-Kook;Choi, Nam-Kyu;Song, Dae-Sung;Yang, Gon-Seung;Seo, Dong-Seok
    • Journal of the Korean Society for Heat Treatment
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    • v.18 no.4
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    • pp.242-246
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    • 2005
  • Silver nanoparticles were synthesized by liquid phase reduction method from aqueous silver nitrate solution and borohybride as a reduction agent. The morphology, particle size and shape were influenced by the reaction conditions such as the concentration of $AgNO_3$, a reduction agent and addition of surfactant. The particle size decreased with decreasing the concentration of silver nitrate and using a borohydride. The obtained Ag particles showed the spherical shape with the range of 10-20 nm.

Construction Considering the Difference of Setting Time of Super Retarding Agent for Reduction of Hydration Heat of Footing Mass Concrete (기초 매스콘크리트의 수화열 저감을 위한 초지연제 응결시간차 공법의 현장 적용)

  • 황인성;배정렬;윤석명;김기철;오선교;한천구
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2003.05a
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    • pp.95-98
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    • 2003
  • This paper presents the results of field experiment to apply the difference of setting tine method using super retarding agent for reducing hydration heat of mass concrete of foundation. According to the results, as the properties of fresh concrete, base concrete satisfies aimed slump and air content, and there is no difference of slump and air content with mixture of super retarding agent. The mixing ratio of super retarding agent is determined for setting time to be retarded by 12 hours in comparison with base concrete, but because the temperature of the air and concrete is low, the difference of setting time is retarded to 24 hours. In man concrete of foundation to which the difference of setting time method is applied, crack by hydration heat is not seen because the lower concrete of super retarding agent generates heat after generation of hydration heat of the upper concrete.

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Preparation of BaTiO3 Powder in $BaO2-TiO2-Reduction Agent-PSCA (Particle Size Control Agent) System by SHS and Its Dielectric Properties (B3O2-TiO2-환원제-입자제어제계에서 자전연소합성법에 의한 BaTiO3분말의 제조 및 유전특성)

  • Yun, Ki-Seok;Lim, Sung-Jae;Nersisyan, Hayk;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.41 no.11
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    • pp.842-850
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    • 2004
  • We have investigated on the preparation of BaTiO$_3$ powder at the system of BaO$_2$-TiO$_2$-Reduction ag.-PSCA by SHS. C and Mg were used as reduction agent, and NaCl was used as PSCA (Particle Size Control Agent). The effects of the various reduction agent and its concentration, particle size control agent, reaction mixture mass on the product in the preparation of BaTiO$_3$ powder at the optimum system by SHS were investigated. The optimum conditions for reaction system and composition were BaO$_2$+TiO$_2$+0.11 Mg +0.2C+0.75NaCl in the As atmosphere. NaCl as PSCA showed the effect of controlling the particle size of product as well as the combustion temperature. The particle size of BaTiO$_3$ synthesized at the optimum condition was about 0.5 ${\mu}{\textrm}{m}$. And as the mixture mass for the reaction was increased, the more stable combustion wave appeared. We have conducted the sintering experiment at the temperature of 130$0^{\circ}C$, the time of 2 h and the atmosphere of air to measure the dielectric properties of BaTiO$_3$ synthesised in this work, and the sample sintered in this condition showed 2,290 of dielectric constant at 10$0^{\circ}C$ and 13,890 at curie point (129$^{\circ}C$).

Effect of Citric Acid in Cu Chemical Mechanical Planarization Slurry on Frictional Characteristics and Step Height Reduction of Cu Pattern

  • Lee, Hyunseop
    • Tribology and Lubricants
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    • v.34 no.6
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    • pp.226-234
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    • 2018
  • Copper chemical mechanical planarization (CMP) has become a key process in integrated circuit (IC) technology. The results of copper CMP depend not only on the mechanical abrasion, but also on the slurry chemistry. The slurry used for Cu CMP is known to have greater chemical reactivity than mechanical material removal. The Cu CMP slurry is composed of abrasive particles, an oxidizing agent, a complexing agent, and a corrosion inhibitor. Citric acid can be used as the complexing agent in Cu CMP slurries, and is widely used for post-CMP cleaning. Although many studies have investigated the effect of citric acid on Cu CMP, no studies have yet been conducted on the interfacial friction characteristics and step height reduction in CMP patterns. In this study, the effect of citric acid on the friction characteristics and step height reduction in a copper wafer with varying pattern densities during CMP are investigated. The prepared slurry consists of citric acid ($C_6H_8O_7$), hydrogen peroxide ($H_2O_2$), and colloidal silica. The friction force is found to depend on the concentration of citric acid in the copper CMP slurry. The step heights of the patterns decrease rapidly with decreasing citric acid concentration in the copper CMP slurry. The step height of the copper pattern decreases more slowly in high-density regions than in low-density regions.

Effects of a Temperature-Sensitive, Anti-Adhesive Agent on the Reduction of Adhesion in a Rabbit Laminectomy Model

  • Park, Jeong Woo;Bak, Koang Hum;Cho, Tae Koo;Chun, Hyoung-Joon;Ryu, Je Il
    • Journal of Korean Neurosurgical Society
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    • v.59 no.3
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    • pp.250-258
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    • 2016
  • Objective : A common cause of failure in laminectomy surgery is when epidural, peridural, or perineural adhesion occurs postoperatively. The purpose of this study is to examine the efficacy of a temperature-sensitive, anti-adhesive agent (TSAA agent), Guardix-SG$^{(R)}$, as a mechanical barrier for the prevention or reduction of peridural scar adhesion in a rabbit laminectomy model. Methods : Twenty-six mature rabbits were used for this study. Each rabbit underwent two separate laminectomies at lumbar vertebrae L3 and L6, left empty (the control group) and applied 2 mL of the TSAA agent (the experimental group), respectively. Invasive scar formation or inflammation after laminectomy was quantitatively evaluated by measuring the thickness of the dura, the distance from the surface of dura to the scar tissues, the number of inflammatory cells in the scar tissues at the laminectomy site, and the concentration of collagen in histological sections. Results : At 6 weeks postsurgery, the dura was significantly thinner and the distance from the surface of dura to the scar tissues was greater in the experimental group than in the control group (p=0.04 and p=0.01). The number of inflammatory cells was not significantly different in the two groups (p=0.08), although the mean number of inflammatory cells was relatively lower in the experimental group than in the control group. Conclusion : The current study suggests that the TSAA agent, Guardix-SG$^{(R)}$, could be useful as an interpositional physical barrier after laminectomy for the prevention or reduction of adhesion.